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Article: Inner shell and valence shell electronic excitation of ClF3 by high energy electron impact. An investigation of potential barrier effects

TitleInner shell and valence shell electronic excitation of ClF3 by high energy electron impact. An investigation of potential barrier effects
Authors
Issue Date1989
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/chemphys
Citation
Chemical Physics, 1989, v. 137 n. 1-3, p. 353-367 How to Cite?
AbstractInner shell (Cl 2p, 2s and F 1s) and valence shell electron energy loss spectra of ClF3 have been measured under conditions of high impact energy (3-3.7 keV) and zero degree scattering angle. The Coulombic potential barrier model is found to provide an extremely satisfactory understanding of (a) the co-existence in ClF3 of intense shape resonances and also intense Rydberg transitions plus direct ionization; and (b) the number and symmetry of the continuum shape resonances observed in the ISEELS spectra of ClF3. The physical significance of the Coulombic potential barrier is further demonstrated in a comparison of the central atom inner shell spectra of SF6, ClF3 and HCl. © 1989.
Persistent Identifierhttp://hdl.handle.net/10722/157227
ISSN
2015 Impact Factor: 1.758
2015 SCImago Journal Rankings: 0.719

 

DC FieldValueLanguage
dc.contributor.authorSze, KHen_US
dc.contributor.authorBrion, CEen_US
dc.date.accessioned2012-08-08T08:48:15Z-
dc.date.available2012-08-08T08:48:15Z-
dc.date.issued1989en_US
dc.identifier.citationChemical Physics, 1989, v. 137 n. 1-3, p. 353-367en_US
dc.identifier.issn0301-0104en_US
dc.identifier.urihttp://hdl.handle.net/10722/157227-
dc.description.abstractInner shell (Cl 2p, 2s and F 1s) and valence shell electron energy loss spectra of ClF3 have been measured under conditions of high impact energy (3-3.7 keV) and zero degree scattering angle. The Coulombic potential barrier model is found to provide an extremely satisfactory understanding of (a) the co-existence in ClF3 of intense shape resonances and also intense Rydberg transitions plus direct ionization; and (b) the number and symmetry of the continuum shape resonances observed in the ISEELS spectra of ClF3. The physical significance of the Coulombic potential barrier is further demonstrated in a comparison of the central atom inner shell spectra of SF6, ClF3 and HCl. © 1989.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/chemphysen_US
dc.relation.ispartofChemical Physicsen_US
dc.titleInner shell and valence shell electronic excitation of ClF3 by high energy electron impact. An investigation of potential barrier effectsen_US
dc.typeArticleen_US
dc.identifier.emailSze, KH:khsze@hku.hken_US
dc.identifier.authoritySze, KH=rp00785en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-0000962888en_US
dc.identifier.volume137en_US
dc.identifier.issue1-3en_US
dc.identifier.spage353en_US
dc.identifier.epage367en_US
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridSze, KH=7006735061en_US
dc.identifier.scopusauthoridBrion, CE=7006196884en_US

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