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Article: The 3(ππ*) Emission of Cy 3PAu(C≡C) nAuPCy 3 (n = 3, 4). Effect of chain length upon acetylenic 3(ππ*) emission

TitleThe 3(ππ*) Emission of Cy 3PAu(C≡C) nAuPCy 3 (n = 3, 4). Effect of chain length upon acetylenic 3(ππ*) emission
Authors
Issue Date2002
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 2002, v. 21 n. 11, p. 2343-2346 How to Cite?
AbstractThe synthesis of luminescent Cy 3PAu(C≡C) nAuPCy 3 complexes (n = 3,4) was presented. the complexes featured the dinuclear gold(I) complexes bridged by C 6 2- and C 8 2- rods. The compounds revealed highly vibronic acetylenic 3(ππ*) excited states, due to Au spin-orbital coupling. The absorption band for the π → π* transition was significantly red-shifted when compared to the lowest-energy dipole-allowed transition of the P(C≡C) 4R (R = CN, tBu) series.
Persistent Identifierhttp://hdl.handle.net/10722/154763
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLu, Wen_HK
dc.contributor.authorXiang, HFen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-08-08T08:30:31Z-
dc.date.available2012-08-08T08:30:31Z-
dc.date.issued2002en_HK
dc.identifier.citationOrganometallics, 2002, v. 21 n. 11, p. 2343-2346en_HK
dc.identifier.issn0276-7333en_HK
dc.identifier.urihttp://hdl.handle.net/10722/154763-
dc.description.abstractThe synthesis of luminescent Cy 3PAu(C≡C) nAuPCy 3 complexes (n = 3,4) was presented. the complexes featured the dinuclear gold(I) complexes bridged by C 6 2- and C 8 2- rods. The compounds revealed highly vibronic acetylenic 3(ππ*) excited states, due to Au spin-orbital coupling. The absorption band for the π → π* transition was significantly red-shifted when compared to the lowest-energy dipole-allowed transition of the P(C≡C) 4R (R = CN, tBu) series.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_HK
dc.relation.ispartofOrganometallicsen_HK
dc.titleThe 3(ππ*) Emission of Cy 3PAu(C≡C) nAuPCy 3 (n = 3, 4). Effect of chain length upon acetylenic 3(ππ*) emissionen_HK
dc.typeArticleen_HK
dc.identifier.emailXiang, HF: hfxiang@eee.hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityXiang, HF=rp00196en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/om011087fen_HK
dc.identifier.scopuseid_2-s2.0-0000619922en_HK
dc.identifier.hkuros69078-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000619922&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume21en_HK
dc.identifier.issue11en_HK
dc.identifier.spage2343en_HK
dc.identifier.epage2346en_HK
dc.identifier.isiWOS:000175734300028-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLu, W=55277832700en_HK
dc.identifier.scopusauthoridXiang, HF=23065758900en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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