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Article: Synthesis of luminescent zirconium thiolate complexes. Crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O

TitleSynthesis of luminescent zirconium thiolate complexes. Crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O
Authors
KeywordsCrystal Structure
Luminescent Complexes
Thiolate Complexes
Zirconium Complexes
Zirconocene
Issue Date1997
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 1997, v. 548 n. 2, p. 289-294 How to Cite?
AbstractSeveral luminescent zirconium thiolate complexes (η5-C5H5)2Zr(SC6H4R-p)2, where R = Cl (1), Me (2), OMe (3), have been synthesized by the reaction of Cp2ZrCl2 with HSC6H4R-p in the presence of Et3N. The crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O (4), which has been isolated as a hydrolysis product of (η5-C5H5)2Zr(SC6H4OMe-p)2, have been determined. Complex 1 crystallizes in the monoclinic space group P21/a, with a = 12.182(1) Å, b = 10.674(4) Å, c= 17.131(2) Å, β= 103.949(6)°, Z = 4, and V = 2161.8(6) Å3. The Zr atom is in a distorted tetrahedral coordination environment with the thiolate ligands adopting an "endo(anti)" configuration. The two Cp rings have a nearly eclipsed geometry. Complex 4 crystallized in the monoclinic space group P21/c, with a= 15.533(1) Å, b = 15.217(4) Å, c = 13.382(2) Å, β = 90.00(2)°, Z = 4, and V = 3162(1) Å3. © 1997 Elsevier Science S.A.
Persistent Identifierhttp://hdl.handle.net/10722/167576
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorQi, GZen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:08:41Z-
dc.date.available2012-10-08T03:08:41Z-
dc.date.issued1997en_US
dc.identifier.citationJournal Of Organometallic Chemistry, 1997, v. 548 n. 2, p. 289-294en_US
dc.identifier.issn0022-328Xen_US
dc.identifier.urihttp://hdl.handle.net/10722/167576-
dc.description.abstractSeveral luminescent zirconium thiolate complexes (η5-C5H5)2Zr(SC6H4R-p)2, where R = Cl (1), Me (2), OMe (3), have been synthesized by the reaction of Cp2ZrCl2 with HSC6H4R-p in the presence of Et3N. The crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O (4), which has been isolated as a hydrolysis product of (η5-C5H5)2Zr(SC6H4OMe-p)2, have been determined. Complex 1 crystallizes in the monoclinic space group P21/a, with a = 12.182(1) Å, b = 10.674(4) Å, c= 17.131(2) Å, β= 103.949(6)°, Z = 4, and V = 2161.8(6) Å3. The Zr atom is in a distorted tetrahedral coordination environment with the thiolate ligands adopting an "endo(anti)" configuration. The two Cp rings have a nearly eclipsed geometry. Complex 4 crystallized in the monoclinic space group P21/c, with a= 15.533(1) Å, b = 15.217(4) Å, c = 13.382(2) Å, β = 90.00(2)°, Z = 4, and V = 3162(1) Å3. © 1997 Elsevier Science S.A.en_US
dc.languageengen_US
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.subjectCrystal Structureen_US
dc.subjectLuminescent Complexesen_US
dc.subjectThiolate Complexesen_US
dc.subjectZirconium Complexesen_US
dc.subjectZirconoceneen_US
dc.titleSynthesis of luminescent zirconium thiolate complexes. Crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2Oen_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0022-328X(97)00488-9-
dc.identifier.scopuseid_2-s2.0-0031564338en_US
dc.identifier.hkuros31402-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0031564338&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume548en_US
dc.identifier.issue2en_US
dc.identifier.spage289en_US
dc.identifier.epage294en_US
dc.publisher.placeSwitzerlanden_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridQi, GZ=8300870200en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

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