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Article: Synthesis, characterisation and photophysical study of alkynylrhenium(I) tricarbonyl diimine complexes and their metal-ion coordination-assisted metallogelation properties

TitleSynthesis, characterisation and photophysical study of alkynylrhenium(I) tricarbonyl diimine complexes and their metal-ion coordination-assisted metallogelation properties
Authors
KeywordsCopper
Diimines
Gelation
Photophysics
Rhenium
Silver
Issue Date2010
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry
Citation
Chemistry - A European Journal, 2010, v. 16 n. 38, p. 11588-11593 How to Cite?
AbstractA series of alkynylrhenium(I) tricarbonyl diimine complexes has been synthesized and characterized. A blue shift of the intense lowenergy MLCT absorption band in the visible region was observed upon coordination of Cu I or AgI. This class of complexes has been found to show rich thermotropic gelation behaviour upon CuI or AgI coordination with their morphology characterized by SEM. Their variable-temperature UV/Vis absorption and emission properties have also been studied. A blue shift in the MLCT absorption band and the switching on of luminescence were observed upon sol-gel transition. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/133595
ISSN
2015 Impact Factor: 5.771
2015 SCImago Journal Rankings: 2.323
ISI Accession Number ID
Funding AgencyGrant Number
University of Hong Kong
University Grants CommitteeAoE/P-03/08
Research Grants Council of Hong Kong Special Administrative Region, ChinaHKU 7060/09P
Funding Information:

V.W.-W.Y. acknowledges support from The University of Hong Kong under the Distinguished Research Achievement Award Scheme. This work has been supported by the University Grants Committee Areas of Excellence Scheme (AoE/P-03/08) and a GRF grant from the Research Grants Council of Hong Kong Special Administrative Region, China (HKU 7060/09P). S.-T.L. acknowledges the receipt of a postgraduate studentship from The University of Hong Kong.

References
Grants

 

DC FieldValueLanguage
dc.contributor.authorLam, STen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2011-05-24T02:11:34Z-
dc.date.available2011-05-24T02:11:34Z-
dc.date.issued2010en_HK
dc.identifier.citationChemistry - A European Journal, 2010, v. 16 n. 38, p. 11588-11593en_HK
dc.identifier.issn0947-6539en_HK
dc.identifier.urihttp://hdl.handle.net/10722/133595-
dc.description.abstractA series of alkynylrhenium(I) tricarbonyl diimine complexes has been synthesized and characterized. A blue shift of the intense lowenergy MLCT absorption band in the visible region was observed upon coordination of Cu I or AgI. This class of complexes has been found to show rich thermotropic gelation behaviour upon CuI or AgI coordination with their morphology characterized by SEM. Their variable-temperature UV/Vis absorption and emission properties have also been studied. A blue shift in the MLCT absorption band and the switching on of luminescence were observed upon sol-gel transition. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistryen_HK
dc.relation.ispartofChemistry - A European Journalen_HK
dc.subjectCopperen_HK
dc.subjectDiiminesen_HK
dc.subjectGelationen_HK
dc.subjectPhotophysicsen_HK
dc.subjectRheniumen_HK
dc.subjectSilveren_HK
dc.titleSynthesis, characterisation and photophysical study of alkynylrhenium(I) tricarbonyl diimine complexes and their metal-ion coordination-assisted metallogelation propertiesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0947-6539&volume=16&issue=38&spage=11588&epage=11593&date=2010&atitle=Synthesis,+characterisation+and+photophysical+study+of+alkynylrhenium(i)+tricarbonyl+diimine+complexes+and+their+metal-ion+coordination-assisted+metallogelation+properties-
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/chem.201001566en_HK
dc.identifier.pmid20853290-
dc.identifier.scopuseid_2-s2.0-77957592546en_HK
dc.identifier.hkuros185270en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-77957592546&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume16en_HK
dc.identifier.issue38en_HK
dc.identifier.spage11588en_HK
dc.identifier.epage11593en_HK
dc.identifier.isiWOS:000283634900014-
dc.publisher.placeGermanyen_HK
dc.relation.projectInstitute of Molecular Functional Materials-
dc.identifier.scopusauthoridLam, ST=25228930700en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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