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Article: Synthesis and spectroscopic studies of manganese porphyrin-thiolate complexes

TitleSynthesis and spectroscopic studies of manganese porphyrin-thiolate complexes
Authors
KeywordsManganese Porphyrin Thiolate
Nmr
Synthesis
Uv-Vis
Issue Date1997
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1997, v. 16 n. 16, p. 2885-2888 How to Cite?
AbstractThe synthesis and spectroscopic characterization of four manganese(III) porphyrin thiolates are reported. The investigated compounds are represented by (TPP)Mn(SR), where TPP is the dianion of tetraphenylporhyrin and R is C6H5, C6H4(p-NO2), Et2NCS and C4H8NCS. Each complex was characterized by UV-vis and 1H NMR spectroscopy. The effects of axial ligands on the UV-vis spectra of synthesized manganese porphyrin complexes is discussed and proton isotropic shifts are shown to be predominantly contact in origin, reflecting extensive porphyrin-to-metal π bonding. © 1997 Elsevier Science Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/167390
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorMu, Len_US
dc.contributor.authorHuang, Jen_US
dc.contributor.authorZhou, Yen_US
dc.contributor.authorShen, Pen_US
dc.date.accessioned2012-10-08T03:06:24Z-
dc.date.available2012-10-08T03:06:24Z-
dc.date.issued1997en_US
dc.identifier.citationPolyhedron, 1997, v. 16 n. 16, p. 2885-2888en_US
dc.identifier.issn0277-5387en_US
dc.identifier.urihttp://hdl.handle.net/10722/167390-
dc.description.abstractThe synthesis and spectroscopic characterization of four manganese(III) porphyrin thiolates are reported. The investigated compounds are represented by (TPP)Mn(SR), where TPP is the dianion of tetraphenylporhyrin and R is C6H5, C6H4(p-NO2), Et2NCS and C4H8NCS. Each complex was characterized by UV-vis and 1H NMR spectroscopy. The effects of axial ligands on the UV-vis spectra of synthesized manganese porphyrin complexes is discussed and proton isotropic shifts are shown to be predominantly contact in origin, reflecting extensive porphyrin-to-metal π bonding. © 1997 Elsevier Science Ltd.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_US
dc.relation.ispartofPolyhedronen_US
dc.subjectManganese Porphyrin Thiolateen_US
dc.subjectNmren_US
dc.subjectSynthesisen_US
dc.subjectUv-Visen_US
dc.titleSynthesis and spectroscopic studies of manganese porphyrin-thiolate complexesen_US
dc.typeArticleen_US
dc.identifier.emailHuang, J:jshuang@hkucc.hku.hken_US
dc.identifier.authorityHuang, J=rp00709en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0277-5387(96)00604-3-
dc.identifier.scopuseid_2-s2.0-0006501230en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0006501230&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume16en_US
dc.identifier.issue16en_US
dc.identifier.spage2885en_US
dc.identifier.epage2888en_US
dc.identifier.isiWOS:A1997XC47600027-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridMu, L=7005437525en_US
dc.identifier.scopusauthoridHuang, J=7407192639en_US
dc.identifier.scopusauthoridZhou, Y=8047648700en_US
dc.identifier.scopusauthoridShen, P=7201767682en_US

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