File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Scopus: eid_2-s2.0-0000962888
- WOS: WOS:A1989AV95300034
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Inner shell and valence shell electronic excitation of ClF3 by high energy electron impact. An investigation of potential barrier effects
Title | Inner shell and valence shell electronic excitation of ClF3 by high energy electron impact. An investigation of potential barrier effects |
---|---|
Authors | |
Issue Date | 1989 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/chemphys |
Citation | Chemical Physics, 1989, v. 137 n. 1-3, p. 353-367 How to Cite? |
Abstract | Inner shell (Cl 2p, 2s and F 1s) and valence shell electron energy loss spectra of ClF3 have been measured under conditions of high impact energy (3-3.7 keV) and zero degree scattering angle. The Coulombic potential barrier model is found to provide an extremely satisfactory understanding of (a) the co-existence in ClF3 of intense shape resonances and also intense Rydberg transitions plus direct ionization; and (b) the number and symmetry of the continuum shape resonances observed in the ISEELS spectra of ClF3. The physical significance of the Coulombic potential barrier is further demonstrated in a comparison of the central atom inner shell spectra of SF6, ClF3 and HCl. © 1989. |
Persistent Identifier | http://hdl.handle.net/10722/157227 |
ISSN | 2023 Impact Factor: 2.0 2023 SCImago Journal Rankings: 0.439 |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sze, KH | en_US |
dc.contributor.author | Brion, CE | en_US |
dc.date.accessioned | 2012-08-08T08:48:15Z | - |
dc.date.available | 2012-08-08T08:48:15Z | - |
dc.date.issued | 1989 | en_US |
dc.identifier.citation | Chemical Physics, 1989, v. 137 n. 1-3, p. 353-367 | en_US |
dc.identifier.issn | 0301-0104 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/157227 | - |
dc.description.abstract | Inner shell (Cl 2p, 2s and F 1s) and valence shell electron energy loss spectra of ClF3 have been measured under conditions of high impact energy (3-3.7 keV) and zero degree scattering angle. The Coulombic potential barrier model is found to provide an extremely satisfactory understanding of (a) the co-existence in ClF3 of intense shape resonances and also intense Rydberg transitions plus direct ionization; and (b) the number and symmetry of the continuum shape resonances observed in the ISEELS spectra of ClF3. The physical significance of the Coulombic potential barrier is further demonstrated in a comparison of the central atom inner shell spectra of SF6, ClF3 and HCl. © 1989. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/chemphys | en_US |
dc.relation.ispartof | Chemical Physics | en_US |
dc.title | Inner shell and valence shell electronic excitation of ClF3 by high energy electron impact. An investigation of potential barrier effects | en_US |
dc.type | Article | en_US |
dc.identifier.email | Sze, KH:khsze@hku.hk | en_US |
dc.identifier.authority | Sze, KH=rp00785 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.scopus | eid_2-s2.0-0000962888 | en_US |
dc.identifier.volume | 137 | en_US |
dc.identifier.issue | 1-3 | en_US |
dc.identifier.spage | 353 | en_US |
dc.identifier.epage | 367 | en_US |
dc.identifier.isi | WOS:A1989AV95300034 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Sze, KH=7006735061 | en_US |
dc.identifier.scopusauthorid | Brion, CE=7006196884 | en_US |
dc.identifier.issnl | 0301-0104 | - |