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Article: Reactions of H2S with AgCl within a porous coordination network

TitleReactions of H2S with AgCl within a porous coordination network
Authors
Issue Date2010
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2010, v. 49 n. 17, p. 7629-7631 How to Cite?
AbstractA silver(I) sulfide species is now imbedded in a porous coordination network. Such a composite system builds on the molecule tetrakis(methylthio)-1, 4-benzenedicarboxate that holds out the hard carboxylate to europium(III) to form a host net, while taking on AgCl using its soft sulfur side arms. AgCl is then treated with H2S to form the dark-colored Ag2S species, while leaving the hard host net intact and upstanding. This hard-soft duality serves to conjoin the rich electronic flavors of metal chalcogenides and the flexible textures of coordination nets. © 2010 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/134386
ISSN
2014 Impact Factor: 4.762
2014 SCImago Journal Rankings: 1.681
ISI Accession Number ID
Funding AgencyGrant Number
City University of Hong Kong7002321
Research Grants Council of HKSAR9050198 (N_CityU 118/06)
NSF0087210
Ohio Board of RegentsCAP-491
Youngstown State University
Funding Information:

This work wass supported by the City University of Hong Kong (Project 7002321) and the Research Grants Council of HKSAR [Project 9050198 (N_CityU 118/06)]. The single-crystal diffractometer was funded by NSF Grant 0087210, by Ohio Board of Regents Grant CAP-491, and by Youngstown State University.

References

 

DC FieldValueLanguage
dc.contributor.authorZhou, XPen_HK
dc.contributor.authorXu, Zen_HK
dc.contributor.authorZeller, Men_HK
dc.contributor.authorHunter, ADen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorLin, Jen_HK
dc.date.accessioned2011-06-17T09:18:51Z-
dc.date.available2011-06-17T09:18:51Z-
dc.date.issued2010en_HK
dc.identifier.citationInorganic Chemistry, 2010, v. 49 n. 17, p. 7629-7631en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/134386-
dc.description.abstractA silver(I) sulfide species is now imbedded in a porous coordination network. Such a composite system builds on the molecule tetrakis(methylthio)-1, 4-benzenedicarboxate that holds out the hard carboxylate to europium(III) to form a host net, while taking on AgCl using its soft sulfur side arms. AgCl is then treated with H2S to form the dark-colored Ag2S species, while leaving the hard host net intact and upstanding. This hard-soft duality serves to conjoin the rich electronic flavors of metal chalcogenides and the flexible textures of coordination nets. © 2010 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleReactions of H2S with AgCl within a porous coordination networken_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=49&issue=17&spage=7629&epage=7631&date=2010&atitle=Reactions+of+H2S+with+AgCl+within+a+porous+coordination+network-
dc.identifier.emailChui, SSY: chuissy@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic101051ren_HK
dc.identifier.pmid20681564-
dc.identifier.scopuseid_2-s2.0-77956192500en_HK
dc.identifier.hkuros185847en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-77956192500&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume49en_HK
dc.identifier.issue17en_HK
dc.identifier.spage7629en_HK
dc.identifier.epage7631en_HK
dc.identifier.isiWOS:000281231800009-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZhou, XP=7410089784en_HK
dc.identifier.scopusauthoridXu, Z=9843801700en_HK
dc.identifier.scopusauthoridZeller, M=8518298000en_HK
dc.identifier.scopusauthoridHunter, AD=7402779700en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridLin, J=8705985400en_HK
dc.identifier.citeulike7866363-

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