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Article: Synthesis and photovoltaic properties of novel alternating phenylenevinylene or fluorenevinylene copolymers containing perylene bisimide

TitleSynthesis and photovoltaic properties of novel alternating phenylenevinylene or fluorenevinylene copolymers containing perylene bisimide
Authors
KeywordsConjugated polymers
Fluorenevinylene
Perylene bisimide
Phenylenevinylene
Photophysics
Polymer solar cells
Synthesis
Issue Date2010
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/react
Citation
Reactive And Functional Polymers, 2010, v. 70 n. 7, p. 426-432 How to Cite?
AbstractTwo novel alternating phenylenevinylene copolymers P6 and P12 as well as one fluorenevinylene copolymer F connected at the 1,7 bay positions with perylene bisimide were synthesized by Heck coupling. They were characterized by GPC, FT-IR, 1H NMR, TGA, TMA, UV-vis, cyclic voltammetry and photoluminescence (PL) emission spectra. The copolymers were soluble in common organic solvents and thermally stable up to ∼300 °C. Their glass transition temperatures were 48-60 °C. The long wavelength absorption maximum was located at 510-542 nm with optical band gaps of ∼2.0 eV. The PL emission maximum of P6 and P12 was red-shifted relative to F. The photovoltaic performance of P6, P12 and F was also investigated. © 2010 Elsevier Ltd. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/129344
ISSN
2015 Impact Factor: 2.725
2015 SCImago Journal Rankings: 0.800
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorMikroyannidis, JAen_HK
dc.contributor.authorCheung, KYen_HK
dc.contributor.authorFung, MKen_HK
dc.contributor.authorDjurišić, ABen_HK
dc.date.accessioned2010-12-23T08:35:41Z-
dc.date.available2010-12-23T08:35:41Z-
dc.date.issued2010en_HK
dc.identifier.citationReactive And Functional Polymers, 2010, v. 70 n. 7, p. 426-432en_HK
dc.identifier.issn1381-5148en_HK
dc.identifier.urihttp://hdl.handle.net/10722/129344-
dc.description.abstractTwo novel alternating phenylenevinylene copolymers P6 and P12 as well as one fluorenevinylene copolymer F connected at the 1,7 bay positions with perylene bisimide were synthesized by Heck coupling. They were characterized by GPC, FT-IR, 1H NMR, TGA, TMA, UV-vis, cyclic voltammetry and photoluminescence (PL) emission spectra. The copolymers were soluble in common organic solvents and thermally stable up to ∼300 °C. Their glass transition temperatures were 48-60 °C. The long wavelength absorption maximum was located at 510-542 nm with optical band gaps of ∼2.0 eV. The PL emission maximum of P6 and P12 was red-shifted relative to F. The photovoltaic performance of P6, P12 and F was also investigated. © 2010 Elsevier Ltd. All rights reserved.en_HK
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/reacten_HK
dc.relation.ispartofReactive and Functional Polymersen_HK
dc.subjectConjugated polymersen_HK
dc.subjectFluorenevinyleneen_HK
dc.subjectPerylene bisimideen_HK
dc.subjectPhenylenevinyleneen_HK
dc.subjectPhotophysicsen_HK
dc.subjectPolymer solar cellsen_HK
dc.subjectSynthesisen_HK
dc.titleSynthesis and photovoltaic properties of novel alternating phenylenevinylene or fluorenevinylene copolymers containing perylene bisimideen_HK
dc.typeArticleen_HK
dc.identifier.emailDjurišić, AB: dalek@hku.hken_HK
dc.identifier.authorityDjurišić, AB=rp00690en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.reactfunctpolym.2010.04.005en_HK
dc.identifier.scopuseid_2-s2.0-77955255940en_HK
dc.identifier.hkuros176960en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-77955255940&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume70en_HK
dc.identifier.issue7en_HK
dc.identifier.spage426en_HK
dc.identifier.epage432en_HK
dc.identifier.isiWOS:000279038200006-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridMikroyannidis, JA=7004509172en_HK
dc.identifier.scopusauthoridCheung, KY=25229974800en_HK
dc.identifier.scopusauthoridFung, MK=35191896100en_HK
dc.identifier.scopusauthoridDjurišić, AB=7004904830en_HK
dc.identifier.citeulike7109120-

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