Article: Photocatalytic decomposition of 4-t-octylphenol over NaBiO 3 driven by visible light: Catalytic kinetics and corrosion products characterization
| Title | Photocatalytic decomposition of 4-t-octylphenol over NaBiO 3 driven by visible light: Catalytic kinetics and corrosion products characterization | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| Authors | Chang, X1 4 Huang, J4 Cheng, C3 Sha, W2 Li, X4 Ji, G1 Deng, S4 Yu, G4 | ||||||||
| Keywords | 4-t-Octylphenol BiOCl NaBiO 3 Photocatalysis | ||||||||
| Issue Date | 2010 | ||||||||
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/jhazmat | ||||||||
| Citation | Journal Of Hazardous Materials, 2010, v. 173 n. 1-3, p. 765-772 [How to Cite?] DOI: http://dx.doi.org/10.1016/j.jhazmat.2009.08.148 | ||||||||
| Abstract | The photocatalytic decomposition of 4-t-octylphenol (4-t-OP) by NaBiO 3 photocatalyst and the catalyst stability in aqueous solution were investigated systematically for the first time. The results showed that some parameters such as catalyst dosage, initial 4-t-OP concentration and pH value of the solution had great effects on the photocatalytic activity. The NaBiO 3 photocatalyst maintained considerable catalytic performance under visible light (λ > 400 nm) irradiation and exhibited a higher photocatalytic activity compared to the commercialized photocatalyst P25. In addition, the corrosion products of NaBiO 3 catalyst under acid condition (HCl aqueous solution contained) were characterized by X-ray diffraction (XRD), transmittance electronic microscopy (TEM), selected area electron diffraction (SAED), X-ray photoelectron spectroscopy (XPS) and UV-vis transmittance spectrum analysis. The results showed that NaBiO 3 was unstable under the acidic condition and the catalyst could convert into Bi 3+-containing compounds such as Bi 2O 3, etc. The experiment demonstrates that NaBiO 3 can be corroded to nano-sized BiOCl crystal in the presence of hydrogen chloride, the band gap of which was estimated to be 3.28 eV by Tauc's approach. © 2009 Elsevier B.V. All rights reserved. | ||||||||
| ISSN | 0304-3894 2011 Impact Factor: 4.173 2011 SCImago Journal Rankings: 0.179 | ||||||||
| DOI | http://dx.doi.org/10.1016/j.jhazmat.2009.08.148 | ||||||||
| ISI Accession Number ID | WOS:000273135600108
Funding Information: This research was financially supported by National Natural Science Foundation of China (No. 50538090), National Science Fund for Distinguished Young Scholars of China (No. 50625823), and National Key Project of Scientific and Technical Supporting Programs (No. 2007BAC03A09). | ||||||||
| References | References in Scopus |
| dc.contributor.author | Chang, X | ||||||||
|---|---|---|---|---|---|---|---|---|---|
| dc.contributor.author | Huang, J | ||||||||
| dc.contributor.author | Cheng, C | ||||||||
| dc.contributor.author | Sha, W | ||||||||
| dc.contributor.author | Li, X | ||||||||
| dc.contributor.author | Ji, G | ||||||||
| dc.contributor.author | Deng, S | ||||||||
| dc.contributor.author | Yu, G | ||||||||
| dc.date.accessioned | 2010-10-31T10:48:41Z | ||||||||
| dc.date.available | 2010-10-31T10:48:41Z | ||||||||
| dc.date.issued | 2010 | ||||||||
| dc.description.abstract | The photocatalytic decomposition of 4-t-octylphenol (4-t-OP) by NaBiO 3 photocatalyst and the catalyst stability in aqueous solution were investigated systematically for the first time. The results showed that some parameters such as catalyst dosage, initial 4-t-OP concentration and pH value of the solution had great effects on the photocatalytic activity. The NaBiO 3 photocatalyst maintained considerable catalytic performance under visible light (λ > 400 nm) irradiation and exhibited a higher photocatalytic activity compared to the commercialized photocatalyst P25. In addition, the corrosion products of NaBiO 3 catalyst under acid condition (HCl aqueous solution contained) were characterized by X-ray diffraction (XRD), transmittance electronic microscopy (TEM), selected area electron diffraction (SAED), X-ray photoelectron spectroscopy (XPS) and UV-vis transmittance spectrum analysis. The results showed that NaBiO 3 was unstable under the acidic condition and the catalyst could convert into Bi 3+-containing compounds such as Bi 2O 3, etc. The experiment demonstrates that NaBiO 3 can be corroded to nano-sized BiOCl crystal in the presence of hydrogen chloride, the band gap of which was estimated to be 3.28 eV by Tauc's approach. © 2009 Elsevier B.V. All rights reserved. | ||||||||
| dc.description.nature | postprint | ||||||||
| dc.identifier.citation | Journal Of Hazardous Materials, 2010, v. 173 n. 1-3, p. 765-772 [How to Cite?] DOI: http://dx.doi.org/10.1016/j.jhazmat.2009.08.148 | ||||||||
| dc.identifier.citeulike | 5760033 | ||||||||
| dc.identifier.doi | http://dx.doi.org/10.1016/j.jhazmat.2009.08.148 | ||||||||
| dc.identifier.epage | 772 | ||||||||
| dc.identifier.hkuros | 176058 | ||||||||
| dc.identifier.isi | WOS:000273135600108
Funding Information: This research was financially supported by National Natural Science Foundation of China (No. 50538090), National Science Fund for Distinguished Young Scholars of China (No. 50625823), and National Key Project of Scientific and Technical Supporting Programs (No. 2007BAC03A09). | ||||||||
| dc.identifier.issn | 0304-3894 2011 Impact Factor: 4.173 2011 SCImago Journal Rankings: 0.179 | ||||||||
| dc.identifier.issue | 1-3 | ||||||||
| dc.identifier.openurl | ![]() | ||||||||
| dc.identifier.pmid | 19800168 | ||||||||
| dc.identifier.scopus | eid_2-s2.0-71749106659 | ||||||||
| dc.identifier.spage | 765 | ||||||||
| dc.identifier.uri | http://hdl.handle.net/10722/124690 | ||||||||
| dc.identifier.volume | 173 | ||||||||
| dc.language | eng | ||||||||
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/jhazmat | ||||||||
| dc.publisher.place | Netherlands | ||||||||
| dc.relation.ispartof | Journal of Hazardous Materials | ||||||||
| dc.relation.references | References in Scopus | ||||||||
| dc.rights | Creative Commons: Attribution 3.0 Hong Kong License | ||||||||
| dc.subject.mesh | Bismuth - chemistry | ||||||||
| dc.subject.mesh | Catalysis | ||||||||
| dc.subject.mesh | Hydrochloric Acid - chemistry | ||||||||
| dc.subject.mesh | Microscopy, Electron, Transmission | ||||||||
| dc.subject.mesh | Phenols - chemistry | ||||||||
| dc.subject | 4-t-Octylphenol | ||||||||
| dc.subject | BiOCl | ||||||||
| dc.subject | NaBiO 3 | ||||||||
| dc.subject | Photocatalysis | ||||||||
| dc.title | Photocatalytic decomposition of 4-t-octylphenol over NaBiO 3 driven by visible light: Catalytic kinetics and corrosion products characterization | ||||||||
| dc.type | Article |
Author Affiliations
- Nanjing University of Aeronautics and Astronautics
- The University of Hong Kong
- Loughborough University
- Tsinghua University


