File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Fourier transform spectroscopy of VO: Rotational structure in the A4Π-X4Σ- system near 10 500 Å

TitleFourier transform spectroscopy of VO: Rotational structure in the A4Π-X4Σ- system near 10 500 Å
Authors
Issue Date1982
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmsp
Citation
Journal Of Molecular Spectroscopy, 1982, v. 92 n. 2, p. 391-409 How to Cite?
AbstractThe A 4Π-X 4Σ - electronic transition of VO in the near infrared was recorded at Doppler-limited resolution by Fourier transform spectroscopy, and rotational analyses performed for the (0, 0) band at 1.05 μm and the (0, 1) band at 1.18 μm. The A 4Π state is found to have comparatively small spin-orbit coupling (A = 35.19 cm -1) so that is is almost completely uncoupled to case (b) at the highest N values observed, near N = 90. The hyperfine structure due to the 51V nucleus (I = 7 2) is prominent in the 4Π 5 2-X 4Σ - subband, and in many of the spin satellite branches; at high N values, where only main branches (ΔN = ΔJ) occur, the lines are sharp, indicating that the hyperfine b parameter (the coefficient of I·S in the magnetic hyperfine Hamiltonian) is the same in the A 4Π and X 4Σ - states. The electron configuration of the A 4Π state is therefore (4sσ) 1(3dδ) 1(4pπ) 1. © 1982.
Persistent Identifierhttp://hdl.handle.net/10722/147699
ISSN
2015 Impact Factor: 1.593
2015 SCImago Journal Rankings: 0.543
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorCheung, ASCen_HK
dc.contributor.authorTaylor, AWen_HK
dc.contributor.authorMerer, AJen_HK
dc.date.accessioned2012-05-29T06:08:46Z-
dc.date.available2012-05-29T06:08:46Z-
dc.date.issued1982en_HK
dc.identifier.citationJournal Of Molecular Spectroscopy, 1982, v. 92 n. 2, p. 391-409en_HK
dc.identifier.issn0022-2852en_HK
dc.identifier.urihttp://hdl.handle.net/10722/147699-
dc.description.abstractThe A 4Π-X 4Σ - electronic transition of VO in the near infrared was recorded at Doppler-limited resolution by Fourier transform spectroscopy, and rotational analyses performed for the (0, 0) band at 1.05 μm and the (0, 1) band at 1.18 μm. The A 4Π state is found to have comparatively small spin-orbit coupling (A = 35.19 cm -1) so that is is almost completely uncoupled to case (b) at the highest N values observed, near N = 90. The hyperfine structure due to the 51V nucleus (I = 7 2) is prominent in the 4Π 5 2-X 4Σ - subband, and in many of the spin satellite branches; at high N values, where only main branches (ΔN = ΔJ) occur, the lines are sharp, indicating that the hyperfine b parameter (the coefficient of I·S in the magnetic hyperfine Hamiltonian) is the same in the A 4Π and X 4Σ - states. The electron configuration of the A 4Π state is therefore (4sσ) 1(3dδ) 1(4pπ) 1. © 1982.en_HK
dc.languageengen_US
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmspen_HK
dc.relation.ispartofJournal of Molecular Spectroscopyen_HK
dc.titleFourier transform spectroscopy of VO: Rotational structure in the A4Π-X4Σ- system near 10 500 Åen_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/0022-2852(82)90110-2-
dc.identifier.scopuseid_2-s2.0-0000573384en_HK
dc.identifier.volume92en_HK
dc.identifier.issue2en_HK
dc.identifier.spage391en_HK
dc.identifier.epage409en_HK
dc.identifier.isiWOS:A1982NL27800007-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK
dc.identifier.scopusauthoridTaylor, AW=24406894300en_HK
dc.identifier.scopusauthoridMerer, AJ=6603864922en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats