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- Publisher Website: 10.1002/anie.201004601
- Scopus: eid_2-s2.0-78649622543
- PMID: 20967916
- WOS: WOS:000284711800029
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Article: Where is the heavy-atom effect? role of the central ligand in tetragold(i) ethynyl complexes
| Title | Where is the heavy-atom effect? role of the central ligand in tetragold(i) ethynyl complexes | ||||
|---|---|---|---|---|---|
| Authors | |||||
| Keywords | density functional calculations gold luminescence photophysics | ||||
| Issue Date | 2010 | ||||
| Publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | ||||
| Citation | Angewandte Chemie - International Edition, 2010, v. 49 n. 48, p. 9206-9209 How to Cite? | ||||
| Abstract | He ain't heavy: The heavy-atom effect is not the sole factor that determines the efficiency of intersystem crossing and triplet radiative decay rates. Theoretical calculations along with experimental evidence show that the central ligand plays a decisive role in the luminescence behavior of tetragold(I) ethynyl complexes (see structures and representations of the highest occupied molecular orbitals). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | ||||
| Persistent Identifier | http://hdl.handle.net/10722/134349 | ||||
| ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 | ||||
| ISI Accession Number ID |
Funding Information: We would like to thank the University Development Fund and the AoE (Area of Excellence Scheme) Program of the University of Hong Kong (Project No. [AoE/P-03/08]) for financial support. We also thank the Computer Centre at the University of Hong Kong for providing supercomputers. | ||||
| References | |||||
| Grants |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Tong, GSM | en_HK |
| dc.contributor.author | Chow, PK | en_HK |
| dc.contributor.author | Che, CM | en_HK |
| dc.date.accessioned | 2011-06-17T09:18:27Z | - |
| dc.date.available | 2011-06-17T09:18:27Z | - |
| dc.date.issued | 2010 | en_HK |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2010, v. 49 n. 48, p. 9206-9209 | en_HK |
| dc.identifier.issn | 1433-7851 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/134349 | - |
| dc.description.abstract | He ain't heavy: The heavy-atom effect is not the sole factor that determines the efficiency of intersystem crossing and triplet radiative decay rates. Theoretical calculations along with experimental evidence show that the central ligand plays a decisive role in the luminescence behavior of tetragold(I) ethynyl complexes (see structures and representations of the highest occupied molecular orbitals). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | en_HK |
| dc.language | eng | en_US |
| dc.publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | en_HK |
| dc.relation.ispartof | Angewandte Chemie - International Edition | en_HK |
| dc.subject | density functional calculations | en_HK |
| dc.subject | gold | en_HK |
| dc.subject | luminescence | en_HK |
| dc.subject | photophysics | en_HK |
| dc.title | Where is the heavy-atom effect? role of the central ligand in tetragold(i) ethynyl complexes | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1433-7851&volume=49&issue=48&spage=9206&epage=9209&date=2010&atitle=Where+is+the+heavy-atom+effect?+Role+of+the+central+ligand+in+tetragold(I)+ethynyl+complexes | - |
| dc.identifier.email | Tong, GSM:tongsm@hkucc.hku.hk | en_HK |
| dc.identifier.email | Che, CM:cmche@hku.hk | en_HK |
| dc.identifier.authority | Tong, GSM=rp00790 | en_HK |
| dc.identifier.authority | Che, CM=rp00670 | en_HK |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.201004601 | en_HK |
| dc.identifier.pmid | 20967916 | - |
| dc.identifier.scopus | eid_2-s2.0-78649622543 | en_HK |
| dc.identifier.hkuros | 185598 | en_US |
| dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-78649622543&selection=ref&src=s&origin=recordpage | en_HK |
| dc.identifier.volume | 49 | en_HK |
| dc.identifier.issue | 48 | en_HK |
| dc.identifier.spage | 9206 | en_HK |
| dc.identifier.epage | 9209 | en_HK |
| dc.identifier.isi | WOS:000284711800029 | - |
| dc.publisher.place | Germany | en_HK |
| dc.relation.project | Institute of Molecular Functional Materials | - |
| dc.identifier.scopusauthorid | Tong, GSM=7102328656 | en_HK |
| dc.identifier.scopusauthorid | Chow, PK=36683876600 | en_HK |
| dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
| dc.identifier.issnl | 1433-7851 | - |