File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: A high-symmetry coordination cage from 38- or 62-component self-assembly

TitleA high-symmetry coordination cage from 38- or 62-component self-assembly
Authors
Issue Date2012
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2012, v. 134 n. 19, p. 8042-8045 How to Cite?
Abstract
Artificial molecular architecture from a large number of subcomponents (>50) via self-assembly remains a formidable challenge for chemists. Reaction of 38 components [14 Ni 2+ and 24 N-methyl-1-(4-imidazolyl) methanimine] under solvothermal conditions reproducibly leads to the formation of a high-symmetry coordination cage. This polyhedral cage can also be obtained in high yield by self-assembly of 62 commercially available subcomponents (24 methylamine, 24 4-formylimidazole, and 14 Ni 2+) under mild conditions involving synchronized formation of both dynamic covalent bonds and coordination bonds. Guest molecules (e.g., water, methylamine, and methanol) are randomly imprisoned in the cage. © 2012 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/159409
ISSN
2013 Impact Factor: 11.444
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZhou, XPen_HK
dc.contributor.authorLiu, Jen_HK
dc.contributor.authorZhan, SZen_HK
dc.contributor.authorYang, JRen_HK
dc.contributor.authorLi, Den_HK
dc.contributor.authorNg, KMen_HK
dc.contributor.authorSun, RWYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-08-16T05:49:09Z-
dc.date.available2012-08-16T05:49:09Z-
dc.date.issued2012en_HK
dc.identifier.citationJournal Of The American Chemical Society, 2012, v. 134 n. 19, p. 8042-8045en_HK
dc.identifier.issn0002-7863en_HK
dc.identifier.urihttp://hdl.handle.net/10722/159409-
dc.description.abstractArtificial molecular architecture from a large number of subcomponents (>50) via self-assembly remains a formidable challenge for chemists. Reaction of 38 components [14 Ni 2+ and 24 N-methyl-1-(4-imidazolyl) methanimine] under solvothermal conditions reproducibly leads to the formation of a high-symmetry coordination cage. This polyhedral cage can also be obtained in high yield by self-assembly of 62 commercially available subcomponents (24 methylamine, 24 4-formylimidazole, and 14 Ni 2+) under mild conditions involving synchronized formation of both dynamic covalent bonds and coordination bonds. Guest molecules (e.g., water, methylamine, and methanol) are randomly imprisoned in the cage. © 2012 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_HK
dc.relation.ispartofJournal of the American Chemical Societyen_HK
dc.titleA high-symmetry coordination cage from 38- or 62-component self-assemblyen_HK
dc.typeArticleen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja302142cen_HK
dc.identifier.pmid22545574-
dc.identifier.scopuseid_2-s2.0-84862064854en_HK
dc.identifier.hkuros205394en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-84862064854&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume134en_HK
dc.identifier.issue19en_HK
dc.identifier.spage8042en_HK
dc.identifier.epage8045en_HK
dc.identifier.isiWOS:000304027100011-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZhou, XP=35363351900en_HK
dc.identifier.scopusauthoridLiu, J=54892160300en_HK
dc.identifier.scopusauthoridZhan, SZ=15072366500en_HK
dc.identifier.scopusauthoridYang, JR=54584693800en_HK
dc.identifier.scopusauthoridLi, D=26324923700en_HK
dc.identifier.scopusauthoridNg, KM=55015524000en_HK
dc.identifier.scopusauthoridSun, RWY=55247541200en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats