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Article: Chemically coupled hydroxyapatite-polyethylene composites: Structure and properties

TitleChemically coupled hydroxyapatite-polyethylene composites: Structure and properties
Authors
Wang, MBonfield, W
KeywordsGrafting
High-density polyethylene
Hydroxyapatite
Properties
Silanation
Structure
Issue Date2001
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/biomaterials
Citation
Biomaterials, 2001, v. 22 n. 11, p. 1311-1320 How to Cite?
DOI: http://dx.doi.org/10.1016/S0142-9612(00)00283-0
AbstractSilanation of hydroxyapatite and acrylic acid grafting of polyethylene were employed to improve bonding between hydroxyapatite and polyethylene. The structure and properties of chemically coupled hydroxyapatite reinforced high-density polyethylene (HA/HDPE) composites were subsequently investigated using various techniques. It was shown that there existed a silicon-containing interphase between the hydroxyapatite particle and the polyethylene matrix. The silane coupling agent used promoted chemical adhesion between hydroxyapatite particles and the polymer. The use of the silane coupling agent also facilitated the penetration of polymer into cavities in individual ceramic particles, which resulted in enhanced mechanical interlocking at the matrix-reinforcement interface. With a strong bond (both mechanical and chemical) being formed between hydroxyapatite and polyethylene, chemically coupled HA/HDPE composites possessed improved mechanical properties and fracture behaviour. Copyright © 2001 Elsevier Science Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/156597
ISSN
0142-9612
2023 Impact Factor: 12.8
2023 SCImago Journal Rankings: 3.016
ISI Accession Number ID
WOS:000168325200013
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorWang, Men_US
dc.contributor.authorBonfield, Wen_US
dc.date.accessioned2012-08-08T08:43:07Z-
dc.date.available2012-08-08T08:43:07Z-
dc.date.issued2001en_US
dc.identifier.citationBiomaterials, 2001, v. 22 n. 11, p. 1311-1320en_US
dc.identifier.issn0142-9612en_US
dc.identifier.urihttp://hdl.handle.net/10722/156597-
dc.description.abstractSilanation of hydroxyapatite and acrylic acid grafting of polyethylene were employed to improve bonding between hydroxyapatite and polyethylene. The structure and properties of chemically coupled hydroxyapatite reinforced high-density polyethylene (HA/HDPE) composites were subsequently investigated using various techniques. It was shown that there existed a silicon-containing interphase between the hydroxyapatite particle and the polyethylene matrix. The silane coupling agent used promoted chemical adhesion between hydroxyapatite particles and the polymer. The use of the silane coupling agent also facilitated the penetration of polymer into cavities in individual ceramic particles, which resulted in enhanced mechanical interlocking at the matrix-reinforcement interface. With a strong bond (both mechanical and chemical) being formed between hydroxyapatite and polyethylene, chemically coupled HA/HDPE composites possessed improved mechanical properties and fracture behaviour. Copyright © 2001 Elsevier Science Ltd.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/biomaterialsen_US
dc.relation.ispartofBiomaterialsen_US
dc.subjectGrafting-
dc.subjectHigh-density polyethylene-
dc.subjectHydroxyapatite-
dc.subjectProperties-
dc.subjectSilanation-
dc.subjectStructure-
dc.subject.meshDurapatite - Chemistryen_US
dc.subject.meshMaterials Testingen_US
dc.subject.meshPolyethylene - Chemistryen_US
dc.subject.meshStructure-Activity Relationshipen_US
dc.titleChemically coupled hydroxyapatite-polyethylene composites: Structure and propertiesen_US
dc.typeArticleen_US
dc.identifier.emailWang, M:memwang@hku.hken_US
dc.identifier.authorityWang, M=rp00185en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0142-9612(00)00283-0en_US
dc.identifier.pmid11336303-
dc.identifier.scopuseid_2-s2.0-0035372013en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035372013&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume22en_US
dc.identifier.issue11en_US
dc.identifier.spage1311en_US
dc.identifier.epage1320en_US
dc.identifier.isiWOS:000168325200013-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridWang, M=15749714100en_US
dc.identifier.scopusauthoridBonfield, W=16490765800en_US
dc.identifier.citeulike9860345-
dc.identifier.issnl0142-9612-

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