File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Physical and electrochemical properties of acid 1-methyl-3-ethylimidazolium chloride/AlCl 3/LiAlCl 4 molten salt

TitlePhysical and electrochemical properties of acid 1-methyl-3-ethylimidazolium chloride/AlCl 3/LiAlCl 4 molten salt
Authors
Issue Date2000
PublisherBeijing Keji Daxue. The Journal's web site is located at http://www.ustb.edu.cn/xuebaozr
Citation
Journal Of University Of Science And Technology Beijing: Mineral Metallurgy Materials (Eng Ed), 2000, v. 7 n. 4, p. 286-291 How to Cite?
AbstractAn acid molten salt was formed by means of mixing 1-methyl-3-ethylimidazolium chloride with AlCl 3 and LiAlCl 4 at ambient temperature. The solubility of LiAlC 4 in the acid molten salt was measured. Variations of specific conductivity, density and kinetic viscosity of molten salt with mole ratio of MeEtImCl/AlCl 3/LiAlCl 4, were observed. A solubility maximum of LiAlCl 4 with 54% in molar fraction was shown at a mole ratio of AlCl 3/MeEtImCl = 1.2. An increase in density and viscosity, and a decrease in specific conductivity were found with increasing the concentrations of LiAlCl 4 and AlCl 3. The dependence of specific conductivity of this acid molten salt upon temperature was found to display Vogel-Tammanm-Fucher behavior. However, Arrhenius behavior was observed at two special mole ratios of MeEtImCl/AlCI 3LiAlCl 4 = 1:1.5:0.05 and 1:1.5:0.10. The conductivity equations of this molten salt at various compositions were constructed. The ion interaction in the acid molten salt was studied using 7Li and 27Al nuclear magnetic resonance spectroscopic methods. The effect of concentrations of LiAlCl 4 and AlCl 3 on the ion interaction was also discussed.
Persistent Identifierhttp://hdl.handle.net/10722/167651
ISSN
2010 Impact Factor: 0.919
References

 

DC FieldValueLanguage
dc.contributor.authorFung, YSen_US
dc.contributor.authorZhou, Ren_US
dc.date.accessioned2012-10-08T03:09:27Z-
dc.date.available2012-10-08T03:09:27Z-
dc.date.issued2000en_US
dc.identifier.citationJournal Of University Of Science And Technology Beijing: Mineral Metallurgy Materials (Eng Ed), 2000, v. 7 n. 4, p. 286-291en_US
dc.identifier.issn1005-8850en_US
dc.identifier.urihttp://hdl.handle.net/10722/167651-
dc.description.abstractAn acid molten salt was formed by means of mixing 1-methyl-3-ethylimidazolium chloride with AlCl 3 and LiAlCl 4 at ambient temperature. The solubility of LiAlC 4 in the acid molten salt was measured. Variations of specific conductivity, density and kinetic viscosity of molten salt with mole ratio of MeEtImCl/AlCl 3/LiAlCl 4, were observed. A solubility maximum of LiAlCl 4 with 54% in molar fraction was shown at a mole ratio of AlCl 3/MeEtImCl = 1.2. An increase in density and viscosity, and a decrease in specific conductivity were found with increasing the concentrations of LiAlCl 4 and AlCl 3. The dependence of specific conductivity of this acid molten salt upon temperature was found to display Vogel-Tammanm-Fucher behavior. However, Arrhenius behavior was observed at two special mole ratios of MeEtImCl/AlCI 3LiAlCl 4 = 1:1.5:0.05 and 1:1.5:0.10. The conductivity equations of this molten salt at various compositions were constructed. The ion interaction in the acid molten salt was studied using 7Li and 27Al nuclear magnetic resonance spectroscopic methods. The effect of concentrations of LiAlCl 4 and AlCl 3 on the ion interaction was also discussed.en_US
dc.languageengen_US
dc.publisherBeijing Keji Daxue. The Journal's web site is located at http://www.ustb.edu.cn/xuebaozren_US
dc.relation.ispartofJournal of University of Science and Technology Beijing: Mineral Metallurgy Materials (Eng Ed)en_US
dc.titlePhysical and electrochemical properties of acid 1-methyl-3-ethylimidazolium chloride/AlCl 3/LiAlCl 4 molten salten_US
dc.typeArticleen_US
dc.identifier.emailFung, YS:ysfung@hku.hken_US
dc.identifier.authorityFung, YS=rp00697en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-0034482475en_US
dc.identifier.hkuros62496-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0034482475&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume7en_US
dc.identifier.issue4en_US
dc.identifier.spage286en_US
dc.identifier.epage291en_US
dc.publisher.placeChinaen_US
dc.identifier.scopusauthoridFung, YS=13309754700en_US
dc.identifier.scopusauthoridZhou, R=55160919500en_US

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats