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Article: The electronic structure of trifluorophosphine studied by photoelectron spectroscopy with variable photon energy

TitleThe electronic structure of trifluorophosphine studied by photoelectron spectroscopy with variable photon energy
Authors
Issue Date1991
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1991 n. 9, p. 2371-2375 How to Cite?
AbstractThe photoelectron spectrum of PF3 has been measured using synchrotron radiation. Relative partial photoionization cross-section and branching ratio data are reported for the valence bands (8-24 eV) over the photon-energy range 30-95 eV. Molecular orbitals regarded previously as purely fluorine lone pair in composition are shown to have significant phosphorus 3p character. Comparison of the results obtained on PF3 with those obtained previously on [Ni(PF3)4] shows that the complex molecular orbitals of the latter derived from the 5e orbitals of PF3 have some nickel 3d character. Metal-to-phosphorus back donation, proposed to occur through the 7e PF3 molecular orbitals, is thus shown also to involve the 5e.
Persistent Identifierhttp://hdl.handle.net/10722/157498
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorGreen, JCen_US
dc.contributor.authorKaltsoyannis, Nen_US
dc.contributor.authorSze, KHen_US
dc.contributor.authorMacdonald, MAen_US
dc.date.accessioned2012-08-08T08:50:35Z-
dc.date.available2012-08-08T08:50:35Z-
dc.date.issued1991en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1991 n. 9, p. 2371-2375en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/157498-
dc.description.abstractThe photoelectron spectrum of PF3 has been measured using synchrotron radiation. Relative partial photoionization cross-section and branching ratio data are reported for the valence bands (8-24 eV) over the photon-energy range 30-95 eV. Molecular orbitals regarded previously as purely fluorine lone pair in composition are shown to have significant phosphorus 3p character. Comparison of the results obtained on PF3 with those obtained previously on [Ni(PF3)4] shows that the complex molecular orbitals of the latter derived from the 5e orbitals of PF3 have some nickel 3d character. Metal-to-phosphorus back donation, proposed to occur through the 7e PF3 molecular orbitals, is thus shown also to involve the 5e.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleThe electronic structure of trifluorophosphine studied by photoelectron spectroscopy with variable photon energyen_US
dc.typeArticleen_US
dc.identifier.emailSze, KH:khsze@hku.hken_US
dc.identifier.authoritySze, KH=rp00785en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9910002371en_US
dc.identifier.scopuseid_2-s2.0-37049070264en_US
dc.identifier.issue9en_US
dc.identifier.spage2371en_US
dc.identifier.epage2375en_US
dc.identifier.isiWOS:A1991GF28400022-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridGreen, JC=7404572278en_US
dc.identifier.scopusauthoridKaltsoyannis, N=7004509648en_US
dc.identifier.scopusauthoridSze, KH=7006735061en_US
dc.identifier.scopusauthoridMacDonald, MA=7401502193en_US

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