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Article: Iron-Catalyzed Nitrene Insertion Reaction for Facile Construction of Amide Compounds

TitleIron-Catalyzed Nitrene Insertion Reaction for Facile Construction of Amide Compounds
Authors
Chen, GQXu, ZJLiu, YZhou, CYChe, CM
Keywordsamide
C-H insertion
catalysis
iron
nitrene
Issue Date2011
PublisherGeorg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml
Citation
Synlett, 2011 n. 8, p. 1174-1178 How to Cite?
DOI: http://dx.doi.org/10.1055/s-0030-1260531
AbstractA facile method for the construction of amide compounds from aldehydes by an iron-catalyzed nitrene insertion reaction has been developed. Both aryl and aliphatic aldehydes can directly afford the corresponding amides with an iron(II)-terpyridine (tpy) complex formed in situ as catalyst, and PhI=NTs as nitrogen source under mild reaction conditions. An ESI-MS study revealed the formation of [Fe(tpy)NTs)]+ as a reaction intermediate. © Georg Thieme Verlag Stuttgart - New York.
Persistent Identifierhttp://hdl.handle.net/10722/135045
ISSN
0936-5214
2021 Impact Factor: 2.170
2020 SCImago Journal Rankings: 0.712
ISI Accession Number ID
WOS:000290206600028
Funding AgencyGrant Number
University of Hong Kong
Hong Kong Research Grants CouncilHKU 1/CRF/08
University Grants Council of HKSARAoE 10/01P
CAS-Croucher Funding Scheme for Joint Laboratory
Croucher Foundation of Hong Kong
CAS-GJHZ200816
Funding Information:

We gratefully acknowledge financial support from The University of Hong Kong (University Development Fund), Hong Kong Research Grants Council (HKU 1/CRF/08), the University Grants Council of HKSAR (Area of Excellence Scheme: AoE 10/01P), CAS-GJHZ200816 and CAS-Croucher Funding Scheme for Joint Laboratory. G.-Q. Chen thanks the Croucher Foundation of Hong Kong for a postgraduate studentship.

References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorChen, GQen_HK
dc.contributor.authorXu, ZJen_HK
dc.contributor.authorLiu, Yen_HK
dc.contributor.authorZhou, CYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2011-07-27T01:27:07Z-
dc.date.available2011-07-27T01:27:07Z-
dc.date.issued2011en_HK
dc.identifier.citationSynlett, 2011 n. 8, p. 1174-1178en_HK
dc.identifier.issn0936-5214en_HK
dc.identifier.urihttp://hdl.handle.net/10722/135045-
dc.description.abstractA facile method for the construction of amide compounds from aldehydes by an iron-catalyzed nitrene insertion reaction has been developed. Both aryl and aliphatic aldehydes can directly afford the corresponding amides with an iron(II)-terpyridine (tpy) complex formed in situ as catalyst, and PhI=NTs as nitrogen source under mild reaction conditions. An ESI-MS study revealed the formation of [Fe(tpy)NTs)]+ as a reaction intermediate. © Georg Thieme Verlag Stuttgart - New York.en_HK
dc.languageengen_US
dc.publisherGeorg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtmlen_HK
dc.relation.ispartofSynletten_HK
dc.rightsSYNLETT. Copyright © Georg Thieme Verlag.-
dc.subjectamideen_HK
dc.subjectC-H insertionen_HK
dc.subjectcatalysisen_HK
dc.subjectironen_HK
dc.subjectnitreneen_HK
dc.titleIron-Catalyzed Nitrene Insertion Reaction for Facile Construction of Amide Compoundsen_HK
dc.typeArticleen_HK
dc.identifier.emailLiu, Y:lyg100@hku.hken_HK
dc.identifier.emailZhou, CY:cyzhou@hku.hken_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityLiu, Y=rp00749en_HK
dc.identifier.authorityZhou, CY=rp00843en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturepostprint-
dc.identifier.doi10.1055/s-0030-1260531en_HK
dc.identifier.scopuseid_2-s2.0-79955673935en_HK
dc.identifier.hkuros188049en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-79955673935&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume8en_US
dc.identifier.issue8en_HK
dc.identifier.spage1174en_HK
dc.identifier.epage1178en_HK
dc.identifier.isiWOS:000290206600028-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridChen, GQ=37100986900en_HK
dc.identifier.scopusauthoridXu, ZJ=8708548900en_HK
dc.identifier.scopusauthoridLiu, Y=8225912600en_HK
dc.identifier.scopusauthoridZhou, CY=35742480200en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.issnl0936-5214-

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