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Article: Molecular wheels of ruthenium and osmium with bridging chalcogenolate ligands: edge-shared-octahedron structures and metal-ion binding
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TitleMolecular wheels of ruthenium and osmium with bridging chalcogenolate ligands: edge-shared-octahedron structures and metal-ion binding
 
AuthorsChan, SLF1
Shek, L1
Huang, JS1
Chui, SSY1
Sun, RWY1
Che, CM1
 
KeywordsChalcogenolates
Molecular wheels
Osmium
Ruthenium
Self-assembly
 
Issue Date2012
 
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
 
CitationAngewandte Chemie (International Edition), 2012, v. 51 n. 11, p. 2614-2617 [How to Cite?]
DOI: http://dx.doi.org/10.1002/anie.201106065
 
AbstractInventing new wheels: Reaction of [M 3(CO) 12] (M=Ru, Os) with 4-RC 6H 4SH afforded [{M(S-4-RC 6H 4) 2(CO) 2} 8] (R=H; I) or [{M(S-4-RC 6H 4) 2(CO) 2} 6] (R=Me, iPr; II; see scheme), all of which have been structurally characterized. The octamers I are unique metal molecular wheels featuring skew-edge-shared octahedra with a central planar M 8 octagon. [{Ru(S-4-iPrC 6H 4) 2(CO) 2} 6] selectively binds a Cu + or Ag + ion to form [M′{Ru(S(4-iPr- C 6H 4)) 2(CO) 2} 6] + (III). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
 
ISSN1433-7851
2013 Impact Factor: 11.336
 
DOIhttp://dx.doi.org/10.1002/anie.201106065
 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorChan, SLF
 
dc.contributor.authorShek, L
 
dc.contributor.authorHuang, JS
 
dc.contributor.authorChui, SSY
 
dc.contributor.authorSun, RWY
 
dc.contributor.authorChe, CM
 
dc.date.accessioned2012-08-16T05:48:53Z
 
dc.date.available2012-08-16T05:48:53Z
 
dc.date.issued2012
 
dc.description.abstractInventing new wheels: Reaction of [M 3(CO) 12] (M=Ru, Os) with 4-RC 6H 4SH afforded [{M(S-4-RC 6H 4) 2(CO) 2} 8] (R=H; I) or [{M(S-4-RC 6H 4) 2(CO) 2} 6] (R=Me, iPr; II; see scheme), all of which have been structurally characterized. The octamers I are unique metal molecular wheels featuring skew-edge-shared octahedra with a central planar M 8 octagon. [{Ru(S-4-iPrC 6H 4) 2(CO) 2} 6] selectively binds a Cu + or Ag + ion to form [M′{Ru(S(4-iPr- C 6H 4)) 2(CO) 2} 6] + (III). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
 
dc.description.naturelink_to_subscribed_fulltext
 
dc.identifier.citationAngewandte Chemie (International Edition), 2012, v. 51 n. 11, p. 2614-2617 [How to Cite?]
DOI: http://dx.doi.org/10.1002/anie.201106065
 
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201106065
 
dc.identifier.epage2617
 
dc.identifier.hkuros205049
 
dc.identifier.issn1433-7851
2013 Impact Factor: 11.336
 
dc.identifier.issue11
 
dc.identifier.scopuseid_2-s2.0-84863246381
 
dc.identifier.spage2614
 
dc.identifier.urihttp://hdl.handle.net/10722/159369
 
dc.identifier.volume51
 
dc.languageeng
 
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
 
dc.publisher.placeGermany
 
dc.relation.ispartofAngewandte Chemie (International Edition)
 
dc.relation.referencesReferences in Scopus
 
dc.subjectChalcogenolates
 
dc.subjectMolecular wheels
 
dc.subjectOsmium
 
dc.subjectRuthenium
 
dc.subjectSelf-assembly
 
dc.titleMolecular wheels of ruthenium and osmium with bridging chalcogenolate ligands: edge-shared-octahedron structures and metal-ion binding
 
dc.typeArticle
 
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<item><contributor.author>Chan, SLF</contributor.author>
<contributor.author>Shek, L</contributor.author>
<contributor.author>Huang, JS</contributor.author>
<contributor.author>Chui, SSY</contributor.author>
<contributor.author>Sun, RWY</contributor.author>
<contributor.author>Che, CM</contributor.author>
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<description.abstract>Inventing new wheels: Reaction of [M 3(CO) 12] (M=Ru, Os) with 4-RC 6H 4SH afforded [{M(S-4-RC 6H 4) 2(CO) 2} 8] (R=H; I) or [{M(S-4-RC 6H 4) 2(CO) 2} 6] (R=Me, iPr; II; see scheme), all of which have been structurally characterized. The octamers I are unique metal molecular wheels featuring skew-edge-shared octahedra with a central planar M 8 octagon. [{Ru(S-4-iPrC 6H 4) 2(CO) 2} 6] selectively binds a Cu + or Ag + ion to form [M&#8242;{Ru(S(4-iPr- C 6H 4)) 2(CO) 2} 6] + (III). Copyright &#169; 2012 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.</description.abstract>
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Author Affiliations
  1. The University of Hong Kong