Comparative study of platinum-group elements in the Coto and Acoje blocks of the Zambales ophiolite complex, Philippines

Abstract

The Zambales Ophiolite Complex (ZOC), Philippines, includes two geochemically distinct, ophiolitic assemblages: the high-Al chromitite-bearing Coto Block and high-Cr chromitite-bearing Acoje Block. This paper reports a comparative platinum-group element (PGE) study of these two blocks. The PGE data were obtained using Ni-sulfide fire assay preconcentration combined with inductively coupled plasma mass spectrometry (ICP-MS) measurement. Podiform chromitites in the Acoje Block have higher Cu, Ir, Ru and Rh contents than their equivalents in the Coto Block, although chromitites from both have similar Pt and Pd contents. The PGE mantle-normalized patterns of dunites from the two blocks are also different: dunites from the Coto Block are depleted in Pt, whereas those from the Acoje Block have a relatively flat pattern. The data demonstrate that Coto and Acoje Blocks have different origins in terms of their source region and partial melting processes. This study implies that the ZOC is a paired ophiolite belt formed in an island arc and back-arc basin environment.