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Article: Synthesis of metallic nanostructures using chemical fluid deposition
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TitleSynthesis of metallic nanostructures using chemical fluid deposition
 
AuthorsLin, CS2
Lam, FLY2
Hu, X2
Tam, WY1
Ng, KM2
 
KeywordsAspect Ratio
Carbon Dioxide
Effluent Treatment
Electric Wire
Industrial Waste Treatment
Metal Casting
Metals
Nanostructured Materials
Nanostructures
Nanowires
Phase Diagrams
Platinum
Platinum Metals
Silica
Silicate Minerals
Silicon Compounds
Supercritical Fluids
Synthesis (Chemical)
 
Issue Date2008
 
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jpccck/
 
CitationJournal Of Physical Chemistry C, 2008, v. 112 n. 27, p. 10068-10072 [How to Cite?]
DOI: http://dx.doi.org/10.1021/jp801845q
 
AbstractWe report the synthesis of metallic nanostructures by a chemical fluid deposition method using carbon dioxide supercritical fluid as the reaction medium. Ordered platinum nanowires were molded out from a mesoporous silica template, SBA-15, with a pore channel diameter of 7 nm. A solubility study of the platinum precursor, platinum(II) dimethylcyclooctadiene, in the supercritical carbon dioxide was carried out to obtain a phase diagram in order to optimize the operating parameters required for the metal deposition process. High-purity and uniform nanowires with large aspect ratios were obtained at moderate temperatures and pressures. © 2008 American Chemical Society.
 
ISSN1932-7447
2013 Impact Factor: 4.835
 
DOIhttp://dx.doi.org/10.1021/jp801845q
 
ISI Accession Number IDWOS:000257335300019
 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorLin, CS
 
dc.contributor.authorLam, FLY
 
dc.contributor.authorHu, X
 
dc.contributor.authorTam, WY
 
dc.contributor.authorNg, KM
 
dc.date.accessioned2011-03-28T09:23:50Z
 
dc.date.available2011-03-28T09:23:50Z
 
dc.date.issued2008
 
dc.description.abstractWe report the synthesis of metallic nanostructures by a chemical fluid deposition method using carbon dioxide supercritical fluid as the reaction medium. Ordered platinum nanowires were molded out from a mesoporous silica template, SBA-15, with a pore channel diameter of 7 nm. A solubility study of the platinum precursor, platinum(II) dimethylcyclooctadiene, in the supercritical carbon dioxide was carried out to obtain a phase diagram in order to optimize the operating parameters required for the metal deposition process. High-purity and uniform nanowires with large aspect ratios were obtained at moderate temperatures and pressures. © 2008 American Chemical Society.
 
dc.description.naturelink_to_subscribed_fulltext
 
dc.identifier.citationJournal Of Physical Chemistry C, 2008, v. 112 n. 27, p. 10068-10072 [How to Cite?]
DOI: http://dx.doi.org/10.1021/jp801845q
 
dc.identifier.doihttp://dx.doi.org/10.1021/jp801845q
 
dc.identifier.eissn1932-7455
 
dc.identifier.epage10072
 
dc.identifier.isiWOS:000257335300019
 
dc.identifier.issn1932-7447
2013 Impact Factor: 4.835
 
dc.identifier.issue27
 
dc.identifier.scopuseid_2-s2.0-49249100557
 
dc.identifier.spage10068
 
dc.identifier.urihttp://hdl.handle.net/10722/132376
 
dc.identifier.volume112
 
dc.languageeng
 
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jpccck/
 
dc.publisher.placeUnited States
 
dc.relation.ispartofJournal of Physical Chemistry C
 
dc.relation.referencesReferences in Scopus
 
dc.subjectAspect Ratio
 
dc.subjectCarbon Dioxide
 
dc.subjectEffluent Treatment
 
dc.subjectElectric Wire
 
dc.subjectIndustrial Waste Treatment
 
dc.subjectMetal Casting
 
dc.subjectMetals
 
dc.subjectNanostructured Materials
 
dc.subjectNanostructures
 
dc.subjectNanowires
 
dc.subjectPhase Diagrams
 
dc.subjectPlatinum
 
dc.subjectPlatinum Metals
 
dc.subjectSilica
 
dc.subjectSilicate Minerals
 
dc.subjectSilicon Compounds
 
dc.subjectSupercritical Fluids
 
dc.subjectSynthesis (Chemical)
 
dc.titleSynthesis of metallic nanostructures using chemical fluid deposition
 
dc.typeArticle
 
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<contributor.author>Ng, KM</contributor.author>
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<description.abstract>We report the synthesis of metallic nanostructures by a chemical fluid deposition method using carbon dioxide supercritical fluid as the reaction medium. Ordered platinum nanowires were molded out from a mesoporous silica template, SBA-15, with a pore channel diameter of 7 nm. A solubility study of the platinum precursor, platinum(II) dimethylcyclooctadiene, in the supercritical carbon dioxide was carried out to obtain a phase diagram in order to optimize the operating parameters required for the metal deposition process. High-purity and uniform nanowires with large aspect ratios were obtained at moderate temperatures and pressures. &#169; 2008 American Chemical Society.</description.abstract>
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<subject>Aspect Ratio</subject>
<subject>Carbon Dioxide</subject>
<subject>Effluent Treatment</subject>
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<subject>Industrial Waste Treatment</subject>
<subject>Metal Casting</subject>
<subject>Metals</subject>
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Author Affiliations
  1. Hong Kong University of Science and Technology, William Mong Institute of Nano Science &amp; Technology
  2. Hong Kong University of Science and Technology