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Article: Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide
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TitleLuminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide
 
AuthorsChe, CM2
Yip, HK2
Lo, WC1
Peng, SM1
 
Issue Date1994
 
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
 
CitationPolyhedron, 1994, v. 13 n. 6-7, p. 887-890 [How to Cite?]
DOI: http://dx.doi.org/10.1016/S0277-5387(00)83005-3
 
AbstractThe reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994.
 
ISSN0277-5387
2012 Impact Factor: 1.813
2012 SCImago Journal Rankings: 0.547
 
DOIhttp://dx.doi.org/10.1016/S0277-5387(00)83005-3
 
DC FieldValue
dc.contributor.authorChe, CM
 
dc.contributor.authorYip, HK
 
dc.contributor.authorLo, WC
 
dc.contributor.authorPeng, SM
 
dc.date.accessioned2012-10-08T03:05:20Z
 
dc.date.available2012-10-08T03:05:20Z
 
dc.date.issued1994
 
dc.description.abstractThe reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994.
 
dc.description.natureLink_to_subscribed_fulltext
 
dc.identifier.citationPolyhedron, 1994, v. 13 n. 6-7, p. 887-890 [How to Cite?]
DOI: http://dx.doi.org/10.1016/S0277-5387(00)83005-3
 
dc.identifier.doihttp://dx.doi.org/10.1016/S0277-5387(00)83005-3
 
dc.identifier.epage890
 
dc.identifier.issn0277-5387
2012 Impact Factor: 1.813
2012 SCImago Journal Rankings: 0.547
 
dc.identifier.issue6-7
 
dc.identifier.scopuseid_2-s2.0-0000696515
 
dc.identifier.spage887
 
dc.identifier.urihttp://hdl.handle.net/10722/167291
 
dc.identifier.volume13
 
dc.languageeng
 
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
 
dc.publisher.placeNetherlands
 
dc.relation.ispartofPolyhedron
 
dc.titleLuminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide
 
dc.typeArticle
 
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<contributor.author>Yip, HK</contributor.author>
<contributor.author>Lo, WC</contributor.author>
<contributor.author>Peng, SM</contributor.author>
<date.accessioned>2012-10-08T03:05:20Z</date.accessioned>
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<date.issued>1994</date.issued>
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<description.abstract>The reaction of [Au(CCPh]&#8734; with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(&#956;2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(&#956;2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular Au&#267;Au separations are 3.083(2) and 3.167(2) &#197;. At room temperature, the [Au3(&#956;2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. &#169; 1994.</description.abstract>
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Author Affiliations
  1. National Taiwan University
  2. The University of Hong Kong