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Article: Metal-free and metallated polymers: Properties and photovoltaic performance
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TitleMetal-free and metallated polymers: Properties and photovoltaic performance
 
AuthorsNg, A1
Ho, CL4
Fung, MK1
Sun, YC1
Shao, SY2
Fu, YY2
Ng, AMC1 3
Li, CH1
Cheung, WK1
Leung, YH1
Djurišić, AB1
Wang, Q4
He, Z4
Wang, X4
Chan, WK1
Xie, ZY2
Zapien, JA5
To, CH5
Wong, WY4
 
KeywordsAlkyne
Metallopolymer
Photovoltaics
Solar cell
Transition metal
 
Issue Date2012
 
PublisherWiley-VCH Verlag GmbH & Co. KGaA.
 
CitationMacromolecular Chemistry And Physics, 2012, v. 213 n. 13, p. 1300-1310 [How to Cite?]
DOI: http://dx.doi.org/10.1002/macp.201100686
 
AbstractWe have studied the properties of organic and organometallic polymers based on a similar chemical structure to elucidate the influence of the metal center on the optical and electronic properties of the polymers as well as their photovoltaic performance. Detailed characterization of the optical properties of both polymers is performed and film morphology and photovoltaic performance are compared. Metal-containing polymers exhibit red-shifted absorption and under optimal processing conditions exhibit different film morphology compared with the metal-free ones. Our results indicate that organometallic polymers represent a promising class of compounds for improved performance in photovoltaic cells. Full Paper: Optical and photovoltaic properties of Pt-containing (P1) and metal-free (P1 MF) polymers with similar structures are investigated (see Figure). It is found that incorporation of metal results not only in an additional absorption band but also results in changes in the film morphology and phase separation, and hence a significant improvement in the photovoltaic performance. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
 
ISSN1022-1352
2012 Impact Factor: 2.386
2012 SCImago Journal Rankings: 0.879
 
DOIhttp://dx.doi.org/10.1002/macp.201100686
 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorNg, A
 
dc.contributor.authorHo, CL
 
dc.contributor.authorFung, MK
 
dc.contributor.authorSun, YC
 
dc.contributor.authorShao, SY
 
dc.contributor.authorFu, YY
 
dc.contributor.authorNg, AMC
 
dc.contributor.authorLi, CH
 
dc.contributor.authorCheung, WK
 
dc.contributor.authorLeung, YH
 
dc.contributor.authorDjurišić, AB
 
dc.contributor.authorWang, Q
 
dc.contributor.authorHe, Z
 
dc.contributor.authorWang, X
 
dc.contributor.authorChan, WK
 
dc.contributor.authorXie, ZY
 
dc.contributor.authorZapien, JA
 
dc.contributor.authorTo, CH
 
dc.contributor.authorWong, WY
 
dc.date.accessioned2012-08-16T05:48:24Z
 
dc.date.available2012-08-16T05:48:24Z
 
dc.date.issued2012
 
dc.description.abstractWe have studied the properties of organic and organometallic polymers based on a similar chemical structure to elucidate the influence of the metal center on the optical and electronic properties of the polymers as well as their photovoltaic performance. Detailed characterization of the optical properties of both polymers is performed and film morphology and photovoltaic performance are compared. Metal-containing polymers exhibit red-shifted absorption and under optimal processing conditions exhibit different film morphology compared with the metal-free ones. Our results indicate that organometallic polymers represent a promising class of compounds for improved performance in photovoltaic cells. Full Paper: Optical and photovoltaic properties of Pt-containing (P1) and metal-free (P1 MF) polymers with similar structures are investigated (see Figure). It is found that incorporation of metal results not only in an additional absorption band but also results in changes in the film morphology and phase separation, and hence a significant improvement in the photovoltaic performance. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
 
dc.description.natureLink_to_subscribed_fulltext
 
dc.identifier.citationMacromolecular Chemistry And Physics, 2012, v. 213 n. 13, p. 1300-1310 [How to Cite?]
DOI: http://dx.doi.org/10.1002/macp.201100686
 
dc.identifier.doihttp://dx.doi.org/10.1002/macp.201100686
 
dc.identifier.epage1310
 
dc.identifier.hkuros202444
 
dc.identifier.issn1022-1352
2012 Impact Factor: 2.386
2012 SCImago Journal Rankings: 0.879
 
dc.identifier.issue13
 
dc.identifier.scopuseid_2-s2.0-84863649272
 
dc.identifier.spage1300
 
dc.identifier.urihttp://hdl.handle.net/10722/159286
 
dc.identifier.volume213
 
dc.languageeng
 
dc.publisherWiley-VCH Verlag GmbH & Co. KGaA.
 
dc.publisher.placeGermany
 
dc.relation.ispartofMacromolecular Chemistry and Physics
 
dc.relation.referencesReferences in Scopus
 
dc.subjectAlkyne
 
dc.subjectMetallopolymer
 
dc.subjectPhotovoltaics
 
dc.subjectSolar cell
 
dc.subjectTransition metal
 
dc.titleMetal-free and metallated polymers: Properties and photovoltaic performance
 
dc.typeArticle
 
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<description.abstract>We have studied the properties of organic and organometallic polymers based on a similar chemical structure to elucidate the influence of the metal center on the optical and electronic properties of the polymers as well as their photovoltaic performance. Detailed characterization of the optical properties of both polymers is performed and film morphology and photovoltaic performance are compared. Metal-containing polymers exhibit red-shifted absorption and under optimal processing conditions exhibit different film morphology compared with the metal-free ones. Our results indicate that organometallic polymers represent a promising class of compounds for improved performance in photovoltaic cells. Full Paper: Optical and photovoltaic properties of Pt-containing (P1) and metal-free (P1 MF) polymers with similar structures are investigated (see Figure). It is found that incorporation of metal results not only in an additional absorption band but also results in changes in the film morphology and phase separation, and hence a significant improvement in the photovoltaic performance. Copyright &#169; 2012 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.</description.abstract>
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Author Affiliations
  1. The University of Hong Kong
  2. Changchun Institute of Applied Chemistry Chinese Academy of Sciences
  3. University of Science and Technology of China
  4. Hong Kong Baptist University
  5. City University of Hong Kong