File Download
 
Links for fulltext
(May Require Subscription)
 
Supplementary

Article: Catena-poly[[diaquacalcium]bis-[μ-2-(1,3-dioxoisoindolin-2-yl)acetato] -κ 3 O,O′:O;κ 3O:O,O′]
  • Basic View
  • Metadata View
  • XML View
TitleCatena-poly[[diaquacalcium]bis-[μ-2-(1,3-dioxoisoindolin-2-yl)acetato] -κ 3 O,O′:O;κ 3O:O,O′]
 
AuthorsBhatti, MH2
Yunus, U2
Saeed, S2
Shah, SR2
Wong, WT1
 
Keywordsdata-to-parameter ratio = 14.6
disorder in main residue
mean σ(CC) = 0.003 Å
R factor = 0.036
single-crystal X-ray study
T = 296 K
wR factor = 0.102
 
Issue Date2011
 
PublisherInternational Union of Crystallography. The Journal's web site is located at http://journals.iucr.org/e/journalhomepage.html
 
CitationActa Crystallographica Section E: Structure Reports Online, 2011, v. 67 n. 8, p. m1102-m1103 [How to Cite?]
DOI: http://dx.doi.org/10.1107/S1600536811027851
 
AbstractIn the title complex, [Ca(C 10H 6NO 4) 2(H 2O) 2] n , the Ca II atom lies on a twofold rotation axis and adopts a dodeca-hedral geometry. The Ca II atom is octa-coordinated by two O atoms from two water molecules and six O atoms from four acetate ligands. Each acetate acts as a tridentate ligand bridging two Ca II atoms, resulting in a chain running along the c axis. O - H⋯O and C - H⋯O hydrogen bonds connect the chains into a two-dimensional network parallel to [011]. π-π interactions between adjacent isoindoline-1,3-dione rings [centroid-centroid distance = 3.4096 (11) Å] further consolidate the structure. One of the carboxylate O atoms is disordered over two sites in a 0.879 (12):0.121 (12) ratio.
 
ISSN1600-5368
2013 SCImago Journal Rankings: 0.227
 
DOIhttp://dx.doi.org/10.1107/S1600536811027851
 
PubMed Central IDPMC3212173
 
ISI Accession Number IDWOS:000294613900069
 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorBhatti, MH
 
dc.contributor.authorYunus, U
 
dc.contributor.authorSaeed, S
 
dc.contributor.authorShah, SR
 
dc.contributor.authorWong, WT
 
dc.date.accessioned2012-08-16T05:48:41Z
 
dc.date.available2012-08-16T05:48:41Z
 
dc.date.issued2011
 
dc.description.abstractIn the title complex, [Ca(C 10H 6NO 4) 2(H 2O) 2] n , the Ca II atom lies on a twofold rotation axis and adopts a dodeca-hedral geometry. The Ca II atom is octa-coordinated by two O atoms from two water molecules and six O atoms from four acetate ligands. Each acetate acts as a tridentate ligand bridging two Ca II atoms, resulting in a chain running along the c axis. O - H⋯O and C - H⋯O hydrogen bonds connect the chains into a two-dimensional network parallel to [011]. π-π interactions between adjacent isoindoline-1,3-dione rings [centroid-centroid distance = 3.4096 (11) Å] further consolidate the structure. One of the carboxylate O atoms is disordered over two sites in a 0.879 (12):0.121 (12) ratio.
 
dc.description.naturepublished_or_final_version
 
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online, 2011, v. 67 n. 8, p. m1102-m1103 [How to Cite?]
DOI: http://dx.doi.org/10.1107/S1600536811027851
 
dc.identifier.citeulike9569790
 
dc.identifier.doihttp://dx.doi.org/10.1107/S1600536811027851
 
dc.identifier.epagem1103
 
dc.identifier.hkuros203948
 
dc.identifier.isiWOS:000294613900069
 
dc.identifier.issn1600-5368
2013 SCImago Journal Rankings: 0.227
 
dc.identifier.issue8
 
dc.identifier.pmcidPMC3212173
 
dc.identifier.pmid22090875
 
dc.identifier.scopuseid_2-s2.0-80051533183
 
dc.identifier.spagem1102
 
dc.identifier.urihttp://hdl.handle.net/10722/159327
 
dc.identifier.volume67
 
dc.languageeng
 
dc.publisherInternational Union of Crystallography. The Journal's web site is located at http://journals.iucr.org/e/journalhomepage.html
 
