Article: Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

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TitleNovel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network
AuthorsWang, H3
Szeto, L1
Chan, WTK3
Yeung, HL3
Wong, KL2
Wong, WT3
Keywords1,2-bis(4-pyridyl)hydrazine
Coordination polymer
Hydrogen bond
Interpenetrating polymer
Metal organic framework
Microporous
Issue Date2012
PublisherN R C Research Press. The Journal's web site is located at http://pubs.nrc-cnrc.gc.ca/cgi-bin/rp/rp2_desc_e?cjc
CitationCanadian Journal Of Chemistry, 2012, v. 90 n. 1, p. 100-107 [How to Cite?]
DOI: http://dx.doi.org/10.1139/v11-132
AbstractTwo MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell. © 2011 Published by NRC Research Press.
ISSN0008-4042
2011 Impact Factor: 1.242
2011 SCImago Journal Rankings: 0.098
DOIhttp://dx.doi.org/10.1139/v11-132
ReferencesReferences in Scopus
DC Field
Value
dc.contributor.authorWang, H
dc.contributor.authorSzeto, L
dc.contributor.authorChan, WTK
dc.contributor.authorYeung, HL
dc.contributor.authorWong, KL
dc.contributor.authorWong, WT
dc.date.accessioned2012-08-16T05:48:39Z
dc.date.available2012-08-16T05:48:39Z
dc.date.issued2012
dc.description.abstractTwo MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell. © 2011 Published by NRC Research Press.
dc.description.natureLink_to_subscribed_fulltext
dc.identifier.citationCanadian Journal Of Chemistry, 2012, v. 90 n. 1, p. 100-107 [How to Cite?]
DOI: http://dx.doi.org/10.1139/v11-132
dc.identifier.doihttp://dx.doi.org/10.1139/v11-132
dc.identifier.epage107
dc.identifier.hkuros203850
dc.identifier.issn0008-4042
2011 Impact Factor: 1.242
2011 SCImago Journal Rankings: 0.098
dc.identifier.issue1
dc.identifier.scopuseid_2-s2.0-84855421542
dc.identifier.spage100
dc.identifier.urihttp://hdl.handle.net/10722/159324
dc.identifier.volume90
dc.languageeng
dc.publisherN R C Research Press. The Journal's web site is located at http://pubs.nrc-cnrc.gc.ca/cgi-bin/rp/rp2_desc_e?cjc
dc.publisher.placeCanada
dc.relation.ispartofCanadian Journal of Chemistry
dc.relation.referencesReferences in Scopus
dc.rightsCanadian Journal of Chemistry. Copyright © NRC Research Press.
dc.subject1,2-bis(4-pyridyl)hydrazine
dc.subjectCoordination polymer
dc.subjectHydrogen bond
dc.subjectInterpenetrating polymer
dc.subjectMetal organic framework
dc.subjectMicroporous
dc.titleNovel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network
dc.typeArticle
Author Affiliations
  1. The University of Hong Kong
  2. Hong Kong Baptist University
  3. Hong Kong Polytechnic University