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Article: Cis ruthenium complexes of 1,4,8,11-tetraazacyclotetradecane (cyclam): Crystal and molecular structure of cis-[Ru(cyclam)Cl2]Cl

TitleCis ruthenium complexes of 1,4,8,11-tetraazacyclotetradecane (cyclam): Crystal and molecular structure of cis-[Ru(cyclam)Cl2]Cl
Authors
Issue Date1985
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 1985, v. 24 n. 9, p. 1359-1363 How to Cite?
AbstractThe crystal and molecular structure of cis-[Ru(cyclam)Cl2]Cl (cyclam = C10H24N4) prepared by the Ru(ox)3 3- (ox = C2O4 2-) method has been determined: monoclinic, space group P21/c, a = 7.579 (1) Å, b = 14.414 (4) Å, c = 14.718 (3) Å, β = 102.33 (1)°, V = 1570.8 (5) Å3, Z = 4. The average Ru-Cl distance, 2.371 (1) Å in the present complex, is substantially longer than that found in the corresponding trans isomer [2.342 (1) Å], reflecting the greater σ-trans effect of the secondary amine N atom over the chloride ligand. Reaction of cis-[Ru(cyclam)Cl2]Cl with N heterocyclic amines and Zn(Hg) yielded cis-[Ru(cyclam)L2]2+ (L2 = (py)2, bpy, phen), the metal-to-ligand charge-transfer transitions of which have been found to be blue shifted from those of the corresponding cis-[Ru(NH3)4L2]2+ species. © 1985 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167306
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorKwong, SSen_US
dc.contributor.authorPoon, CKen_US
dc.contributor.authorLai, TPen_US
dc.contributor.authorMak, TCWen_US
dc.date.accessioned2012-10-08T03:05:30Z-
dc.date.available2012-10-08T03:05:30Z-
dc.date.issued1985en_US
dc.identifier.citationInorganic Chemistry, 1985, v. 24 n. 9, p. 1359-1363en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167306-
dc.description.abstractThe crystal and molecular structure of cis-[Ru(cyclam)Cl2]Cl (cyclam = C10H24N4) prepared by the Ru(ox)3 3- (ox = C2O4 2-) method has been determined: monoclinic, space group P21/c, a = 7.579 (1) Å, b = 14.414 (4) Å, c = 14.718 (3) Å, β = 102.33 (1)°, V = 1570.8 (5) Å3, Z = 4. The average Ru-Cl distance, 2.371 (1) Å in the present complex, is substantially longer than that found in the corresponding trans isomer [2.342 (1) Å], reflecting the greater σ-trans effect of the secondary amine N atom over the chloride ligand. Reaction of cis-[Ru(cyclam)Cl2]Cl with N heterocyclic amines and Zn(Hg) yielded cis-[Ru(cyclam)L2]2+ (L2 = (py)2, bpy, phen), the metal-to-ligand charge-transfer transitions of which have been found to be blue shifted from those of the corresponding cis-[Ru(NH3)4L2]2+ species. © 1985 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleCis ruthenium complexes of 1,4,8,11-tetraazacyclotetradecane (cyclam): Crystal and molecular structure of cis-[Ru(cyclam)Cl2]Clen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic00203a019-
dc.identifier.scopuseid_2-s2.0-0000866705en_US
dc.identifier.volume24en_US
dc.identifier.issue9en_US
dc.identifier.spage1359en_US
dc.identifier.epage1363en_US
dc.identifier.isiWOS:A1985AFX0600019-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridKwong, SS=15134212900en_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US
dc.identifier.scopusauthoridLai, TP=15134382500en_US
dc.identifier.scopusauthoridMak, TCW=7401931058en_US

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