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Article: Where is the heavy-atom effect? role of the central ligand in tetragold(i) ethynyl complexes

TitleWhere is the heavy-atom effect? role of the central ligand in tetragold(i) ethynyl complexes
Authors
Keywordsdensity functional calculations
gold
luminescence
photophysics
Issue Date2010
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2010, v. 49 n. 48, p. 9206-9209 How to Cite?
AbstractHe ain't heavy: The heavy-atom effect is not the sole factor that determines the efficiency of intersystem crossing and triplet radiative decay rates. Theoretical calculations along with experimental evidence show that the central ligand plays a decisive role in the luminescence behavior of tetragold(I) ethynyl complexes (see structures and representations of the highest occupied molecular orbitals). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/134349
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID
Funding AgencyGrant Number
University of Hong KongAoE/P-03/08
Funding Information:

We would like to thank the University Development Fund and the AoE (Area of Excellence Scheme) Program of the University of Hong Kong (Project No. [AoE/P-03/08]) for financial support. We also thank the Computer Centre at the University of Hong Kong for providing supercomputers.

References
Grants

 

DC FieldValueLanguage
dc.contributor.authorTong, GSMen_HK
dc.contributor.authorChow, PKen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2011-06-17T09:18:27Z-
dc.date.available2011-06-17T09:18:27Z-
dc.date.issued2010en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2010, v. 49 n. 48, p. 9206-9209en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/134349-
dc.description.abstractHe ain't heavy: The heavy-atom effect is not the sole factor that determines the efficiency of intersystem crossing and triplet radiative decay rates. Theoretical calculations along with experimental evidence show that the central ligand plays a decisive role in the luminescence behavior of tetragold(I) ethynyl complexes (see structures and representations of the highest occupied molecular orbitals). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectdensity functional calculationsen_HK
dc.subjectgolden_HK
dc.subjectluminescenceen_HK
dc.subjectphotophysicsen_HK
dc.titleWhere is the heavy-atom effect? role of the central ligand in tetragold(i) ethynyl complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=49&issue=48&spage=9206&epage=9209&date=2010&atitle=Where+is+the+heavy-atom+effect?+Role+of+the+central+ligand+in+tetragold(I)+ethynyl+complexes-
dc.identifier.emailTong, GSM:tongsm@hkucc.hku.hken_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityTong, GSM=rp00790en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201004601en_HK
dc.identifier.pmid20967916-
dc.identifier.scopuseid_2-s2.0-78649622543en_HK
dc.identifier.hkuros185598en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-78649622543&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume49en_HK
dc.identifier.issue48en_HK
dc.identifier.spage9206en_HK
dc.identifier.epage9209en_HK
dc.identifier.isiWOS:000284711800029-
dc.publisher.placeGermanyen_HK
dc.relation.projectInstitute of Molecular Functional Materials-
dc.identifier.scopusauthoridTong, GSM=7102328656en_HK
dc.identifier.scopusauthoridChow, PK=36683876600en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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