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Article: Reactions of H2S with AgCl within a porous coordination network
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TitleReactions of H2S with AgCl within a porous coordination network
 
AuthorsZhou, XP3
Xu, Z3
Zeller, M4
Hunter, AD4
Chui, SSY1
Che, CM1
Lin, J2
 
Issue Date2010
 
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
 
CitationInorganic Chemistry, 2010, v. 49 n. 17, p. 7629-7631 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic101051r
 
AbstractA silver(I) sulfide species is now imbedded in a porous coordination network. Such a composite system builds on the molecule tetrakis(methylthio)-1, 4-benzenedicarboxate that holds out the hard carboxylate to europium(III) to form a host net, while taking on AgCl using its soft sulfur side arms. AgCl is then treated with H2S to form the dark-colored Ag2S species, while leaving the hard host net intact and upstanding. This hard-soft duality serves to conjoin the rich electronic flavors of metal chalcogenides and the flexible textures of coordination nets. © 2010 American Chemical Society.
 
ISSN0020-1669
2012 Impact Factor: 4.593
2012 SCImago Journal Rankings: 1.778
 
DOIhttp://dx.doi.org/10.1021/ic101051r
 
ISI Accession Number IDWOS:000281231800009
Funding AgencyGrant Number
City University of Hong Kong7002321
Research Grants Council of HKSAR9050198 (N_CityU 118/06)
NSF0087210
Ohio Board of RegentsCAP-491
Youngstown State University
Funding Information:

This work wass supported by the City University of Hong Kong (Project 7002321) and the Research Grants Council of HKSAR [Project 9050198 (N_CityU 118/06)]. The single-crystal diffractometer was funded by NSF Grant 0087210, by Ohio Board of Regents Grant CAP-491, and by Youngstown State University.

 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorZhou, XP
 
dc.contributor.authorXu, Z
 
dc.contributor.authorZeller, M
 
dc.contributor.authorHunter, AD
 
dc.contributor.authorChui, SSY
 
dc.contributor.authorChe, CM
 
dc.contributor.authorLin, J
 
dc.date.accessioned2011-06-17T09:18:51Z
 
dc.date.available2011-06-17T09:18:51Z
 
dc.date.issued2010
 
dc.description.abstractA silver(I) sulfide species is now imbedded in a porous coordination network. Such a composite system builds on the molecule tetrakis(methylthio)-1, 4-benzenedicarboxate that holds out the hard carboxylate to europium(III) to form a host net, while taking on AgCl using its soft sulfur side arms. AgCl is then treated with H2S to form the dark-colored Ag2S species, while leaving the hard host net intact and upstanding. This hard-soft duality serves to conjoin the rich electronic flavors of metal chalcogenides and the flexible textures of coordination nets. © 2010 American Chemical Society.
 
dc.description.natureLink_to_subscribed_fulltext
 
dc.identifier.citationInorganic Chemistry, 2010, v. 49 n. 17, p. 7629-7631 [How to Cite?]
DOI: http://dx.doi.org/10.1021/ic101051r
 
dc.identifier.citeulike7866363
 
dc.identifier.doihttp://dx.doi.org/10.1021/ic101051r
 
dc.identifier.epage7631
 
dc.identifier.hkuros185847
 
dc.identifier.isiWOS:000281231800009
Funding AgencyGrant Number
City University of Hong Kong7002321
Research Grants Council of HKSAR9050198 (N_CityU 118/06)
NSF0087210
Ohio Board of RegentsCAP-491
Youngstown State University
Funding Information:

This work wass supported by the City University of Hong Kong (Project 7002321) and the Research Grants Council of HKSAR [Project 9050198 (N_CityU 118/06)]. The single-crystal diffractometer was funded by NSF Grant 0087210, by Ohio Board of Regents Grant CAP-491, and by Youngstown State University.

 
dc.identifier.issn0020-1669
2012 Impact Factor: 4.593
2012 SCImago Journal Rankings: 1.778
 
dc.identifier.issue17
 
dc.identifier.openurl
 
dc.identifier.pmid20681564
 
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dc.identifier.urihttp://hdl.handle.net/10722/134386
 
dc.identifier.volume49
 
dc.languageeng
 
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
 
dc.publisher.placeUnited States
 
dc.relation.ispartofInorganic Chemistry
 
dc.relation.referencesReferences in Scopus
 
dc.titleReactions of H2S with AgCl within a porous coordination network
 
dc.typeArticle
 
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Author Affiliations
  1. The University of Hong Kong
  2. College of Chemistry and Molecular Engineering, Peking University
  3. City University of Hong Kong
  4. Youngstown State University