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- Publisher Website: 10.1021/ic000688g
- Scopus: eid_2-s2.0-0034638848
- PMID: 11151374
- WOS: WOS:000165858100020
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Article: Synthesis, emission, and electrochemical properties of luminescent dinuclear Zinc(II) chalcogenolate complexes. Dynamic 1H NMR studies and x-ray crystal structure of [(bpy) Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2]
Title | Synthesis, emission, and electrochemical properties of luminescent dinuclear Zinc(II) chalcogenolate complexes. Dynamic 1H NMR studies and x-ray crystal structure of [(bpy) Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2] |
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Authors | |
Issue Date | 2000 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
Citation | Inorganic Chemistry, 2000, v. 39 n. 25, p. 5741-5746 How to Cite? |
Abstract | A series of novel luminescent dinuclear zinc(II) diimine complexes with bridging chalcogenolate ligands have been synthesized, in which the two zinc atoms were found to exist in different coordination environment. The luminescence and electrochemical behavior of these complexes have been studied. These complexes have also been shown to exhibit dynamic fluxional behavior in solution due to an exchange of the bridging and terminal thiolate ligands. The mechanism and kinetics of which have been investigated by variable-temperature 1H NMR studies. The X-ray crystal structure of [(bpy)Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2] has also been determined. |
Persistent Identifier | http://hdl.handle.net/10722/167660 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Pui, YL | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.date.accessioned | 2012-10-08T03:09:32Z | - |
dc.date.available | 2012-10-08T03:09:32Z | - |
dc.date.issued | 2000 | en_US |
dc.identifier.citation | Inorganic Chemistry, 2000, v. 39 n. 25, p. 5741-5746 | en_US |
dc.identifier.issn | 0020-1669 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167660 | - |
dc.description.abstract | A series of novel luminescent dinuclear zinc(II) diimine complexes with bridging chalcogenolate ligands have been synthesized, in which the two zinc atoms were found to exist in different coordination environment. The luminescence and electrochemical behavior of these complexes have been studied. These complexes have also been shown to exhibit dynamic fluxional behavior in solution due to an exchange of the bridging and terminal thiolate ligands. The mechanism and kinetics of which have been investigated by variable-temperature 1H NMR studies. The X-ray crystal structure of [(bpy)Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2] has also been determined. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_US |
dc.relation.ispartof | Inorganic Chemistry | en_US |
dc.subject.mesh | Crystallography, X-Ray | en_US |
dc.subject.mesh | Electrochemistry | en_US |
dc.subject.mesh | Kinetics | en_US |
dc.subject.mesh | Ligands | en_US |
dc.subject.mesh | Luminescence | en_US |
dc.subject.mesh | Magnetic Resonance Spectroscopy | en_US |
dc.subject.mesh | Models, Molecular | en_US |
dc.subject.mesh | Molecular Conformation | en_US |
dc.subject.mesh | Organometallic Compounds - Chemical Synthesis - Chemistry | en_US |
dc.subject.mesh | Thermodynamics | en_US |
dc.subject.mesh | Zinc | en_US |
dc.title | Synthesis, emission, and electrochemical properties of luminescent dinuclear Zinc(II) chalcogenolate complexes. Dynamic 1H NMR studies and x-ray crystal structure of [(bpy) Zn 2(SC 6H 4-Cl-p) (μ-SC 6H 4-Cl-p)(μ-OAc) 2] | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ic000688g | en_US |
dc.identifier.pmid | 11151374 | - |
dc.identifier.scopus | eid_2-s2.0-0034638848 | en_US |
dc.identifier.hkuros | 62298 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0034638848&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 39 | en_US |
dc.identifier.issue | 25 | en_US |
dc.identifier.spage | 5741 | en_US |
dc.identifier.epage | 5746 | en_US |
dc.identifier.isi | WOS:000165858100020 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Pui, YL=6507440586 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.issnl | 0020-1669 | - |