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Article: Metal-free intramolecular aziridination of allylic carbamates mediated by hypervalent iodine compounds

TitleMetal-free intramolecular aziridination of allylic carbamates mediated by hypervalent iodine compounds
Authors
Keywordsallylic carbamate
aziridination
hypervalent iodine
ring opening
vicinal diamine
Issue Date2011
PublisherGeorg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.com
Citation
Synthesis, 2011 n. 18, p. 2959-2967 How to Cite?
AbstractAn efficient and practical hypervalent iodine compound mediated metal-free intramolecular aziridination reaction of allylic carbamates was developed. Analytically pure aziridines were obtained in high yields by simple filtration of the reaction mixture. In situ ring opening of the aziridines provides an easy access to useful vicinal amino alcohol derivatives and diamine compounds. Up to 16% ee was obtained when chiral hypervalent iodine compound was used. © Georg Thieme Verlag Stuttgart - New York.
Persistent Identifierhttp://hdl.handle.net/10722/159343
ISSN
2015 Impact Factor: 2.652
2015 SCImago Journal Rankings: 1.115
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorDeng, QHen_HK
dc.contributor.authorWang, JCen_HK
dc.contributor.authorXu, ZJen_HK
dc.contributor.authorZhou, CYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-08-16T05:48:46Z-
dc.date.available2012-08-16T05:48:46Z-
dc.date.issued2011en_HK
dc.identifier.citationSynthesis, 2011 n. 18, p. 2959-2967en_HK
dc.identifier.issn0039-7881en_HK
dc.identifier.urihttp://hdl.handle.net/10722/159343-
dc.description.abstractAn efficient and practical hypervalent iodine compound mediated metal-free intramolecular aziridination reaction of allylic carbamates was developed. Analytically pure aziridines were obtained in high yields by simple filtration of the reaction mixture. In situ ring opening of the aziridines provides an easy access to useful vicinal amino alcohol derivatives and diamine compounds. Up to 16% ee was obtained when chiral hypervalent iodine compound was used. © Georg Thieme Verlag Stuttgart - New York.en_HK
dc.languageengen_US
dc.publisherGeorg Thieme Verlag. The Journal's web site is located at www.thieme-chemistry.comen_HK
dc.relation.ispartofSynthesisen_HK
dc.subjectallylic carbamateen_HK
dc.subjectaziridinationen_HK
dc.subjecthypervalent iodineen_HK
dc.subjectring openingen_HK
dc.subjectvicinal diamineen_HK
dc.titleMetal-free intramolecular aziridination of allylic carbamates mediated by hypervalent iodine compoundsen_HK
dc.typeArticleen_HK
dc.identifier.emailZhou, CY:cyzhou@hku.hken_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityZhou, CY=rp00843en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1055/s-0030-1260150en_HK
dc.identifier.scopuseid_2-s2.0-80052662989en_HK
dc.identifier.hkuros204506en_US
dc.identifier.hkuros205248-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-80052662989&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue18en_HK
dc.identifier.spage2959en_HK
dc.identifier.epage2967en_HK
dc.identifier.isiWOS:000295686400012-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridDeng, QH=8987982900en_HK
dc.identifier.scopusauthoridWang, JC=52464857400en_HK
dc.identifier.scopusauthoridXu, ZJ=50162911000en_HK
dc.identifier.scopusauthoridZhou, CY=35742480200en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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