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Article: Rotational dependence of the predissociation linewidths of the Schumann-Runge bands of O2

TitleRotational dependence of the predissociation linewidths of the Schumann-Runge bands of O2
Authors
Issue Date1993
PublisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp
Citation
The Journal Of Chemical Physics, 1993, v. 99 n. 2, p. 1086-1092 How to Cite?
AbstractThe predissociation linewidths of vibrational levels v=0-12 for 16O 2, 16O 18O, and 18O 2 molecules in the B 3Σ u - state with rotational quantum numbers N≤20 have been calculated taking into account the spin-orbit interactions of the B 3Σ u - state with the 5Π u, 3Σ u +, 3Π u, and 1Π u states, and the rotational coupling with the 3Π u, state. The predissociation linewidths exhibit systematic variations with rotational quantum number for different vibrational levels. Good agreement between most of the calculated and experimental linewidths has been obtained for all three isotopic molecules, with the exception of the set of linewidths of 16O 2 for v=0 and 2. The agreement can be improved by adjustment of the 1Π u potential and the strength of the spin-orbit interaction between the B 3Σ u - and 1Π u states. © 1993 American Institute of Physics.
Persistent Identifierhttp://hdl.handle.net/10722/147714
ISSN
2015 Impact Factor: 2.894
2015 SCImago Journal Rankings: 0.959
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorCheung, ASCen_HK
dc.contributor.authorMok, DKWen_HK
dc.contributor.authorJamieson, MJen_HK
dc.contributor.authorFinch, Men_HK
dc.contributor.authorYoshino, Ken_HK
dc.contributor.authorDalgarno, Aen_HK
dc.contributor.authorParkinson, WHen_HK
dc.date.accessioned2012-05-29T06:08:52Z-
dc.date.available2012-05-29T06:08:52Z-
dc.date.issued1993en_HK
dc.identifier.citationThe Journal Of Chemical Physics, 1993, v. 99 n. 2, p. 1086-1092en_HK
dc.identifier.issn0021-9606en_HK
dc.identifier.urihttp://hdl.handle.net/10722/147714-
dc.description.abstractThe predissociation linewidths of vibrational levels v=0-12 for 16O 2, 16O 18O, and 18O 2 molecules in the B 3Σ u - state with rotational quantum numbers N≤20 have been calculated taking into account the spin-orbit interactions of the B 3Σ u - state with the 5Π u, 3Σ u +, 3Π u, and 1Π u states, and the rotational coupling with the 3Π u, state. The predissociation linewidths exhibit systematic variations with rotational quantum number for different vibrational levels. Good agreement between most of the calculated and experimental linewidths has been obtained for all three isotopic molecules, with the exception of the set of linewidths of 16O 2 for v=0 and 2. The agreement can be improved by adjustment of the 1Π u potential and the strength of the spin-orbit interaction between the B 3Σ u - and 1Π u states. © 1993 American Institute of Physics.en_HK
dc.languageengen_US
dc.publisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jspen_HK
dc.relation.ispartofThe Journal of Chemical Physicsen_HK
dc.rightsCreative Commons: Attribution 3.0 Hong Kong License-
dc.rightsCopyright (1993) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in (The Journal Of Chemical Physics, 1993, v. 99 n. 2, p. 1086-1092) and may be found at (http://jcp.aip.org/resource/1/jcpsa6/v99/i2/p1086_s1).-
dc.titleRotational dependence of the predissociation linewidths of the Schumann-Runge bands of O2en_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturepublished_or_final_versionen_US
dc.identifier.doi10.1063/1.466204-
dc.identifier.scopuseid_2-s2.0-0004671068en_HK
dc.identifier.volume99en_HK
dc.identifier.issue2en_HK
dc.identifier.spage1086en_HK
dc.identifier.epage1092en_HK
dc.identifier.isiWOS:A1993LM89400034-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK
dc.identifier.scopusauthoridMok, DKW=7005683712en_HK
dc.identifier.scopusauthoridJamieson, MJ=24352276800en_HK
dc.identifier.scopusauthoridFinch, M=23014532000en_HK
dc.identifier.scopusauthoridYoshino, K=7401650773en_HK
dc.identifier.scopusauthoridDalgarno, A=22987883200en_HK
dc.identifier.scopusauthoridParkinson, WH=7006361375en_HK

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