File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Synthesis and electrocatalytic properties of a cis-diaquo-ruthenium(II) complex with 6,6'-dichloro-2,2'-bipyridine

TitleSynthesis and electrocatalytic properties of a cis-diaquo-ruthenium(II) complex with 6,6'-dichloro-2,2'-bipyridine
Authors
Issue Date1991
Citation
Journal Of Electroanalytical Chemistry, 1991, v. 319 n. 1-2, p. 207-216 How to Cite?
AbstractThe syntheses of cis-[RuII(6,6'-Cl2bpy)2(OH2) 2(ClO4)2, cis-[RuVI(6,6'-Cl2bpy)2]O)2] ClO4)2 and cis-[RuII(6,6'-Cl2bpy) 2(CH3CN)2](ClO4)2 ·H2O complexes are described. In 0.1 M CF3COOH, cis-[RuII (6,6'-Cl2bpy)2(OH2)2]2+ exhibits two quasi-reversible, two-electron couples at 0.93 and 1.17 V vs. SCE assignable to the cis-[RuVI(6,6'-Cl2bpy)2(O)(OH2 )]2+/cis-[RuII(6,6'-Cl 2bpy)2(OH2)2]2+ and the cis-[RuVI(6,6'-Cl2bpy)2(O)2] 2+/cis- [RuVI(6,6'-Cl2bpy)2(O)(OH2)] 2+ couples, respectively. The formal potentials of both couples shift to more negative values by 60 mV per unit pH change as the pH of the medium is raised. cis-[RuVI (6,6'-Cl2bpy)2(O)2)]2+ generated electrochemically is an active catalyst for the oxidation of alcohols, tetrahydrofuran, dextrose and chloride. Incorporation of cis-[RuII(6,6'-Cl2bpy) 2(OH2)2]2+ into Nafion® films on the electrodes produces electrodes at which the rate of oxidation of organic substrates and chloride ion is enhanced. © 1992.
Persistent Identifierhttp://hdl.handle.net/10722/167280
ISSN
2007 Impact Factor: 2.58
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWong, KYen_US
dc.contributor.authorLee, WOen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorAnson, FCen_US
dc.date.accessioned2012-10-08T03:05:11Z-
dc.date.available2012-10-08T03:05:11Z-
dc.date.issued1991en_US
dc.identifier.citationJournal Of Electroanalytical Chemistry, 1991, v. 319 n. 1-2, p. 207-216en_US
dc.identifier.issn0022-0728en_US
dc.identifier.urihttp://hdl.handle.net/10722/167280-
dc.description.abstractThe syntheses of cis-[RuII(6,6'-Cl2bpy)2(OH2) 2(ClO4)2, cis-[RuVI(6,6'-Cl2bpy)2]O)2] ClO4)2 and cis-[RuII(6,6'-Cl2bpy) 2(CH3CN)2](ClO4)2 ·H2O complexes are described. In 0.1 M CF3COOH, cis-[RuII (6,6'-Cl2bpy)2(OH2)2]2+ exhibits two quasi-reversible, two-electron couples at 0.93 and 1.17 V vs. SCE assignable to the cis-[RuVI(6,6'-Cl2bpy)2(O)(OH2 )]2+/cis-[RuII(6,6'-Cl 2bpy)2(OH2)2]2+ and the cis-[RuVI(6,6'-Cl2bpy)2(O)2] 2+/cis- [RuVI(6,6'-Cl2bpy)2(O)(OH2)] 2+ couples, respectively. The formal potentials of both couples shift to more negative values by 60 mV per unit pH change as the pH of the medium is raised. cis-[RuVI (6,6'-Cl2bpy)2(O)2)]2+ generated electrochemically is an active catalyst for the oxidation of alcohols, tetrahydrofuran, dextrose and chloride. Incorporation of cis-[RuII(6,6'-Cl2bpy) 2(OH2)2]2+ into Nafion® films on the electrodes produces electrodes at which the rate of oxidation of organic substrates and chloride ion is enhanced. © 1992.en_US
dc.languageengen_US
dc.relation.ispartofJournal of Electroanalytical Chemistryen_US
dc.titleSynthesis and electrocatalytic properties of a cis-diaquo-ruthenium(II) complex with 6,6'-dichloro-2,2'-bipyridineen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0022-0728(91)87079-J-
dc.identifier.scopuseid_2-s2.0-0000550474en_US
dc.identifier.volume319en_US
dc.identifier.issue1-2en_US
dc.identifier.spage207en_US
dc.identifier.epage216en_US
dc.identifier.isiWOS:A1991HJ07400016-
dc.identifier.scopusauthoridWong, KY=37096572700en_US
dc.identifier.scopusauthoridLee, WO=7407087172en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridAnson, FC=7006393695en_US

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats