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Article: An investigation of the electronic structure of osmium tetroxide by photoelectron spectroscopy with variable photon energy

TitleAn investigation of the electronic structure of osmium tetroxide by photoelectron spectroscopy with variable photon energy
Authors
Issue Date1990
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1990, v. 175 n. 4, p. 359-363 How to Cite?
AbstractRelative partial photoionization cross sections and photoelectron branching ratios have been obtained for the valence bands of osmium tetroxide in the ionization energy range 12 to 18 eV. The photon energies used ranged between 24 and 100 eV. The ionization cross sections of the 2t 2 and 2a 1 orbitals show evidence or substantial metal character establishing strong Os-O σ-bonding. Very little evidence is found for π-bonding. © 1990.
Persistent Identifierhttp://hdl.handle.net/10722/157387
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757

 

DC FieldValueLanguage
dc.contributor.authorGreen, JCen_US
dc.contributor.authorKaltsoyannis, Nen_US
dc.contributor.authorSze, KHen_US
dc.contributor.authorMacdonald, MAen_US
dc.date.accessioned2012-08-08T08:49:33Z-
dc.date.available2012-08-08T08:49:33Z-
dc.date.issued1990en_US
dc.identifier.citationChemical Physics Letters, 1990, v. 175 n. 4, p. 359-363en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://hdl.handle.net/10722/157387-
dc.description.abstractRelative partial photoionization cross sections and photoelectron branching ratios have been obtained for the valence bands of osmium tetroxide in the ionization energy range 12 to 18 eV. The photon energies used ranged between 24 and 100 eV. The ionization cross sections of the 2t 2 and 2a 1 orbitals show evidence or substantial metal character establishing strong Os-O σ-bonding. Very little evidence is found for π-bonding. © 1990.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_US
dc.relation.ispartofChemical Physics Lettersen_US
dc.titleAn investigation of the electronic structure of osmium tetroxide by photoelectron spectroscopy with variable photon energyen_US
dc.typeArticleen_US
dc.identifier.emailSze, KH:khsze@hku.hken_US
dc.identifier.authoritySze, KH=rp00785en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-10844288360en_US
dc.identifier.volume175en_US
dc.identifier.issue4en_US
dc.identifier.spage359en_US
dc.identifier.epage363en_US
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridGreen, JC=7404572278en_US
dc.identifier.scopusauthoridKaltsoyannis, N=7004509648en_US
dc.identifier.scopusauthoridSze, KH=7006735061en_US
dc.identifier.scopusauthoridMacDonald, MA=7401502193en_US

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