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Article: A high-symmetry coordination cage from 38- or 62-component self-assembly
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TitleA high-symmetry coordination cage from 38- or 62-component self-assembly
 
AuthorsZhou, XP2
Liu, J2
Zhan, SZ2
Yang, JR2
Li, D2
Ng, KM1
Sun, RWY1
Che, CM1
 
Issue Date2012
 
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
 
CitationJournal Of The American Chemical Society, 2012, v. 134 n. 19, p. 8042-8045 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ja302142c
 
AbstractArtificial molecular architecture from a large number of subcomponents (>50) via self-assembly remains a formidable challenge for chemists. Reaction of 38 components [14 Ni 2+ and 24 N-methyl-1-(4-imidazolyl) methanimine] under solvothermal conditions reproducibly leads to the formation of a high-symmetry coordination cage. This polyhedral cage can also be obtained in high yield by self-assembly of 62 commercially available subcomponents (24 methylamine, 24 4-formylimidazole, and 14 Ni 2+) under mild conditions involving synchronized formation of both dynamic covalent bonds and coordination bonds. Guest molecules (e.g., water, methylamine, and methanol) are randomly imprisoned in the cage. © 2012 American Chemical Society.
 
ISSN0002-7863
2013 Impact Factor: 11.444
 
DOIhttp://dx.doi.org/10.1021/ja302142c
 
ISI Accession Number IDWOS:000304027100011
 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorZhou, XP
 
dc.contributor.authorLiu, J
 
dc.contributor.authorZhan, SZ
 
dc.contributor.authorYang, JR
 
dc.contributor.authorLi, D
 
dc.contributor.authorNg, KM
 
dc.contributor.authorSun, RWY
 
dc.contributor.authorChe, CM
 
dc.date.accessioned2012-08-16T05:49:09Z
 
dc.date.available2012-08-16T05:49:09Z
 
dc.date.issued2012
 
dc.description.abstractArtificial molecular architecture from a large number of subcomponents (>50) via self-assembly remains a formidable challenge for chemists. Reaction of 38 components [14 Ni 2+ and 24 N-methyl-1-(4-imidazolyl) methanimine] under solvothermal conditions reproducibly leads to the formation of a high-symmetry coordination cage. This polyhedral cage can also be obtained in high yield by self-assembly of 62 commercially available subcomponents (24 methylamine, 24 4-formylimidazole, and 14 Ni 2+) under mild conditions involving synchronized formation of both dynamic covalent bonds and coordination bonds. Guest molecules (e.g., water, methylamine, and methanol) are randomly imprisoned in the cage. © 2012 American Chemical Society.
 
dc.description.naturelink_to_subscribed_fulltext
 
dc.identifier.citationJournal Of The American Chemical Society, 2012, v. 134 n. 19, p. 8042-8045 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ja302142c
 
dc.identifier.doihttp://dx.doi.org/10.1021/ja302142c
 
dc.identifier.epage8045
 
dc.identifier.hkuros205394
 
dc.identifier.isiWOS:000304027100011
 
dc.identifier.issn0002-7863
2013 Impact Factor: 11.444
 
dc.identifier.issue19
 
dc.identifier.pmid22545574
 
dc.identifier.scopuseid_2-s2.0-84862064854
 
dc.identifier.spage8042
 
dc.identifier.urihttp://hdl.handle.net/10722/159409
 
dc.identifier.volume134
 
dc.languageeng
 
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
 
dc.publisher.placeUnited States
 
dc.relation.ispartofJournal of the American Chemical Society
 
dc.relation.referencesReferences in Scopus
 
dc.titleA high-symmetry coordination cage from 38- or 62-component self-assembly
 
dc.typeArticle
 
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Author Affiliations
  1. The University of Hong Kong
  2. Shantou University