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Article: Structural and mechanistic studies of coordination compounds. 27. Synthesis and characterization of some trans ruthenium(III) complexes with four different saturated macrocyclic quadridentate secondary amines
| Title | Structural and mechanistic studies of coordination compounds. 27. Synthesis and characterization of some trans ruthenium(III) complexes with four different saturated macrocyclic quadridentate secondary amines |
|---|---|
| Authors | |
| Issue Date | 1981 |
| Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
| Citation | Inorganic Chemistry, 1981, v. 20 n. 6, p. 1640-1643 How to Cite? |
| Abstract | Some ruthenium(III) complexes of the type trans-[Ru(L)X2]+ with four different saturated macrocyclic quadridentate secondary amines [L = 1,4,8,11-tetraazacyclotetradecane (cyclam), X2 = (Cl)Br, I2, (NCS)2, and (CH3COO)2; L = 1,4,8,12-tetraazacyclopentadecane ([15]aneN4), C-meso- and C-rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (teta and tetb respectively), X2 = Cl2 and Br2] have been prepared and characterized. They are all monomeric, low-spin species with a trans configuration. The electronic and infrared absorption spectra of these complexes are discussed. © 1981 American Chemical Society. |
| Persistent Identifier | http://hdl.handle.net/10722/167349 |
| ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Poon, CK | en_US |
| dc.contributor.author | Che, CM | en_US |
| dc.date.accessioned | 2012-10-08T03:05:55Z | - |
| dc.date.available | 2012-10-08T03:05:55Z | - |
| dc.date.issued | 1981 | en_US |
| dc.identifier.citation | Inorganic Chemistry, 1981, v. 20 n. 6, p. 1640-1643 | en_US |
| dc.identifier.issn | 0020-1669 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10722/167349 | - |
| dc.description.abstract | Some ruthenium(III) complexes of the type trans-[Ru(L)X2]+ with four different saturated macrocyclic quadridentate secondary amines [L = 1,4,8,11-tetraazacyclotetradecane (cyclam), X2 = (Cl)Br, I2, (NCS)2, and (CH3COO)2; L = 1,4,8,12-tetraazacyclopentadecane ([15]aneN4), C-meso- and C-rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (teta and tetb respectively), X2 = Cl2 and Br2] have been prepared and characterized. They are all monomeric, low-spin species with a trans configuration. The electronic and infrared absorption spectra of these complexes are discussed. © 1981 American Chemical Society. | en_US |
| dc.language | eng | en_US |
| dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_US |
| dc.relation.ispartof | Inorganic Chemistry | en_US |
| dc.title | Structural and mechanistic studies of coordination compounds. 27. Synthesis and characterization of some trans ruthenium(III) complexes with four different saturated macrocyclic quadridentate secondary amines | en_US |
| dc.type | Article | en_US |
| dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
| dc.identifier.authority | Che, CM=rp00670 | en_US |
| dc.description.nature | link_to_subscribed_fulltext | en_US |
| dc.identifier.scopus | eid_2-s2.0-0001490579 | en_US |
| dc.identifier.volume | 20 | en_US |
| dc.identifier.issue | 6 | en_US |
| dc.identifier.spage | 1640 | en_US |
| dc.identifier.epage | 1643 | en_US |
| dc.identifier.isi | WOS:A1981LS20400004 | - |
| dc.publisher.place | United States | en_US |
| dc.identifier.scopusauthorid | Poon, CK=7202673504 | en_US |
| dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
| dc.identifier.issnl | 0020-1669 | - |