dc.publisher.placeUnited States
 
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Online
 
dc.relation.referencesReferences in Scopus
 
dc.rightsThe definitive version is available at www.blackwell-synergy.com
 
dc.rightsCreative Commons: Attribution 3.0 Hong Kong License
 
dc.subjectdata-to-parameter ratio = 14.6
 
dc.subjectdisorder in main residue
 
dc.subjectmean σ(CC) = 0.003 Å
 
dc.subjectR factor = 0.036
 
dc.subjectsingle-crystal X-ray study
 
dc.subjectT = 296 K
 
dc.subjectwR factor = 0.102
 
dc.titleCatena-poly[[diaquacalcium]bis-[μ-2-(1,3-dioxoisoindolin-2-yl)acetato] -κ 3 O,O′:O;κ 3O:O,O′]
 
dc.typeArticle
 
<?xml encoding="utf-8" version="1.0"?>
<item><contributor.author>Bhatti, MH</contributor.author>
<contributor.author>Yunus, U</contributor.author>
<contributor.author>Saeed, S</contributor.author>
<contributor.author>Shah, SR</contributor.author>
<contributor.author>Wong, WT</contributor.author>
<date.accessioned>2012-08-16T05:48:41Z</date.accessioned>
<date.available>2012-08-16T05:48:41Z</date.available>
<date.issued>2011</date.issued>
<identifier.citation>Acta Crystallographica Section E: Structure Reports Online, 2011, v. 67 n. 8, p. m1102-m1103</identifier.citation>
<identifier.issn>1600-5368</identifier.issn>
<identifier.uri>http://hdl.handle.net/10722/159327</identifier.uri>
<description.abstract>In the title complex, [Ca(C 10H 6NO 4) 2(H 2O) 2] n , the Ca II atom lies on a twofold rotation axis and adopts a dodeca-hedral geometry. The Ca II atom is octa-coordinated by two O atoms from two water molecules and six O atoms from four acetate ligands. Each acetate acts as a tridentate ligand bridging two Ca II atoms, resulting in a chain running along the c axis. O - H&#8943;O and C - H&#8943;O hydrogen bonds connect the chains into a two-dimensional network parallel to [011]. &#960;-&#960; interactions between adjacent isoindoline-1,3-dione rings [centroid-centroid distance = 3.4096 (11) &#197;] further consolidate the structure. One of the carboxylate O atoms is disordered over two sites in a 0.879 (12):0.121 (12) ratio.</description.abstract>
<language>eng</language>
<publisher>International Union of Crystallography. The Journal&apos;s web site is located at http://journals.iucr.org/e/journalhomepage.html</publisher>
<relation.ispartof>Acta Crystallographica Section E: Structure Reports Online</relation.ispartof>
<rights>The definitive version is available at www.blackwell-synergy.com</rights>
<rights>Creative Commons: Attribution 3.0 Hong Kong License</rights>
<subject>data-to-parameter ratio = 14.6</subject>
<subject>disorder in main residue</subject>
<subject>mean &#963;(CC) = 0.003 &#197;</subject>
<subject>R factor = 0.036</subject>
<subject>single-crystal X-ray study</subject>
<subject>T = 296 K</subject>
<subject>wR factor = 0.102</subject>
<title>Catena-poly[[diaquacalcium]bis-[&#956;-2-(1,3-dioxoisoindolin-2-yl)acetato] -&#954; 3 O,O&#8242;:O;&#954; 3O:O,O&#8242;]</title>
<type>Article</type>
<description.nature>published_or_final_version</description.nature>
<identifier.doi>10.1107/S1600536811027851</identifier.doi>
<identifier.pmid>22090875</identifier.pmid>
<identifier.pmcid>PMC3212173</identifier.pmcid>
<identifier.scopus>eid_2-s2.0-80051533183</identifier.scopus>
<identifier.hkuros>203948</identifier.hkuros>
<relation.references>http://www.scopus.com/mlt/select.url?eid=2-s2.0-80051533183&amp;selection=ref&amp;src=s&amp;origin=recordpage</relation.references>
<identifier.volume>67</identifier.volume>
<identifier.issue>8</identifier.issue>
<identifier.spage>m1102</identifier.spage>
<identifier.epage>m1103</identifier.epage>
<identifier.isi>WOS:000294613900069</identifier.isi>
<publisher.place>United States</publisher.place>
<identifier.citeulike>9569790</identifier.citeulike>
<bitstream.url>http://hub.hku.hk/bitstream/10722/159327/1/content.pdf</bitstream.url>
</item>
Author Affiliations
  1. The University of Hong Kong
  2. Allama Iqbal Open University