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Article: Synthesis and reactivity of dihydroxoruthenium(IV) complex of tetramesitylporphyrin. Aerobic epoxidation of norbornene by ruthenium porphyrins

TitleSynthesis and reactivity of dihydroxoruthenium(IV) complex of tetramesitylporphyrin. Aerobic epoxidation of norbornene by ruthenium porphyrins
Authors
Issue Date1993
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1993, v. 12 n. 19, p. 2331-2334 How to Cite?
AbstractTreatment of Ru(TMP)(CO) with m-CPBA in CH2Cl2/EtOH afforded Ru (TMP)(OH)2, isolated as air-stable violet crystals. Ru(TMP)(OH)2 in paramagnetic (μeff ca 2.7 B.M.) and displays broad 1H NMR signals with paramagnetic isotropic shifts. The IR spectrum shows a band at 760 cm-1 assignable to the RuO stretch. Ru(TMP)(OH)2 is capable of catalysing aerobic epoxidation of alkenes under mild conditions. © 1993.
Persistent Identifierhttp://hdl.handle.net/10722/167309
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLeung, WHen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorYeung, CHen_US
dc.contributor.authorPoo, CKen_US
dc.date.accessioned2012-10-08T03:05:30Z-
dc.date.available2012-10-08T03:05:30Z-
dc.date.issued1993en_US
dc.identifier.citationPolyhedron, 1993, v. 12 n. 19, p. 2331-2334en_US
dc.identifier.issn0277-5387en_US
dc.identifier.urihttp://hdl.handle.net/10722/167309-
dc.description.abstractTreatment of Ru(TMP)(CO) with m-CPBA in CH2Cl2/EtOH afforded Ru (TMP)(OH)2, isolated as air-stable violet crystals. Ru(TMP)(OH)2 in paramagnetic (μeff ca 2.7 B.M.) and displays broad 1H NMR signals with paramagnetic isotropic shifts. The IR spectrum shows a band at 760 cm-1 assignable to the RuO stretch. Ru(TMP)(OH)2 is capable of catalysing aerobic epoxidation of alkenes under mild conditions. © 1993.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_US
dc.relation.ispartofPolyhedronen_US
dc.titleSynthesis and reactivity of dihydroxoruthenium(IV) complex of tetramesitylporphyrin. Aerobic epoxidation of norbornene by ruthenium porphyrinsen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0277-5387(00)83049-1-
dc.identifier.scopuseid_2-s2.0-0000919389en_US
dc.identifier.volume12en_US
dc.identifier.issue19en_US
dc.identifier.spage2331en_US
dc.identifier.epage2334en_US
dc.identifier.isiWOS:A1993MD05400006-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridLeung, WH=7201504510en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridYeung, CH=7201354141en_US
dc.identifier.scopusauthoridPoo, CK=24303541000en_US

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