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Article: Laser Induced Fluorescence Spectrum of the A4Π-X4Σ- (0,0) Band of MoN

TitleLaser Induced Fluorescence Spectrum of the A4Π-X4Σ- (0,0) Band of MoN
Authors
Issue Date1995
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmsp
Citation
Journal Of Molecular Spectroscopy, 1995, v. 173 n. 1, p. 194-204 How to Cite?
AbstractThe A 4Π-X 4Σ - (0,0) band of MoN between 5990 and 6350 Å has been studied using laser induced fluorescence spectroscopy. In addition to observing the stronger ΔΣ = 0 transitions, the weaker ΔΣ = ±1 transitions have also been recorded and analyzed. The 95Mo and 97Mo nuclear hyperfine structures (I = 5 2) give considerable broadening to the F 1 and F 4 branches with six hyperfine components of a rotational line spread more than 0.1 cm -1. The hyperfine linewidths vary with J in the manner expected for spin uncoupling from case (a β) to case (b βJ) in a high multiplicity state. A merged least-squares fit of the present data and the earlier work yielded improved molecular constants of both the A 4Π and X 4Σ - states of the seven isotopic molecules. © 1995 Academic Press. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/148342
ISSN
2015 Impact Factor: 1.593
2015 SCImago Journal Rankings: 0.543
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorSze, NSKen_HK
dc.contributor.authorCheung, ASCen_HK
dc.date.accessioned2012-05-29T06:12:20Z-
dc.date.available2012-05-29T06:12:20Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal Of Molecular Spectroscopy, 1995, v. 173 n. 1, p. 194-204en_HK
dc.identifier.issn0022-2852en_HK
dc.identifier.urihttp://hdl.handle.net/10722/148342-
dc.description.abstractThe A 4Π-X 4Σ - (0,0) band of MoN between 5990 and 6350 Å has been studied using laser induced fluorescence spectroscopy. In addition to observing the stronger ΔΣ = 0 transitions, the weaker ΔΣ = ±1 transitions have also been recorded and analyzed. The 95Mo and 97Mo nuclear hyperfine structures (I = 5 2) give considerable broadening to the F 1 and F 4 branches with six hyperfine components of a rotational line spread more than 0.1 cm -1. The hyperfine linewidths vary with J in the manner expected for spin uncoupling from case (a β) to case (b βJ) in a high multiplicity state. A merged least-squares fit of the present data and the earlier work yielded improved molecular constants of both the A 4Π and X 4Σ - states of the seven isotopic molecules. © 1995 Academic Press. All rights reserved.en_HK
dc.languageengen_US
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmspen_HK
dc.relation.ispartofJournal of Molecular Spectroscopyen_HK
dc.titleLaser Induced Fluorescence Spectrum of the A4Π-X4Σ- (0,0) Band of MoNen_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1006/jmsp.1995.1228en_HK
dc.identifier.scopuseid_2-s2.0-0039344505en_HK
dc.identifier.hkuros9396-
dc.identifier.volume173en_HK
dc.identifier.issue1en_HK
dc.identifier.spage194en_HK
dc.identifier.epage204en_HK
dc.identifier.isiWOS:A1995RU65200018-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridSze, NSK=7003280176en_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK

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