Article: Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide
| Title | Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide |
|---|---|
| Authors | Che, CM2 Yip, HK2 Lo, WC1 Peng, SM1 |
| Issue Date | 1994 |
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
| Citation | Polyhedron, 1994, v. 13 n. 6-7, p. 887-890 [How to Cite?] |
| Abstract | The reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994. |
| ISSN | 0277-5387 2011 Impact Factor: 2.057 2011 SCImago Journal Rankings: 0.100 |
| dc.contributor.author | Che, CM |
|---|---|
| dc.contributor.author | Yip, HK |
| dc.contributor.author | Lo, WC |
| dc.contributor.author | Peng, SM |
| dc.date.accessioned | 2012-10-08T03:05:20Z |
| dc.date.available | 2012-10-08T03:05:20Z |
| dc.date.issued | 1994 |
| dc.description.abstract | The reaction of [Au(CCPh]∞ with dppm [bis(diphenylphosphino)methane] in ethanol gave [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2]. The complex has been characterized by X-ray crystal analysis. The structure consists of a trinuclear. [Au3(μ2-dppm)2 (CCPh)2]+ cation with the three gold atoms arranged in an isosceles triangle. The intramolecular AuċAu separations are 3.083(2) and 3.167(2) Å. At room temperature, the [Au3(μ2-dppm)2(CCPh)2][Au(CCPh)2] complex is photoluminescent in the solid state and in solution. © 1994. |
| dc.description.nature | Link_to_subscribed_fulltext |
| dc.identifier.citation | Polyhedron, 1994, v. 13 n. 6-7, p. 887-890 [How to Cite?] |
| dc.identifier.epage | 890 |
| dc.identifier.issn | 0277-5387 2011 Impact Factor: 2.057 2011 SCImago Journal Rankings: 0.100 |
| dc.identifier.issue | 6-7 |
| dc.identifier.scopus | eid_2-s2.0-0000696515 |
| dc.identifier.spage | 887 |
| dc.identifier.uri | http://hdl.handle.net/10722/167291 |
| dc.identifier.volume | 13 |
| dc.language | eng |
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
| dc.publisher.place | Netherlands |
| dc.relation.ispartof | Polyhedron |
| dc.title | Luminescent metal clusters. Spectroscopic properties and X-ray structure of a trinuclear gold(I) complex containing bis(diphenylphosphino)methane and phenylacetylide |
| dc.type | Article |
Author Affiliations
- National Taiwan University
- The University of Hong Kong