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Article: New tricyanoiron(III) building blocks for the construction of molecule-based magnets

TitleNew tricyanoiron(III) building blocks for the construction of molecule-based magnets
Authors
Keywordsbuilding block
cyano
iron
molecule-based magnet
Schiff base
Issue Date2010
PublisherScience China Press, co-published with Springer. The Journal's web site is located at http://chem.scichina.com:8081/sciBe/EN/volumn/current.shtml
Citation
Science China Chemistry, 2010, v. 53 n. 10, p. 2106-2111 How to Cite?
AbstractA series of tricyanoiron(III) complexes with the general formula mer-[Fe III(5-Xsap)(CN) 3] 2- (X = H, Me, MeO, Cl or Br, sapH 2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh 4) 2[Fe III(sap)(CN) 3] and (PPh 4) 2[Fe III(5-Mesap)(CN) 3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.
Persistent Identifierhttp://hdl.handle.net/10722/139002
ISSN
2015 Impact Factor: 2.429
2015 SCImago Journal Rankings: 0.567
ISI Accession Number ID
Funding AgencyGrant Number
City University of Hong Kong7002319
Research Grants Council of Hong KongN_CityU 107/08
National Natural Science Foundation of China20831160505
Funding Information:

The work was supported by the City University of Hong Kong (7002319), the Research Grants Council of Hong Kong (N_CityU 107/08), and the National Natural Science Foundation of China (20831160505).

References

 

DC FieldValueLanguage
dc.contributor.authorMan, WLen_HK
dc.contributor.authorXiang, Jen_HK
dc.contributor.authorLau, PHen_HK
dc.contributor.authorGao, Sen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorLau, TCen_HK
dc.date.accessioned2011-09-23T05:43:58Z-
dc.date.available2011-09-23T05:43:58Z-
dc.date.issued2010en_HK
dc.identifier.citationScience China Chemistry, 2010, v. 53 n. 10, p. 2106-2111en_HK
dc.identifier.issn1674-7291en_HK
dc.identifier.urihttp://hdl.handle.net/10722/139002-
dc.description.abstractA series of tricyanoiron(III) complexes with the general formula mer-[Fe III(5-Xsap)(CN) 3] 2- (X = H, Me, MeO, Cl or Br, sapH 2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh 4) 2[Fe III(sap)(CN) 3] and (PPh 4) 2[Fe III(5-Mesap)(CN) 3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.en_HK
dc.languageengen_US
dc.publisherScience China Press, co-published with Springer. The Journal's web site is located at http://chem.scichina.com:8081/sciBe/EN/volumn/current.shtmlen_HK
dc.relation.ispartofScience China Chemistryen_HK
dc.subjectbuilding blocken_HK
dc.subjectcyanoen_HK
dc.subjectironen_HK
dc.subjectmolecule-based magneten_HK
dc.subjectSchiff baseen_HK
dc.titleNew tricyanoiron(III) building blocks for the construction of molecule-based magnetsen_HK
dc.typeArticleen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1007/s11426-010-4119-4en_HK
dc.identifier.scopuseid_2-s2.0-78049458693en_HK
dc.identifier.hkuros195797en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-78049458693&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume53en_HK
dc.identifier.issue10en_HK
dc.identifier.spage2106en_HK
dc.identifier.epage2111en_HK
dc.identifier.isiWOS:000283396200006-
dc.publisher.placeChinaen_HK
dc.identifier.scopusauthoridMan, WL=7005307944en_HK
dc.identifier.scopusauthoridXiang, J=36467466600en_HK
dc.identifier.scopusauthoridLau, PH=15921593400en_HK
dc.identifier.scopusauthoridGao, S=7403257903en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridLau, TC=7102222310en_HK

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