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Article: Laser spectroscopy of ScI: Rotational analysis of the D1Π-X1Σ+ system

TitleLaser spectroscopy of ScI: Rotational analysis of the D1Π-X1Σ+ system
Authors
KeywordsD state
Electronic transition
LIF
Molecular constants
ScI
Issue Date2011
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmsp
Citation
Journal of Molecular Spectroscopy, 2011, v. 268 n. 1-2, p. 3-6 How to Cite?
AbstractHigh resolution laser spectrum of scandium monoiodide (ScI) between 613 and 704 nm has been investigated using the technique of laser vaporization/reaction with free jet expansion and laser induced fluorescence spectroscopy. Seven vibrational bands of the D 1Π-X 1Σ + transition of ScI were recorded and analyzed. Accurate molecular constants for the v = 0-2 levels of the D 1Π state and the v = 0-3 levels of the X 1Σ + state were obtained. Detailed analysis of the recorded spectrum indicates that the v = 2 level of the X 1Σ + state is perturbed by the v = 1 level of the a 3Δ 1 state at J = 8. A comparison of molecular constants for the D 1Π and X 1Σ + states of scandium monohalides indicates a weakening of chemical bonding between the scandium and the halogen atoms down the group. © 2011 Elsevier Inc. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/148648
ISSN
2015 Impact Factor: 1.593
2015 SCImago Journal Rankings: 0.543
ISI Accession Number ID
Funding AgencyGrant Number
Research Grants Council of the Hong Kong Special Administrative Region, ChinaHKU 701008
Funding Information:

We would like to thank Mr. P.M. Yeung and Mr. H.F. Pang for technical assistance. The work described here was supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China (Project No.: HKU 701008).

References

 

DC FieldValueLanguage
dc.contributor.authorXia, ZHen_HK
dc.contributor.authorXia, Yen_HK
dc.contributor.authorChan, MCen_HK
dc.contributor.authorCheung, ASCen_HK
dc.date.accessioned2012-05-29T06:14:22Z-
dc.date.available2012-05-29T06:14:22Z-
dc.date.issued2011en_HK
dc.identifier.citationJournal of Molecular Spectroscopy, 2011, v. 268 n. 1-2, p. 3-6en_HK
dc.identifier.issn0022-2852en_HK
dc.identifier.urihttp://hdl.handle.net/10722/148648-
dc.description.abstractHigh resolution laser spectrum of scandium monoiodide (ScI) between 613 and 704 nm has been investigated using the technique of laser vaporization/reaction with free jet expansion and laser induced fluorescence spectroscopy. Seven vibrational bands of the D 1Π-X 1Σ + transition of ScI were recorded and analyzed. Accurate molecular constants for the v = 0-2 levels of the D 1Π state and the v = 0-3 levels of the X 1Σ + state were obtained. Detailed analysis of the recorded spectrum indicates that the v = 2 level of the X 1Σ + state is perturbed by the v = 1 level of the a 3Δ 1 state at J = 8. A comparison of molecular constants for the D 1Π and X 1Σ + states of scandium monohalides indicates a weakening of chemical bonding between the scandium and the halogen atoms down the group. © 2011 Elsevier Inc. All rights reserved.en_HK
dc.languageengen_US
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmspen_HK
dc.relation.ispartofJournal of Molecular Spectroscopyen_HK
dc.subjectD stateen_HK
dc.subjectElectronic transitionen_HK
dc.subjectLIFen_HK
dc.subjectMolecular constantsen_HK
dc.subjectScIen_HK
dc.titleLaser spectroscopy of ScI: Rotational analysis of the D1Π-X1Σ+ systemen_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/j.jms.2011.03.014en_HK
dc.identifier.scopuseid_2-s2.0-80052268952en_HK
dc.identifier.hkuros205593-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-80052268952&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume268en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage3en_HK
dc.identifier.epage6en_HK
dc.identifier.isiWOS:000294833100002-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridXia, ZH=7402151546en_HK
dc.identifier.scopusauthoridXia, Y=36814899600en_HK
dc.identifier.scopusauthoridChan, MC=7402597692en_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK
dc.identifier.citeulike9230829-

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