Article: Reactions of H2S with AgCl within a porous coordination network

File Download Links for fulltext
(May Require Subscription)
Supplementary
  • Basic View
  • Metadata View
  • XML View
TitleReactions of H2S with AgCl within a porous coordination network
AuthorsZhou, XP2
Xu, Z2
Zeller, M4
Hunter, AD4
Chui, SSY1
Che, CM1
Lin, J3
Issue Date2010
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
CitationInorganic Chemistry, 2010, v. 49 n. 17, p. 7629-7631 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic101051r
AbstractA silver(I) sulfide species is now imbedded in a porous coordination network. Such a composite system builds on the molecule tetrakis(methylthio)-1, 4-benzenedicarboxate that holds out the hard carboxylate to europium(III) to form a host net, while taking on AgCl using its soft sulfur side arms. AgCl is then treated with H2S to form the dark-colored Ag2S species, while leaving the hard host net intact and upstanding. This hard-soft duality serves to conjoin the rich electronic flavors of metal chalcogenides and the flexible textures of coordination nets. © 2010 American Chemical Society.
ISSN0020-1669
2011 Impact Factor: 4.601
2011 SCImago Journal Rankings: 0.315
DOIhttp://dx.doi.org/10.1021/ic101051r
ISI Accession Number IDWOS:000281231800009
Funding AgencyGrant Number
City University of Hong Kong7002321
Research Grants Council of HKSAR9050198 (N_CityU 118/06)
NSF0087210
Ohio Board of RegentsCAP-491
Youngstown State University
Funding Information:

This work wass supported by the City University of Hong Kong (Project 7002321) and the Research Grants Council of HKSAR [Project 9050198 (N_CityU 118/06)]. The single-crystal diffractometer was funded by NSF Grant 0087210, by Ohio Board of Regents Grant CAP-491, and by Youngstown State University.

ReferencesReferences in Scopus
DC Field
Value
dc.contributor.authorZhou, XP
dc.contributor.authorXu, Z
dc.contributor.authorZeller, M
dc.contributor.authorHunter, AD
dc.contributor.authorChui, SSY
dc.contributor.authorChe, CM
dc.contributor.authorLin, J
dc.date.accessioned2011-06-17T09:18:51Z
dc.date.available2011-06-17T09:18:51Z
dc.date.issued2010
dc.description.abstractA silver(I) sulfide species is now imbedded in a porous coordination network. Such a composite system builds on the molecule tetrakis(methylthio)-1, 4-benzenedicarboxate that holds out the hard carboxylate to europium(III) to form a host net, while taking on AgCl using its soft sulfur side arms. AgCl is then treated with H2S to form the dark-colored Ag2S species, while leaving the hard host net intact and upstanding. This hard-soft duality serves to conjoin the rich electronic flavors of metal chalcogenides and the flexible textures of coordination nets. © 2010 American Chemical Society.
dc.description.natureLink_to_subscribed_fulltext
dc.identifier.citationInorganic Chemistry, 2010, v. 49 n. 17, p. 7629-7631 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic101051r
dc.identifier.citeulike7866363
dc.identifier.doihttp://dx.doi.org/10.1021/ic101051r
dc.identifier.epage7631
dc.identifier.hkuros185847
dc.identifier.isiWOS:000281231800009
Funding AgencyGrant Number
City University of Hong Kong7002321
Research Grants Council of HKSAR9050198 (N_CityU 118/06)
NSF0087210
Ohio Board of RegentsCAP-491
Youngstown State University
Funding Information:

This work wass supported by the City University of Hong Kong (Project 7002321) and the Research Grants Council of HKSAR [Project 9050198 (N_CityU 118/06)]. The single-crystal diffractometer was funded by NSF Grant 0087210, by Ohio Board of Regents Grant CAP-491, and by Youngstown State University.

dc.identifier.issn0020-1669
2011 Impact Factor: 4.601
2011 SCImago Journal Rankings: 0.315
dc.identifier.issue17
dc.identifier.openurl
dc.identifier.pmid20681564
dc.identifier.scopuseid_2-s2.0-77956192500
dc.identifier.spage7629
dc.identifier.urihttp://hdl.handle.net/10722/134386
dc.identifier.volume49
dc.languageeng
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
dc.publisher.placeUnited States
dc.relation.ispartofInorganic Chemistry
dc.relation.referencesReferences in Scopus
dc.titleReactions of H2S with AgCl within a porous coordination network
dc.typeArticle
Author Affiliations
  1. The University of Hong Kong
  2. City University of Hong Kong
  3. College of Chemistry and Molecular Engineering, Peking University
  4. Youngstown State University