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Article: Synthesis, emission, and molecular orbital studies of luminescent hafnium thiolate complexes. Crystal structures of (η5-C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p)
Title | Synthesis, emission, and molecular orbital studies of luminescent hafnium thiolate complexes. Crystal structures of (η5-C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p) |
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Authors | |
Issue Date | 1998 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics |
Citation | Organometallics, 1998, v. 17 n. 25, p. 5448-5453 How to Cite? |
Abstract | A series of luminescent hafnium thiolate complexes (η5C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p, C6H4 tBu-p) have been synthesized by the reaction of (η5-C5Me5)2HfCl2 with LiSR and shown to exhibit rich luminescence behavior. The crystal structures of (η5-C5Me5)2Hf-(S nBu)2, (η5-C5Me5)2Hf(SC 6H5)2, and (η5-C5Me5)2Hf(SC 6H4OMe-p)2 have been determined. Fenske-Hall molecular orbital calculations on the hafnium thiolate complexes reveal a thiolate-based HOMO and a LUMO that is mainly composed of hafnium d character. © 1998 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/167315 |
ISSN | 2023 Impact Factor: 2.5 2023 SCImago Journal Rankings: 0.654 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Qi, GZ | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.date.accessioned | 2012-10-08T03:05:35Z | - |
dc.date.available | 2012-10-08T03:05:35Z | - |
dc.date.issued | 1998 | en_US |
dc.identifier.citation | Organometallics, 1998, v. 17 n. 25, p. 5448-5453 | en_US |
dc.identifier.issn | 0276-7333 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167315 | - |
dc.description.abstract | A series of luminescent hafnium thiolate complexes (η5C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p, C6H4 tBu-p) have been synthesized by the reaction of (η5-C5Me5)2HfCl2 with LiSR and shown to exhibit rich luminescence behavior. The crystal structures of (η5-C5Me5)2Hf-(S nBu)2, (η5-C5Me5)2Hf(SC 6H5)2, and (η5-C5Me5)2Hf(SC 6H4OMe-p)2 have been determined. Fenske-Hall molecular orbital calculations on the hafnium thiolate complexes reveal a thiolate-based HOMO and a LUMO that is mainly composed of hafnium d character. © 1998 American Chemical Society. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics | en_US |
dc.relation.ispartof | Organometallics | en_US |
dc.title | Synthesis, emission, and molecular orbital studies of luminescent hafnium thiolate complexes. Crystal structures of (η5-C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/om980602f | - |
dc.identifier.scopus | eid_2-s2.0-0001005494 | en_US |
dc.identifier.hkuros | 39871 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0001005494&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 17 | en_US |
dc.identifier.issue | 25 | en_US |
dc.identifier.spage | 5448 | en_US |
dc.identifier.epage | 5453 | en_US |
dc.identifier.isi | WOS:000077517600003 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Qi, GZ=8300870200 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.issnl | 0276-7333 | - |