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Article: Molecular Belts and Collars in the Making: A Hexaepoxyoctacosahydro[12]cyclacene Derivative

TitleMolecular Belts and Collars in the Making: A Hexaepoxyoctacosahydro[12]cyclacene Derivative
Authors
Kohnke, Franz H.Slawin, Alexandra M.Z.Stoddart, J. FraserWilliams, David J.
Issue Date1987
Citation
Angewandte Chemie International Edition in English, 1987, v. 26, n. 9, p. 892-894 How to Cite?
DOI: http://dx.doi.org/10.1002/anie.198708921
AbstractRepeated Diels–Alder reactions of the suitably curved and stiff reactants 1 and 2 furnish, via the central intermediate 3, the intellectually appealing title (and cover page) compound. In the last step of the synthesis, 3 is allowed to react with 2 under high pressure (9–10 kbar). The yield is nevertheless 20%. The Diels–Alder reactions are remarkably stereoselective, the intermediates are topologically extremely interesting, and the final product—it speaks for itself. (Figure Presented.) Copyright © 1987 by VCH Verlagsgesellschaft mbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/333205
ISSN
0570-0833
ISI Accession Number ID
WOS:A1987K569300010

 

DC FieldValueLanguage
dc.contributor.authorKohnke, Franz H.-
dc.contributor.authorSlawin, Alexandra M.Z.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:17:30Z-
dc.date.available2023-10-06T05:17:30Z-
dc.date.issued1987-
dc.identifier.citationAngewandte Chemie International Edition in English, 1987, v. 26, n. 9, p. 892-894-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/333205-
dc.description.abstractRepeated Diels–Alder reactions of the suitably curved and stiff reactants 1 and 2 furnish, via the central intermediate 3, the intellectually appealing title (and cover page) compound. In the last step of the synthesis, 3 is allowed to react with 2 under high pressure (9–10 kbar). The yield is nevertheless 20%. The Diels–Alder reactions are remarkably stereoselective, the intermediates are topologically extremely interesting, and the final product—it speaks for itself. (Figure Presented.) Copyright © 1987 by VCH Verlagsgesellschaft mbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.titleMolecular Belts and Collars in the Making: A Hexaepoxyoctacosahydro[12]cyclacene Derivative-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.198708921-
dc.identifier.scopuseid_2-s2.0-84985516504-
dc.identifier.volume26-
dc.identifier.issue9-
dc.identifier.spage892-
dc.identifier.epage894-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1987K569300010-

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