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Article: Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide

TitleLuminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide
Authors
Issue Date1994
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1994, v. 13 n. 6-7, p. 887-890 How to Cite?
Abstract
The reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994.
Persistent Identifierhttp://hdl.handle.net/10722/167291
ISSN
2013 Impact Factor: 2.047
2013 SCImago Journal Rankings: 0.570
ISI Accession Number ID

 

Author Affiliations
  1. National Taiwan University
  2. The University of Hong Kong
DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorYip, HKen_US
dc.contributor.authorLo, WCen_US
dc.contributor.authorPeng, SMen_US
dc.date.accessioned2012-10-08T03:05:20Z-
dc.date.available2012-10-08T03:05:20Z-
dc.date.issued1994en_US
dc.identifier.citationPolyhedron, 1994, v. 13 n. 6-7, p. 887-890en_US
dc.identifier.issn0277-5387en_US
dc.identifier.urihttp://hdl.handle.net/10722/167291-
dc.description.abstractThe reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_US
dc.relation.ispartofPolyhedronen_US
dc.titleLuminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylideen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0277-5387(00)83005-3-
dc.identifier.scopuseid_2-s2.0-0000696515en_US
dc.identifier.volume13en_US
dc.identifier.issue6-7en_US
dc.identifier.spage887en_US
dc.identifier.epage890en_US
dc.identifier.isiWOS:A1994NE63500005-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridYip, HK=15068942100en_US
dc.identifier.scopusauthoridLo, WC=7201502447en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US

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