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- Publisher Website: 10.1039/c39850000314
- Scopus: eid_2-s2.0-37049101723
- WOS: WOS:A1985ADX2100003
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Article: An investigation of the kinetic and thermodynamic stability of a tribenzomacrobicyclic polyether complex with diquat in acetone solution
| Title | An investigation of the kinetic and thermodynamic stability of a tribenzomacrobicyclic polyether complex with diquat in acetone solution |
|---|---|
| Authors | |
| Issue Date | 1985 |
| Citation | Journal of the Chemical Society, Chemical Communications, 1985, n. 6, p. 314-317 How to Cite? |
| Abstract | Variable-temperature 1H n.m.r. spectroscopic studies in CD 3COCD3 and u.v. spectroscopic measurements in Me 2CO demonstrate that in the 1:1 complex, [Diquat·(1)] 2+, the guest is encapsulated within the host and that the complexation strength (ΔGo = -7.4 kcal mol-1) is enhanced by the macrobicyclic cryptate effect. |
| Persistent Identifier | http://hdl.handle.net/10722/332797 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kohnke, Franz H. | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:14:21Z | - |
| dc.date.available | 2023-10-06T05:14:21Z | - |
| dc.date.issued | 1985 | - |
| dc.identifier.citation | Journal of the Chemical Society, Chemical Communications, 1985, n. 6, p. 314-317 | - |
| dc.identifier.issn | 0022-4936 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332797 | - |
| dc.description.abstract | Variable-temperature 1H n.m.r. spectroscopic studies in CD 3COCD3 and u.v. spectroscopic measurements in Me 2CO demonstrate that in the 1:1 complex, [Diquat·(1)] 2+, the guest is encapsulated within the host and that the complexation strength (ΔGo = -7.4 kcal mol-1) is enhanced by the macrobicyclic cryptate effect. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | - |
| dc.title | An investigation of the kinetic and thermodynamic stability of a tribenzomacrobicyclic polyether complex with diquat in acetone solution | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/c39850000314 | - |
| dc.identifier.scopus | eid_2-s2.0-37049101723 | - |
| dc.identifier.issue | 6 | - |
| dc.identifier.spage | 314 | - |
| dc.identifier.epage | 317 | - |
| dc.identifier.isi | WOS:A1985ADX2100003 | - |