File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Synthesis, emission, and electrochemical properties of luminescent dinuclear Zinc(II) chalcogenolate complexes. Dynamic 1H NMR studies and x-ray crystal structure of [(bpy) Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2]

TitleSynthesis, emission, and electrochemical properties of luminescent dinuclear Zinc(II) chalcogenolate complexes. Dynamic 1H NMR studies and x-ray crystal structure of [(bpy) Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2]
Authors
Issue Date2000
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2000, v. 39 n. 25, p. 5741-5746 How to Cite?
AbstractA series of novel luminescent dinuclear zinc(II) diimine complexes with bridging chalcogenolate ligands have been synthesized, in which the two zinc atoms were found to exist in different coordination environment. The luminescence and electrochemical behavior of these complexes have been studied. These complexes have also been shown to exhibit dynamic fluxional behavior in solution due to an exchange of the bridging and terminal thiolate ligands. The mechanism and kinetics of which have been investigated by variable-temperature 1H NMR studies. The X-ray crystal structure of [(bpy)Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2] has also been determined.
Persistent Identifierhttp://hdl.handle.net/10722/167660
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorPui, YLen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:09:32Z-
dc.date.available2012-10-08T03:09:32Z-
dc.date.issued2000en_US
dc.identifier.citationInorganic Chemistry, 2000, v. 39 n. 25, p. 5741-5746en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167660-
dc.description.abstractA series of novel luminescent dinuclear zinc(II) diimine complexes with bridging chalcogenolate ligands have been synthesized, in which the two zinc atoms were found to exist in different coordination environment. The luminescence and electrochemical behavior of these complexes have been studied. These complexes have also been shown to exhibit dynamic fluxional behavior in solution due to an exchange of the bridging and terminal thiolate ligands. The mechanism and kinetics of which have been investigated by variable-temperature 1H NMR studies. The X-ray crystal structure of [(bpy)Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2] has also been determined.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.subject.meshCrystallography, X-Rayen_US
dc.subject.meshElectrochemistryen_US
dc.subject.meshKineticsen_US
dc.subject.meshLigandsen_US
dc.subject.meshLuminescenceen_US
dc.subject.meshMagnetic Resonance Spectroscopyen_US
dc.subject.meshModels, Molecularen_US
dc.subject.meshMolecular Conformationen_US
dc.subject.meshOrganometallic Compounds - Chemical Synthesis - Chemistryen_US
dc.subject.meshThermodynamicsen_US
dc.subject.meshZincen_US
dc.titleSynthesis, emission, and electrochemical properties of luminescent dinuclear Zinc(II) chalcogenolate complexes. Dynamic 1H NMR studies and x-ray crystal structure of [(bpy) Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2]en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic000688gen_US
dc.identifier.pmid11151374-
dc.identifier.scopuseid_2-s2.0-0034638848en_US
dc.identifier.hkuros62298-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0034638848&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume39en_US
dc.identifier.issue25en_US
dc.identifier.spage5741en_US
dc.identifier.epage5746en_US
dc.identifier.isiWOS:000165858100020-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridPui, YL=6507440586en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats