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Article: Laser spectroscopy of the C1Σ+-X1Σ+ transition of ScBr

TitleLaser spectroscopy of the C1Σ+-X1Σ+ transition of ScBr
Authors
KeywordsEquilibrium bond length
Isotopomers
Laser induced fluorescence
Least squares fit
Line positions
Issue Date2012
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 2012, v. 527, p. 7-10 How to Cite?
AbstractThe laser induced fluorescence spectrum of scandium monobromide (ScBr) between 795 and 845 nm has been recorded and analyzed. ScBr was produced by reacting laser vaporized Sc atoms with ethyl bromide (C 2H 5Br). Spectra of six vibrational bands of both Sc 79Br and Sc 81Br isotopomers of the C 1Σ +-X 1Σ + transition were observed. A least-squares fit of the measured line positions yielded accurate molecular constants for the v = 0-3 levels of the C 1Σ + state and the v = 0-2 levels of the X 1Σ + state. The equilibrium bond length of the C 1Σ + state has been determined to be 2.4776 . © 2012 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/146856
ISSN
2023 Impact Factor: 2.8
2023 SCImago Journal Rankings: 0.502
ISI Accession Number ID
Funding AgencyGrant Number
Research Grants Council of Hong Kong Special Administrative Region, ChinaHKU 701008
Funding Information:

We would like to thank Mr. P. M. Yeung and Dr. H. F. Pang for technical assistance. The work described here was supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China (Project No.: HKU 701008).

References

 

DC FieldValueLanguage
dc.contributor.authorXia, Yen_HK
dc.contributor.authorLiao, Zen_HK
dc.contributor.authorYang, Men_HK
dc.contributor.authorChan, MCen_HK
dc.contributor.authorCheung, ASCen_HK
dc.date.accessioned2012-05-23T05:42:46Z-
dc.date.available2012-05-23T05:42:46Z-
dc.date.issued2012en_HK
dc.identifier.citationChemical Physics Letters, 2012, v. 527, p. 7-10en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/146856-
dc.description.abstractThe laser induced fluorescence spectrum of scandium monobromide (ScBr) between 795 and 845 nm has been recorded and analyzed. ScBr was produced by reacting laser vaporized Sc atoms with ethyl bromide (C 2H 5Br). Spectra of six vibrational bands of both Sc 79Br and Sc 81Br isotopomers of the C 1Σ +-X 1Σ + transition were observed. A least-squares fit of the measured line positions yielded accurate molecular constants for the v = 0-3 levels of the C 1Σ + state and the v = 0-2 levels of the X 1Σ + state. The equilibrium bond length of the C 1Σ + state has been determined to be 2.4776 . © 2012 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in Chemical Physics Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Chemical Physics Letters, 2012, v. 527, p. 7-10. DOI: 10.1016/j.cplett.2012.01.017-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.subjectEquilibrium bond length-
dc.subjectIsotopomers-
dc.subjectLaser induced fluorescence-
dc.subjectLeast squares fit-
dc.subjectLine positions-
dc.titleLaser spectroscopy of the C1Σ+-X1Σ+ transition of ScBren_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.description.naturepostprint-
dc.identifier.doi10.1016/j.cplett.2012.01.017en_HK
dc.identifier.scopuseid_2-s2.0-84857234349en_HK
dc.identifier.hkuros199749en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-84857234349&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume527en_HK
dc.identifier.spage7en_HK
dc.identifier.epage10en_HK
dc.identifier.isiWOS:000300614300002-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridXia, Y=36814899600en_HK
dc.identifier.scopusauthoridLiao, Z=54912034100en_HK
dc.identifier.scopusauthoridYang, M=7404926247en_HK
dc.identifier.scopusauthoridChan, MC=7402597692en_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK
dc.identifier.citeulike10257866-
dc.identifier.issnl0009-2614-

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