Article: Studies on surface preparation and smoothness of nanostructured Bi 2Te 3-based alloys by electrochemical and mechanical methods

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TitleStudies on surface preparation and smoothness of nanostructured Bi 2Te 3-based alloys by electrochemical and mechanical methods
AuthorsFeng, HP1
Yu, B2
Chen, S1
Collins, K1
He, C1
Ren, ZF2
Chen, G1
KeywordsBismuth telluride based alloys
Chemical mechanical polishing
Electrolysis
Nanostructures
Thermoelectrics
Issue Date2011
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/electacta
CitationElectrochimica Acta, 2011, v. 56 n. 8, p. 3079-3084 [How to Cite?]
DOI: http://dx.doi.org/10.1016/j.electacta.2010.12.008
AbstractSignificant improvements in the dimensionless thermoelectric figure-of-merit (ZT) for nanostructured bismuth telluride, Bi 2Te 3, and its alloys have been demonstrated. In designing high-performance thermoelectric devices, variations in the thermal and electrical contact resistances due to interfacial effects between the nanostructured alloy and the metallic electrodes remain a significant issue. Smooth scratch-free surfaces should provide a baseline for contact resistance studies. In this paper, the root mean square roughness over a 10 μm 2 of nanostructured bismuth tellurium based alloys was reduced from 133 nm to 1.9 nm by a procedure consisting of electrolysis, mechanical polishing, and chemical mechanical polishing (CMP). Post-CMP cleaning was also developed to yield a wettable surface for the subsequent conformable metallization. © 2010 Elsevier Ltd. All rights reserved.
ISSN0013-4686
2011 Impact Factor: 3.832
2011 SCImago Journal Rankings: 0.262
DOIhttp://dx.doi.org/10.1016/j.electacta.2010.12.008
ISI Accession Number IDWOS:000289133000014
Funding AgencyGrant Number
U.S. Department of Energy, Office of Science, Office of Basic Energy SciencesDE-SC0001299
Funding Information:

The authors thank Jonathan K. Tong and Dr. Sheng Shen for very helpful discussions and editorial assistance, and also thank Daniel Kraemer for fabricating the polishing jig. This work is supported by "Solid State Solar-Thermal Energy Conversion Center (S3TEC)", an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number: DE-SC0001299 (G.C. and Z.F.R.).

ReferencesReferences in Scopus
DC Field
Value
dc.contributor.authorFeng, HP
dc.contributor.authorYu, B
dc.contributor.authorChen, S
dc.contributor.authorCollins, K
dc.contributor.authorHe, C
dc.contributor.authorRen, ZF
dc.contributor.authorChen, G
dc.date.accessioned2011-10-10T07:13:46Z
dc.date.available2011-10-10T07:13:46Z
dc.date.issued2011
dc.description.abstractSignificant improvements in the dimensionless thermoelectric figure-of-merit (ZT) for nanostructured bismuth telluride, Bi 2Te 3, and its alloys have been demonstrated. In designing high-performance thermoelectric devices, variations in the thermal and electrical contact resistances due to interfacial effects between the nanostructured alloy and the metallic electrodes remain a significant issue. Smooth scratch-free surfaces should provide a baseline for contact resistance studies. In this paper, the root mean square roughness over a 10 μm 2 of nanostructured bismuth tellurium based alloys was reduced from 133 nm to 1.9 nm by a procedure consisting of electrolysis, mechanical polishing, and chemical mechanical polishing (CMP). Post-CMP cleaning was also developed to yield a wettable surface for the subsequent conformable metallization. © 2010 Elsevier Ltd. All rights reserved.
dc.description.natureLink_to_subscribed_fulltext
dc.identifier.citationElectrochimica Acta, 2011, v. 56 n. 8, p. 3079-3084 [How to Cite?]
DOI: http://dx.doi.org/10.1016/j.electacta.2010.12.008
dc.identifier.citeulike8450014
dc.identifier.doihttp://dx.doi.org/10.1016/j.electacta.2010.12.008
dc.identifier.epage3084
dc.identifier.isiWOS:000289133000014
Funding AgencyGrant Number
U.S. Department of Energy, Office of Science, Office of Basic Energy SciencesDE-SC0001299
Funding Information:

The authors thank Jonathan K. Tong and Dr. Sheng Shen for very helpful discussions and editorial assistance, and also thank Daniel Kraemer for fabricating the polishing jig. This work is supported by "Solid State Solar-Thermal Energy Conversion Center (S3TEC)", an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number: DE-SC0001299 (G.C. and Z.F.R.).

dc.identifier.issn0013-4686
2011 Impact Factor: 3.832
2011 SCImago Journal Rankings: 0.262
dc.identifier.issue8
dc.identifier.scopuseid_2-s2.0-79952445070
dc.identifier.spage3079
dc.identifier.urihttp://hdl.handle.net/10722/142041
dc.identifier.volume56
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/electacta
dc.publisher.placeUnited Kingdom
dc.relation.ispartofElectrochimica Acta
dc.relation.referencesReferences in Scopus
dc.subjectBismuth telluride based alloys
dc.subjectChemical mechanical polishing
dc.subjectElectrolysis
dc.subjectNanostructures
dc.subjectThermoelectrics
dc.titleStudies on surface preparation and smoothness of nanostructured Bi 2Te 3-based alloys by electrochemical and mechanical methods
dc.typeArticle
Author Affiliations
  1. Massachusetts Institute of Technology
  2. Boston College