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Article: Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands

TitleSynthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands
Authors
Issue Date2001
Citation
Journal Of The Chemical Society, Dalton Transactions, 2001 n. 12, p. 1911-1919 How to Cite?
AbstractA series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen) 2{=C(CH 2Ph)NHC 6H 4}]CF 3SO 3, [Ru(bpy) 2{=C(CH 2Ph)NMeC 6H 4}]PF 6 and [Ru(bpy) 2{=C(CH 2C 4H 3S)NHC 6H 4}]CF 3SO 3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies.
Persistent Identifierhttp://hdl.handle.net/10722/167674
ISSN
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorChu, BWKen_US
dc.contributor.authorKo, CCen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:09:50Z-
dc.date.available2012-10-08T03:09:50Z-
dc.date.issued2001en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 2001 n. 12, p. 1911-1919en_US
dc.identifier.issn1470-479Xen_US
dc.identifier.urihttp://hdl.handle.net/10722/167674-
dc.description.abstractA series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen) 2{=C(CH 2Ph)NHC 6H 4}]CF 3SO 3, [Ru(bpy) 2{=C(CH 2Ph)NMeC 6H 4}]PF 6 and [Ru(bpy) 2{=C(CH 2C 4H 3S)NHC 6H 4}]CF 3SO 3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleSynthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligandsen_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/B100696G-
dc.identifier.scopuseid_2-s2.0-0034743192en_US
dc.identifier.hkuros62507-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0034743192&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue12en_US
dc.identifier.spage1911en_US
dc.identifier.epage1919en_US
dc.identifier.isiWOS:000169158500018-
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridChu, BWK=35209639800en_US
dc.identifier.scopusauthoridKo, CC=35210609800en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

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