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Article: Conjugated copolymers containing low bandgap rhenium(I) complexes
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TitleConjugated copolymers containing low bandgap rhenium(I) complexes
 
AuthorsMak, CSK1
Cheung, WK1
Leung, QY1
Chan, WK1
 
KeywordsConjugated polymer
Low bandgap
Metal-containing polymer
Morphology
Photovoltaic
Rhenium(I)
 
Issue Date2010
 
PublisherWiley - V C H Verlag GmbH & Co KGaA.
 
CitationMacromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882 [How to Cite?]
DOI: http://dx.doi.org/10.1002/marc.200900890
 
AbstractConjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA.
 
ISSN1022-1336
2013 Impact Factor: 4.608
 
DOIhttp://dx.doi.org/10.1002/marc.200900890
 
ISI Accession Number IDWOS:000278436300014
Funding AgencyGrant Number
Research Grants Council of the Hong Kong Special Administrative Region, ChinaHKU 7008/07P
7005/08P
University of Hong Kong
Funding Information:

The project was supported by the Research Grants Council of the Hong Kong Special Administrative Region, China (project Nos. HKU 7008/07P and 7005/08P). Financial support from the University Development Fund, Strategic Research Theme and Small Project Fund (administrated by The University of Hong Kong) are also acknowledged.

 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorMak, CSK
 
dc.contributor.authorCheung, WK
 
dc.contributor.authorLeung, QY
 
dc.contributor.authorChan, WK
 
dc.date.accessioned2010-09-06T06:16:57Z
 
dc.date.available2010-09-06T06:16:57Z
 
dc.date.issued2010
 
dc.description.abstractConjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA.
 
dc.description.naturelink_to_subscribed_fulltext
 
dc.identifier.citationMacromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882 [How to Cite?]
DOI: http://dx.doi.org/10.1002/marc.200900890
 
dc.identifier.doihttp://dx.doi.org/10.1002/marc.200900890
 
dc.identifier.eissn1521-3927
 
dc.identifier.epage882
 
dc.identifier.hkuros170070
 
dc.identifier.isiWOS:000278436300014
Funding AgencyGrant Number
Research Grants Council of the Hong Kong Special Administrative Region, ChinaHKU 7008/07P
7005/08P
University of Hong Kong
Funding Information:

The project was supported by the Research Grants Council of the Hong Kong Special Administrative Region, China (project Nos. HKU 7008/07P and 7005/08P). Financial support from the University Development Fund, Strategic Research Theme and Small Project Fund (administrated by The University of Hong Kong) are also acknowledged.

 
dc.identifier.issn1022-1336
2013 Impact Factor: 4.608
 
dc.identifier.issue9-10
 
dc.identifier.openurl
 
dc.identifier.scopuseid_2-s2.0-77952643584
 
dc.identifier.spage875
 
dc.identifier.urihttp://hdl.handle.net/10722/69800
 
dc.identifier.volume31
 
dc.languageeng
 
dc.publisherWiley - V C H Verlag GmbH & Co KGaA.
 
dc.publisher.placeGermany
 
dc.relation.ispartofMacromolecular Rapid Communications
 
dc.relation.referencesReferences in Scopus
 
dc.subjectConjugated polymer
 
dc.subjectLow bandgap
 
dc.subjectMetal-containing polymer
 
dc.subjectMorphology
 
dc.subjectPhotovoltaic
 
dc.subjectRhenium(I)
 
dc.titleConjugated copolymers containing low bandgap rhenium(I) complexes
 
dc.typeArticle
 
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Author Affiliations
  1. The University of Hong Kong