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Article: A novel polymeric silver(I) complex with a one-dimensional chain structure

TitleA novel polymeric silver(I) complex with a one-dimensional chain structure
Authors
KeywordsCrystal structures
One-dimensional chain
Silver(I) complexes
Thiolate complexes
Issue Date1999
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche
Citation
Inorganic Chemistry Communications, 1999, v. 2 n. 6, p. 241-243 How to Cite?
AbstractThe polymeric silver(I)-thiolate complex [Ag6(μ3-SC4N2H3) 4(μ2-SC4N2H3) 2]n has been prepared from the assembly reaction of AgSCN and sodium pyrimidine-2-thiolate in DMF. X-ray diffraction analyses show that the complex exhibits a one-dimensional chain structure with the metal atom core arranged in distorted tetrahedra sharing apexes. The pyrimidime-2-thiolate ligands in the chain act as both bridging and chelating ligands linking either two- or three-silver(I) centers. The coordination environment of each Ag(I) in the complex is either a distorted tetrahedron of S3N or a triangle of S2N.
Persistent Identifierhttp://hdl.handle.net/10722/122020
ISSN
2015 Impact Factor: 1.762
2015 SCImago Journal Rankings: 0.489
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorSu, Wen_HK
dc.contributor.authorCao, Ren_HK
dc.contributor.authorHong, Men_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorLu, Jen_HK
dc.date.accessioned2010-09-26T10:58:10Z-
dc.date.available2010-09-26T10:58:10Z-
dc.date.issued1999en_HK
dc.identifier.citationInorganic Chemistry Communications, 1999, v. 2 n. 6, p. 241-243en_HK
dc.identifier.issn1387-7003en_HK
dc.identifier.urihttp://hdl.handle.net/10722/122020-
dc.description.abstractThe polymeric silver(I)-thiolate complex [Ag6(μ3-SC4N2H3) 4(μ2-SC4N2H3) 2]n has been prepared from the assembly reaction of AgSCN and sodium pyrimidine-2-thiolate in DMF. X-ray diffraction analyses show that the complex exhibits a one-dimensional chain structure with the metal atom core arranged in distorted tetrahedra sharing apexes. The pyrimidime-2-thiolate ligands in the chain act as both bridging and chelating ligands linking either two- or three-silver(I) centers. The coordination environment of each Ag(I) in the complex is either a distorted tetrahedron of S3N or a triangle of S2N.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inocheen_HK
dc.relation.ispartofInorganic Chemistry Communicationsen_HK
dc.subjectCrystal structuresen_HK
dc.subjectOne-dimensional chainen_HK
dc.subjectSilver(I) complexesen_HK
dc.subjectThiolate complexesen_HK
dc.titleA novel polymeric silver(I) complex with a one-dimensional chain structureen_HK
dc.typeArticleen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S1387-7003(99)00058-1-
dc.identifier.scopuseid_2-s2.0-0033447270en_HK
dc.identifier.hkuros56919en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0033447270&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume2en_HK
dc.identifier.issue6en_HK
dc.identifier.spage241en_HK
dc.identifier.epage243en_HK
dc.identifier.isiWOS:000081166900006-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridSu, W=7402010403en_HK
dc.identifier.scopusauthoridCao, R=7103341331en_HK
dc.identifier.scopusauthoridHong, M=7402688147en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridLu, J=7601560287en_HK

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