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Article: Synthesis of luminescent zirconium thiolate complexes. Crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O
Title | Synthesis of luminescent zirconium thiolate complexes. Crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O |
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Authors | |
Keywords | Crystal Structure Luminescent Complexes Thiolate Complexes Zirconium Complexes Zirconocene |
Issue Date | 1997 |
Publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem |
Citation | Journal Of Organometallic Chemistry, 1997, v. 548 n. 2, p. 289-294 How to Cite? |
Abstract | Several luminescent zirconium thiolate complexes (η5-C5H5)2Zr(SC6H4R-p)2, where R = Cl (1), Me (2), OMe (3), have been synthesized by the reaction of Cp2ZrCl2 with HSC6H4R-p in the presence of Et3N. The crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O (4), which has been isolated as a hydrolysis product of (η5-C5H5)2Zr(SC6H4OMe-p)2, have been determined. Complex 1 crystallizes in the monoclinic space group P21/a, with a = 12.182(1) Å, b = 10.674(4) Å, c= 17.131(2) Å, β= 103.949(6)°, Z = 4, and V = 2161.8(6) Å3. The Zr atom is in a distorted tetrahedral coordination environment with the thiolate ligands adopting an "endo(anti)" configuration. The two Cp rings have a nearly eclipsed geometry. Complex 4 crystallized in the monoclinic space group P21/c, with a= 15.533(1) Å, b = 15.217(4) Å, c = 13.382(2) Å, β = 90.00(2)°, Z = 4, and V = 3162(1) Å3. © 1997 Elsevier Science S.A. |
Persistent Identifier | http://hdl.handle.net/10722/167576 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Qi, GZ | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.date.accessioned | 2012-10-08T03:08:41Z | - |
dc.date.available | 2012-10-08T03:08:41Z | - |
dc.date.issued | 1997 | en_US |
dc.identifier.citation | Journal Of Organometallic Chemistry, 1997, v. 548 n. 2, p. 289-294 | en_US |
dc.identifier.issn | 0022-328X | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167576 | - |
dc.description.abstract | Several luminescent zirconium thiolate complexes (η5-C5H5)2Zr(SC6H4R-p)2, where R = Cl (1), Me (2), OMe (3), have been synthesized by the reaction of Cp2ZrCl2 with HSC6H4R-p in the presence of Et3N. The crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O (4), which has been isolated as a hydrolysis product of (η5-C5H5)2Zr(SC6H4OMe-p)2, have been determined. Complex 1 crystallizes in the monoclinic space group P21/a, with a = 12.182(1) Å, b = 10.674(4) Å, c= 17.131(2) Å, β= 103.949(6)°, Z = 4, and V = 2161.8(6) Å3. The Zr atom is in a distorted tetrahedral coordination environment with the thiolate ligands adopting an "endo(anti)" configuration. The two Cp rings have a nearly eclipsed geometry. Complex 4 crystallized in the monoclinic space group P21/c, with a= 15.533(1) Å, b = 15.217(4) Å, c = 13.382(2) Å, β = 90.00(2)°, Z = 4, and V = 3162(1) Å3. © 1997 Elsevier Science S.A. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem | en_US |
dc.relation.ispartof | Journal of Organometallic Chemistry | en_US |
dc.subject | Crystal Structure | en_US |
dc.subject | Luminescent Complexes | en_US |
dc.subject | Thiolate Complexes | en_US |
dc.subject | Zirconium Complexes | en_US |
dc.subject | Zirconocene | en_US |
dc.title | Synthesis of luminescent zirconium thiolate complexes. Crystal structures of (η5-C5H5)2Zr(SC6H4Cl-p)2 and [(η5-C5H5)2Zr(SC6H4OMe-p)]2O | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0022-328X(97)00488-9 | - |
dc.identifier.scopus | eid_2-s2.0-0031564338 | en_US |
dc.identifier.hkuros | 31402 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0031564338&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 548 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.spage | 289 | en_US |
dc.identifier.epage | 294 | en_US |
dc.publisher.place | Switzerland | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Qi, GZ=8300870200 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.issnl | 0022-328X | - |