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Article: Elimination of AgR (R = H, CH 3, C 6H 5) from collisionally-activated argentinated amines

TitleElimination of AgR (R = H, CH 3, C 6H 5) from collisionally-activated argentinated amines
Authors
KeywordsAgh
Argentinated Amines
Elimination
Fragmentation
Issue Date2000
Citation
European Journal Of Mass Spectrometry, 2000, v. 6 n. 2, p. 187-192 How to Cite?
AbstractFragmentation of collisionally-activated argentinated amines results in the formation of Ag + and non-silver-containing ions. The latter are likely immonium ions that are formed after elimination of AgH and, when the ion structures permit, AgCH 3 or AgC 6H 5. The H, CH 3 and C 6H 5 groups are attached to the carbon alpha to the amino nitrogen, and are believed to be cleaved with the Ag in a 1,2-elimination. This hypothesis is supported by potential energy hypersurfaces calculated using density functional theory for the reactions involving methanamine and ethanamine.
Persistent Identifierhttp://hdl.handle.net/10722/167654
ISSN
2015 Impact Factor: 1.011
2015 SCImago Journal Rankings: 0.380
References

 

DC FieldValueLanguage
dc.contributor.authorGrewal, RNen_US
dc.contributor.authorRodriquez, CFen_US
dc.contributor.authorShoeib, Ten_US
dc.contributor.authorChu, IKen_US
dc.contributor.authorTu, YPen_US
dc.contributor.authorHopkinson, ACen_US
dc.contributor.authorSiu, KWMen_US
dc.date.accessioned2012-10-08T03:09:29Z-
dc.date.available2012-10-08T03:09:29Z-
dc.date.issued2000en_US
dc.identifier.citationEuropean Journal Of Mass Spectrometry, 2000, v. 6 n. 2, p. 187-192en_US
dc.identifier.issn1469-0667en_US
dc.identifier.urihttp://hdl.handle.net/10722/167654-
dc.description.abstractFragmentation of collisionally-activated argentinated amines results in the formation of Ag + and non-silver-containing ions. The latter are likely immonium ions that are formed after elimination of AgH and, when the ion structures permit, AgCH 3 or AgC 6H 5. The H, CH 3 and C 6H 5 groups are attached to the carbon alpha to the amino nitrogen, and are believed to be cleaved with the Ag in a 1,2-elimination. This hypothesis is supported by potential energy hypersurfaces calculated using density functional theory for the reactions involving methanamine and ethanamine.en_US
dc.languageengen_US
dc.relation.ispartofEuropean Journal of Mass Spectrometryen_US
dc.subjectAghen_US
dc.subjectArgentinated Aminesen_US
dc.subjectEliminationen_US
dc.subjectFragmentationen_US
dc.titleElimination of AgR (R = H, CH 3, C 6H 5) from collisionally-activated argentinated aminesen_US
dc.typeArticleen_US
dc.identifier.emailChu, IK:ivankchu@hku.hken_US
dc.identifier.authorityChu, IK=rp00683en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-0034557670en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0034557670&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume6en_US
dc.identifier.issue2en_US
dc.identifier.spage187en_US
dc.identifier.epage192en_US
dc.identifier.scopusauthoridGrewal, RN=7101680807en_US
dc.identifier.scopusauthoridRodriquez, CF=7004085075en_US
dc.identifier.scopusauthoridShoeib, T=6603516521en_US
dc.identifier.scopusauthoridChu, IK=7103327484en_US
dc.identifier.scopusauthoridTu, YP=36118358900en_US
dc.identifier.scopusauthoridHopkinson, AC=15067169300en_US
dc.identifier.scopusauthoridSiu, KWM=35312218500en_US

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