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Article: New tricyanoiron(III) building blocks for the construction of molecule-based magnets
Title | New tricyanoiron(III) building blocks for the construction of molecule-based magnets | ||||||||
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Authors | |||||||||
Keywords | building block cyano iron molecule-based magnet Schiff base | ||||||||
Issue Date | 2010 | ||||||||
Publisher | Science China Press, co-published with Springer. The Journal's web site is located at http://chem.scichina.com:8081/sciBe/EN/volumn/current.shtml | ||||||||
Citation | Science China Chemistry, 2010, v. 53 n. 10, p. 2106-2111 How to Cite? | ||||||||
Abstract | A series of tricyanoiron(III) complexes with the general formula mer-[Fe III(5-Xsap)(CN) 3] 2- (X = H, Me, MeO, Cl or Br, sapH 2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh 4) 2[Fe III(sap)(CN) 3] and (PPh 4) 2[Fe III(5-Mesap)(CN) 3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg. | ||||||||
Persistent Identifier | http://hdl.handle.net/10722/139002 | ||||||||
ISSN | 2023 Impact Factor: 10.4 2023 SCImago Journal Rankings: 2.316 | ||||||||
ISI Accession Number ID |
Funding Information: The work was supported by the City University of Hong Kong (7002319), the Research Grants Council of Hong Kong (N_CityU 107/08), and the National Natural Science Foundation of China (20831160505). | ||||||||
References |
DC Field | Value | Language |
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dc.contributor.author | Man, WL | en_HK |
dc.contributor.author | Xiang, J | en_HK |
dc.contributor.author | Lau, PH | en_HK |
dc.contributor.author | Gao, S | en_HK |
dc.contributor.author | Wong, WT | en_HK |
dc.contributor.author | Lau, TC | en_HK |
dc.date.accessioned | 2011-09-23T05:43:58Z | - |
dc.date.available | 2011-09-23T05:43:58Z | - |
dc.date.issued | 2010 | en_HK |
dc.identifier.citation | Science China Chemistry, 2010, v. 53 n. 10, p. 2106-2111 | en_HK |
dc.identifier.issn | 1674-7291 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/139002 | - |
dc.description.abstract | A series of tricyanoiron(III) complexes with the general formula mer-[Fe III(5-Xsap)(CN) 3] 2- (X = H, Me, MeO, Cl or Br, sapH 2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh 4) 2[Fe III(sap)(CN) 3] and (PPh 4) 2[Fe III(5-Mesap)(CN) 3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg. | en_HK |
dc.language | eng | en_US |
dc.publisher | Science China Press, co-published with Springer. The Journal's web site is located at http://chem.scichina.com:8081/sciBe/EN/volumn/current.shtml | en_HK |
dc.relation.ispartof | Science China Chemistry | en_HK |
dc.subject | building block | en_HK |
dc.subject | cyano | en_HK |
dc.subject | iron | en_HK |
dc.subject | molecule-based magnet | en_HK |
dc.subject | Schiff base | en_HK |
dc.title | New tricyanoiron(III) building blocks for the construction of molecule-based magnets | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
dc.identifier.authority | Wong, WT=rp00811 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1007/s11426-010-4119-4 | en_HK |
dc.identifier.scopus | eid_2-s2.0-78049458693 | en_HK |
dc.identifier.hkuros | 195797 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-78049458693&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 53 | en_HK |
dc.identifier.issue | 10 | en_HK |
dc.identifier.spage | 2106 | en_HK |
dc.identifier.epage | 2111 | en_HK |
dc.identifier.isi | WOS:000283396200006 | - |
dc.publisher.place | China | en_HK |
dc.identifier.scopusauthorid | Man, WL=7005307944 | en_HK |
dc.identifier.scopusauthorid | Xiang, J=36467466600 | en_HK |
dc.identifier.scopusauthorid | Lau, PH=15921593400 | en_HK |
dc.identifier.scopusauthorid | Gao, S=7403257903 | en_HK |
dc.identifier.scopusauthorid | Wong, WT=7403973084 | en_HK |
dc.identifier.scopusauthorid | Lau, TC=7102222310 | en_HK |
dc.identifier.issnl | 1869-1870 | - |