File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/ol071269r
- Scopus: eid_2-s2.0-35548976772
- PMID: 17880226
- WOS: WOS:000249987200006
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Transition-metal-catalyzed group transfer reactions for selective C-H bond functionalization of artemisinin
Title | Transition-metal-catalyzed group transfer reactions for selective C-H bond functionalization of artemisinin |
---|---|
Authors | |
Issue Date | 2007 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html |
Citation | Organic Letters, 2007, v. 9 n. 21, p. 4107-4110 How to Cite? |
Abstract | Three types of novel artemisinin derivatives have been synthesized through transition-metal-catalyzed intramolecular carbenoid and nitrenoid C-H bond insertion reactions. With rhodium complexes as catalysts, lactone 11 was synthesized via carbene insertion reaction at the C16 position in 90% yield; oxazolidinone 13 was synthesized via nitrene insertion reaction at the C10 position in 87% yield based on 77% conversion; and sulfamidate 14 was synthesized via nitrene insertion reaction at the C8 position in 87% yield. © 2007 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/135047 |
ISSN | 2023 Impact Factor: 4.9 2023 SCImago Journal Rankings: 1.245 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Liu, Y | en_HK |
dc.contributor.author | Xiao, W | en_HK |
dc.contributor.author | Wong, MK | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2011-07-27T01:27:09Z | - |
dc.date.available | 2011-07-27T01:27:09Z | - |
dc.date.issued | 2007 | en_HK |
dc.identifier.citation | Organic Letters, 2007, v. 9 n. 21, p. 4107-4110 | en_HK |
dc.identifier.issn | 1523-7060 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/135047 | - |
dc.description.abstract | Three types of novel artemisinin derivatives have been synthesized through transition-metal-catalyzed intramolecular carbenoid and nitrenoid C-H bond insertion reactions. With rhodium complexes as catalysts, lactone 11 was synthesized via carbene insertion reaction at the C16 position in 90% yield; oxazolidinone 13 was synthesized via nitrene insertion reaction at the C10 position in 87% yield based on 77% conversion; and sulfamidate 14 was synthesized via nitrene insertion reaction at the C8 position in 87% yield. © 2007 American Chemical Society. | en_HK |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/orlef7/index.html | en_HK |
dc.relation.ispartof | Organic Letters | en_HK |
dc.subject.mesh | Antineoplastic Agents - chemical synthesis - chemistry - pharmacology | - |
dc.subject.mesh | Artemisinins - chemical synthesis - chemistry - pharmacology | - |
dc.subject.mesh | Catalysis | - |
dc.subject.mesh | Drug Screening Assays, Antitumor | - |
dc.subject.mesh | Rhodium - chemistry | - |
dc.title | Transition-metal-catalyzed group transfer reactions for selective C-H bond functionalization of artemisinin | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1523-7060&volume=9&issue=21&spage=4107–4110&epage=&date=2007&atitle=Transition-metal-catalyzed+group+transfer+reactions+for+selective+C-H+bond+functionalization+of+artemisinin | en_US |
dc.identifier.email | Liu, Y:lyg100@hku.hk | en_HK |
dc.identifier.email | Che, CM:cmche@hku.hk | en_HK |
dc.identifier.authority | Liu, Y=rp00749 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/ol071269r | en_HK |
dc.identifier.pmid | 17880226 | - |
dc.identifier.scopus | eid_2-s2.0-35548976772 | en_HK |
dc.identifier.hkuros | 188096 | en_US |
dc.identifier.hkuros | 148214 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-35548976772&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 9 | en_HK |
dc.identifier.issue | 21 | en_HK |
dc.identifier.spage | 4107 | en_HK |
dc.identifier.epage | 4110 | en_HK |
dc.identifier.isi | WOS:000249987200006 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Liu, Y=8225912600 | en_HK |
dc.identifier.scopusauthorid | Xiao, W=36901279100 | en_HK |
dc.identifier.scopusauthorid | Wong, MK=7403908449 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 1523-7052 | - |