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Article: Synthesis and structural characterization of ruthenium π-arene and π-cyclodienyl complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane

TitleSynthesis and structural characterization of ruthenium π-arene and π-cyclodienyl complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane
Authors
Issue Date1998
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 1998, v. 17 n. 2, p. 151-155 How to Cite?
AbstractThe reaction between Ru(Me3tacn)Cl3 (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) and silver trifluoromethanesulfonate in ethanol affords a green species: treatment with cyclohexa-1,3-diene gives [Ru(Me3tacn)(η6-C6H6)] 2+ (1), while in the presence of zinc dust, reactions with 1-(trimethylsilyl)cyclopentadiene, 1-(trimethylsilyl)indene cyclohexa-13-diene, and cycloheptatriene yield [Ru(Me3tacn)(η5-C5H5)] + (2), [Ru(Me3tacn)(η5-C9H7)] + (3), [Ru(Me3-tacn)((1-5-η)-C6H7)]+ (4), and [Ru(Me3tacn)((1-5-η)-C7H9)]+ (5), respectively. X-ray diffraction studies of the [PF6]- salts of complexes 3-5 show that in each case the η5-bonded unsaturated hydrocarbon moiety is virtually planar.
Persistent Identifierhttp://hdl.handle.net/10722/167302
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYang, SMen_US
dc.contributor.authorChan, MCWen_US
dc.contributor.authorPeng, SMen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:05:27Z-
dc.date.available2012-10-08T03:05:27Z-
dc.date.issued1998en_US
dc.identifier.citationOrganometallics, 1998, v. 17 n. 2, p. 151-155en_US
dc.identifier.issn0276-7333en_US
dc.identifier.urihttp://hdl.handle.net/10722/167302-
dc.description.abstractThe reaction between Ru(Me3tacn)Cl3 (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) and silver trifluoromethanesulfonate in ethanol affords a green species: treatment with cyclohexa-1,3-diene gives [Ru(Me3tacn)(η6-C6H6)] 2+ (1), while in the presence of zinc dust, reactions with 1-(trimethylsilyl)cyclopentadiene, 1-(trimethylsilyl)indene cyclohexa-13-diene, and cycloheptatriene yield [Ru(Me3tacn)(η5-C5H5)] + (2), [Ru(Me3tacn)(η5-C9H7)] + (3), [Ru(Me3-tacn)((1-5-η)-C6H7)]+ (4), and [Ru(Me3tacn)((1-5-η)-C7H9)]+ (5), respectively. X-ray diffraction studies of the [PF6]- salts of complexes 3-5 show that in each case the η5-bonded unsaturated hydrocarbon moiety is virtually planar.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_US
dc.relation.ispartofOrganometallicsen_US
dc.titleSynthesis and structural characterization of ruthenium π-arene and π-cyclodienyl complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononaneen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/om970617y-
dc.identifier.scopuseid_2-s2.0-0000797482en_US
dc.identifier.hkuros32039-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000797482&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume17en_US
dc.identifier.issue2en_US
dc.identifier.spage151en_US
dc.identifier.epage155en_US
dc.identifier.isiWOS:000071670700006-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridYang, SM=7408521494en_US
dc.identifier.scopusauthoridChan, MCW=7402598116en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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