Article: Luminescent organogold(III) complexes with long-lived triplet excited states for light-induced oxidative C-H bond functionalization and hydrogen production

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TitleLuminescent organogold(III) complexes with long-lived triplet excited states for light-induced oxidative C-H bond functionalization and hydrogen production
AuthorsTo, WP1
Tong, GSM1
Lu, W1 2
Ma, C1
Liu, J1
Chow, ALF1
Che, CM1
KeywordsGold
Hydrogen production
Luminescence
N-heterocyclic carbenes
Photooxidation
Issue Date2012
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
CitationAngewandte Chemie (International Edition), 2012, v. 51 n. 11, p. 2654-2657 [How to Cite?]
DOI: http://dx.doi.org/10.1002/anie.201108080
AbstractAll that glitters is gold: Highly phosphorescent gold(III) complexes (see picture) with extended π-conjugated cyclometalating ligands exhibit rich photophysical and photochemical properties. They act as efficient photocatalysts/photosensitizers for oxidative functionalizations of secondary and tertiary benzylic amines and homogeneous hydrogen production from a water/acetonitrile mixture. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
ISSN1433-7851
2011 Impact Factor: 13.455
DOIhttp://dx.doi.org/10.1002/anie.201108080
ISI Accession Number IDWOS:000301173800020
ReferencesReferences in Scopus
DC Field
Value
dc.contributor.authorTo, WP
dc.contributor.authorTong, GSM
dc.contributor.authorLu, W
dc.contributor.authorMa, C
dc.contributor.authorLiu, J
dc.contributor.authorChow, ALF
dc.contributor.authorChe, CM
dc.date.accessioned2012-08-16T05:48:52Z
dc.date.available2012-08-16T05:48:52Z
dc.date.issued2012
dc.description.abstractAll that glitters is gold: Highly phosphorescent gold(III) complexes (see picture) with extended π-conjugated cyclometalating ligands exhibit rich photophysical and photochemical properties. They act as efficient photocatalysts/photosensitizers for oxidative functionalizations of secondary and tertiary benzylic amines and homogeneous hydrogen production from a water/acetonitrile mixture. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.natureLink_to_subscribed_fulltext
dc.identifier.citationAngewandte Chemie (International Edition), 2012, v. 51 n. 11, p. 2654-2657 [How to Cite?]
DOI: http://dx.doi.org/10.1002/anie.201108080
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201108080
dc.identifier.epage2657
dc.identifier.hkuros204832
dc.identifier.isiWOS:000301173800020
dc.identifier.issn1433-7851
2011 Impact Factor: 13.455
dc.identifier.issue11
dc.identifier.pmid22308117
dc.identifier.scopuseid_2-s2.0-84863230421
dc.identifier.spage2654
dc.identifier.urihttp://hdl.handle.net/10722/159364
dc.identifier.volume51
dc.languageeng
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
dc.publisher.placeGermany
dc.relation.ispartofAngewandte Chemie (International Edition)
dc.relation.referencesReferences in Scopus
dc.subject.meshWater - chemistry
dc.subject.meshQuantum theory
dc.subject.meshOxidation-reduction
dc.subject.meshOrganogold compounds - chemistry
dc.subject.meshLuminescent measurements
dc.subject.meshLight
dc.subject.meshHydrogen - metabolism
dc.subject.meshGold - chemistry
dc.subject.meshCoordination complexes - chemistry
dc.subject.meshCarbon - chemistry
dc.subject.meshAcetone - chemistry
dc.subjectGold
dc.subjectHydrogen production
dc.subjectLuminescence
dc.subjectN-heterocyclic carbenes
dc.subjectPhotooxidation
dc.titleLuminescent organogold(III) complexes with long-lived triplet excited states for light-induced oxidative C-H bond functionalization and hydrogen production
dc.typeArticle
Author Affiliations
  1. The University of Hong Kong
  2. University of Science and Technology of China