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Article: Inner and valence shell electronic excitation of dimethyl sulfoxide by electron energy loss and photoabsorption spectroscopies

TitleInner and valence shell electronic excitation of dimethyl sulfoxide by electron energy loss and photoabsorption spectroscopies
Authors
Issue Date1988
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/chemphys
Citation
Chemical Physics, 1988, v. 121 n. 2, p. 279-297 How to Cite?
AbstractThe electronic excitation spectra of all inner shells and the valence shell of dimethyl sulfoxide (DMSO) have been measured using electron energy loss spectroscopy (S 2s, 2p, O 1s, C 1s and valence shell) and synchrotron radiation photoabsorption (S 1s). The spectra in the pre-edge regions are interpreted as excitations to virtual valence and Rydberg orbitals. A linear correlation between the SC bond lengths and the term values of S 2p 3 2 → σ* (SC) transitions is demonstrated for DMSO and other sulfur compounds. © 1988.
Persistent Identifierhttp://hdl.handle.net/10722/157231
ISSN
2015 Impact Factor: 1.758
2015 SCImago Journal Rankings: 0.719

 

DC FieldValueLanguage
dc.contributor.authorSze, KHen_US
dc.contributor.authorBrion, CEen_US
dc.contributor.authorTronc, Men_US
dc.contributor.authorBodeur, Sen_US
dc.contributor.authorHitchcock, APen_US
dc.date.accessioned2012-08-08T08:48:17Z-
dc.date.available2012-08-08T08:48:17Z-
dc.date.issued1988en_US
dc.identifier.citationChemical Physics, 1988, v. 121 n. 2, p. 279-297en_US
dc.identifier.issn0301-0104en_US
dc.identifier.urihttp://hdl.handle.net/10722/157231-
dc.description.abstractThe electronic excitation spectra of all inner shells and the valence shell of dimethyl sulfoxide (DMSO) have been measured using electron energy loss spectroscopy (S 2s, 2p, O 1s, C 1s and valence shell) and synchrotron radiation photoabsorption (S 1s). The spectra in the pre-edge regions are interpreted as excitations to virtual valence and Rydberg orbitals. A linear correlation between the SC bond lengths and the term values of S 2p 3 2 → σ* (SC) transitions is demonstrated for DMSO and other sulfur compounds. © 1988.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/chemphysen_US
dc.relation.ispartofChemical Physicsen_US
dc.titleInner and valence shell electronic excitation of dimethyl sulfoxide by electron energy loss and photoabsorption spectroscopiesen_US
dc.typeArticleen_US
dc.identifier.emailSze, KH:khsze@hku.hken_US
dc.identifier.authoritySze, KH=rp00785en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-0001707663en_US
dc.identifier.volume121en_US
dc.identifier.issue2en_US
dc.identifier.spage279en_US
dc.identifier.epage297en_US
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridSze, KH=7006735061en_US
dc.identifier.scopusauthoridBrion, CE=7006196884en_US
dc.identifier.scopusauthoridTronc, M=6603957797en_US
dc.identifier.scopusauthoridBodeur, S=12765409300en_US
dc.identifier.scopusauthoridHitchcock, AP=7005567890en_US

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