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Article: Laser induced fluorescence spectroscopy of ZrN: Rotational structure in the A2Π-X2Σ(2,2) band

TitleLaser induced fluorescence spectroscopy of ZrN: Rotational structure in the A2Π-X2Σ(2,2) band
Authors
Issue Date1997
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1997, v. 269 n. 1-2, p. 49-53 How to Cite?
AbstractThe A 2Π-X 2Σ (2,2) band of ZrN between 5661 and 5891 Å has been studied using laser induced fluorescence and wavelength resolved fluorescence spectroscopy. All the 12 branches expected from a 2Π- 2Σ transition have been observed and assigned. Three strong perturbations at J = 16.5, 23.5 and 36.5 of the 2Π 3/2 substate v = 2 level have been found. Since both e and f Λ-doubling components of the 2H 3/2 state are perturbed to nearly the same extent, which is consistent with the perturbing state being degenerate. Magnetic hyperfine splitting of the 91ZrN molecule with v = 2 has been identified and analyzed.
Persistent Identifierhttp://hdl.handle.net/10722/148098
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChan, CMTen_HK
dc.contributor.authorLi, Hen_HK
dc.contributor.authorCheung, ASCen_HK
dc.date.accessioned2012-05-29T06:10:49Z-
dc.date.available2012-05-29T06:10:49Z-
dc.date.issued1997en_HK
dc.identifier.citationChemical Physics Letters, 1997, v. 269 n. 1-2, p. 49-53en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/148098-
dc.description.abstractThe A 2Π-X 2Σ (2,2) band of ZrN between 5661 and 5891 Å has been studied using laser induced fluorescence and wavelength resolved fluorescence spectroscopy. All the 12 branches expected from a 2Π- 2Σ transition have been observed and assigned. Three strong perturbations at J = 16.5, 23.5 and 36.5 of the 2Π 3/2 substate v = 2 level have been found. Since both e and f Λ-doubling components of the 2H 3/2 state are perturbed to nearly the same extent, which is consistent with the perturbing state being degenerate. Magnetic hyperfine splitting of the 91ZrN molecule with v = 2 has been identified and analyzed.en_HK
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.titleLaser induced fluorescence spectroscopy of ZrN: Rotational structure in the A2Π-X2Σ(2,2) banden_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0009-2614(97)00239-X-
dc.identifier.scopuseid_2-s2.0-0031585975en_HK
dc.identifier.hkuros31449-
dc.identifier.hkuros22438-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0031585975&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume269en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage49en_HK
dc.identifier.epage53en_HK
dc.identifier.isiWOS:A1997WV11300007-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridChan, CMT=25948133800en_HK
dc.identifier.scopusauthoridLi, H=8576263300en_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK

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