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Article: Synthesis, photophysics, and electrochemistry of luminescent binuclear rhenium(I) complexes containing μ-bridging thiolates. X-ray crystal structure of [{Re(bpy)(CO)3}2(μ-SC6H4-CH 3-P)]OTf

TitleSynthesis, photophysics, and electrochemistry of luminescent binuclear rhenium(I) complexes containing μ-bridging thiolates. X-ray crystal structure of [{Re(bpy)(CO)3}2(μ-SC6H4-CH 3-P)]OTf
Authors
Issue Date1997
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 1997, v. 16 n. 8, p. 1729-1734 How to Cite?
AbstractA series of binuclear Re(I) thiolato complexes [{Re(L-L)(CO)3}2(μ-SC6H 4-X-P)]OTf[L-L = phen, X = CH3 (1), OCH3 (2), C(CH3)3 (3), Cl (4), F (5); L-L = bpy, X = CH3 (6); L-L = 5,5′-Me2-bpy, X = CH3 (7)] have been synthesized and their photophysical and electrochemical properties studied. The X-ray crystal structure of 6 has also been determined. The complexes have been shown to exhibit long-lived luminescence both in the solid state and in fluid solutions at room temperature. The emission has been assigned as being derived from a 3MLCT origin.
Persistent Identifierhttp://hdl.handle.net/10722/167310
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorWong, KMCen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:05:31Z-
dc.date.available2012-10-08T03:05:31Z-
dc.date.issued1997en_US
dc.identifier.citationOrganometallics, 1997, v. 16 n. 8, p. 1729-1734en_US
dc.identifier.issn0276-7333en_US
dc.identifier.urihttp://hdl.handle.net/10722/167310-
dc.description.abstractA series of binuclear Re(I) thiolato complexes [{Re(L-L)(CO)3}2(μ-SC6H 4-X-P)]OTf[L-L = phen, X = CH3 (1), OCH3 (2), C(CH3)3 (3), Cl (4), F (5); L-L = bpy, X = CH3 (6); L-L = 5,5′-Me2-bpy, X = CH3 (7)] have been synthesized and their photophysical and electrochemical properties studied. The X-ray crystal structure of 6 has also been determined. The complexes have been shown to exhibit long-lived luminescence both in the solid state and in fluid solutions at room temperature. The emission has been assigned as being derived from a 3MLCT origin.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_US
dc.relation.ispartofOrganometallicsen_US
dc.titleSynthesis, photophysics, and electrochemistry of luminescent binuclear rhenium(I) complexes containing μ-bridging thiolates. X-ray crystal structure of [{Re(bpy)(CO)3}2(μ-SC6H4-CH 3-P)]OTfen_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.emailWong, KMC:wongmc@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.identifier.authorityWong, KMC=rp00809en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/om960797w-
dc.identifier.scopuseid_2-s2.0-0000926247en_US
dc.identifier.hkuros25817-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000926247&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume16en_US
dc.identifier.issue8en_US
dc.identifier.spage1729en_US
dc.identifier.epage1734en_US
dc.identifier.isiWOS:A1997WU31800030-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridWong, KMC=8061067200en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US

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