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Article: Molecular wheels of ruthenium and osmium with bridging chalcogenolate ligands: edge-shared-octahedron structures and metal-ion binding

TitleMolecular wheels of ruthenium and osmium with bridging chalcogenolate ligands: edge-shared-octahedron structures and metal-ion binding
Authors
KeywordsChalcogenolates
Molecular wheels
Osmium
Ruthenium
Self-assembly
Issue Date2012
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie (International Edition), 2012, v. 51 n. 11, p. 2614-2617 How to Cite?
AbstractInventing new wheels: Reaction of [M 3(CO) 12] (M=Ru, Os) with 4-RC 6H 4SH afforded [{M(S-4-RC 6H 4) 2(CO) 2} 8] (R=H; I) or [{M(S-4-RC 6H 4) 2(CO) 2} 6] (R=Me, iPr; II; see scheme), all of which have been structurally characterized. The octamers I are unique metal molecular wheels featuring skew-edge-shared octahedra with a central planar M 8 octagon. [{Ru(S-4-iPrC 6H 4) 2(CO) 2} 6] selectively binds a Cu + or Ag + ion to form [M′{Ru(S(4-iPr- C 6H 4)) 2(CO) 2} 6] + (III). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/159369
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChan, SLFen_HK
dc.contributor.authorShek, Len_HK
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorSun, RWYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-08-16T05:48:53Z-
dc.date.available2012-08-16T05:48:53Z-
dc.date.issued2012en_HK
dc.identifier.citationAngewandte Chemie (International Edition), 2012, v. 51 n. 11, p. 2614-2617en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/159369-
dc.description.abstractInventing new wheels: Reaction of [M 3(CO) 12] (M=Ru, Os) with 4-RC 6H 4SH afforded [{M(S-4-RC 6H 4) 2(CO) 2} 8] (R=H; I) or [{M(S-4-RC 6H 4) 2(CO) 2} 6] (R=Me, iPr; II; see scheme), all of which have been structurally characterized. The octamers I are unique metal molecular wheels featuring skew-edge-shared octahedra with a central planar M 8 octagon. [{Ru(S-4-iPrC 6H 4) 2(CO) 2} 6] selectively binds a Cu + or Ag + ion to form [M′{Ru(S(4-iPr- C 6H 4)) 2(CO) 2} 6] + (III). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie (International Edition)en_HK
dc.subjectChalcogenolatesen_HK
dc.subjectMolecular wheelsen_HK
dc.subjectOsmiumen_HK
dc.subjectRutheniumen_HK
dc.subjectSelf-assemblyen_HK
dc.titleMolecular wheels of ruthenium and osmium with bridging chalcogenolate ligands: edge-shared-octahedron structures and metal-ion bindingen_HK
dc.typeArticleen_HK
dc.identifier.emailChan, SLF: sharonlf@hku.hken_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.emailSun, RWY: rwysun@hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hk-
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authoritySun, RWY=rp00781en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201106065en_HK
dc.identifier.pmid22065616-
dc.identifier.scopuseid_2-s2.0-84863246381en_HK
dc.identifier.hkuros205049en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-84863246381&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume51en_HK
dc.identifier.issue11en_HK
dc.identifier.spage2614en_HK
dc.identifier.epage2617en_HK
dc.identifier.isiWOS:000301173800010-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridSun, RWY=26325835800en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridHuang, JS=54964622200en_HK
dc.identifier.scopusauthoridShek, L=55277701900en_HK
dc.identifier.scopusauthoridChan, SLF=27167455400en_HK

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