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Article: Two singlet electronic transitions in the near infrared attributed to VO+

TitleTwo singlet electronic transitions in the near infrared attributed to VO+
Authors
Issue Date1984
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmsp
Citation
Journal Of Molecular Spectroscopy, 1984, v. 108 n. 2, p. 343-351 How to Cite?
AbstractTwo new singlet electronic transitions, consisting of sequences near 8400 and 9200 Å, have been recorded by Fourier transform emission spectroscopy, where the source was a microwave discharge in flowing VOCl 3 vapor mixed with helium. Rotational analysis shows that these are probably 1Σ +- 1Σ + and 1Δ- 1Δ transitions, and arguments are presented indicating that the carrier is VO +, for which no previous spectroscopic observations have been reported. The lower electronic states of both transitions show highly anomalous centrifugal distortion effects, presumably as a result of rotational perturbations: The perturbing electronic state may be the 3Δ state which arises from the same configuration as the lower 1Δ state. © 1984.
Persistent Identifierhttp://hdl.handle.net/10722/147706
ISSN
2015 Impact Factor: 1.593
2015 SCImago Journal Rankings: 0.543
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorMerer, AJen_HK
dc.contributor.authorCheung, ASCen_HK
dc.contributor.authorTaylor, AWen_HK
dc.date.accessioned2012-05-29T06:08:49Z-
dc.date.available2012-05-29T06:08:49Z-
dc.date.issued1984en_HK
dc.identifier.citationJournal Of Molecular Spectroscopy, 1984, v. 108 n. 2, p. 343-351en_HK
dc.identifier.issn0022-2852en_HK
dc.identifier.urihttp://hdl.handle.net/10722/147706-
dc.description.abstractTwo new singlet electronic transitions, consisting of sequences near 8400 and 9200 Å, have been recorded by Fourier transform emission spectroscopy, where the source was a microwave discharge in flowing VOCl 3 vapor mixed with helium. Rotational analysis shows that these are probably 1Σ +- 1Σ + and 1Δ- 1Δ transitions, and arguments are presented indicating that the carrier is VO +, for which no previous spectroscopic observations have been reported. The lower electronic states of both transitions show highly anomalous centrifugal distortion effects, presumably as a result of rotational perturbations: The perturbing electronic state may be the 3Δ state which arises from the same configuration as the lower 1Δ state. © 1984.en_HK
dc.languageengen_US
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmspen_HK
dc.relation.ispartofJournal of Molecular Spectroscopyen_HK
dc.titleTwo singlet electronic transitions in the near infrared attributed to VO+en_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0022-2852(84)90190-5-
dc.identifier.scopuseid_2-s2.0-0001262566en_HK
dc.identifier.volume108en_HK
dc.identifier.issue2en_HK
dc.identifier.spage343en_HK
dc.identifier.epage351en_HK
dc.identifier.isiWOS:A1984TV40700013-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridMerer, AJ=6603864922en_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK
dc.identifier.scopusauthoridTaylor, AW=24406894300en_HK

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