File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Conjugated copolymers containing low bandgap rhenium(I) complexes

TitleConjugated copolymers containing low bandgap rhenium(I) complexes
Authors
KeywordsConjugated polymer
Low bandgap
Metal-containing polymer
Morphology
Photovoltaic
Rhenium(I)
Issue Date2010
PublisherWiley - V C H Verlag GmbH & Co KGaA.
Citation
Macromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882 How to Cite?
AbstractConjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/69800
ISSN
2014 Impact Factor: 4.941
2014 SCImago Journal Rankings: 1.619
ISI Accession Number ID
Funding AgencyGrant Number
Research Grants Council of the Hong Kong Special Administrative Region, ChinaHKU 7008/07P
7005/08P
University of Hong Kong
Funding Information:

The project was supported by the Research Grants Council of the Hong Kong Special Administrative Region, China (project Nos. HKU 7008/07P and 7005/08P). Financial support from the University Development Fund, Strategic Research Theme and Small Project Fund (administrated by The University of Hong Kong) are also acknowledged.

References

 

DC FieldValueLanguage
dc.contributor.authorMak, CSKen_HK
dc.contributor.authorCheung, WKen_HK
dc.contributor.authorLeung, QYen_HK
dc.contributor.authorChan, WKen_HK
dc.date.accessioned2010-09-06T06:16:57Z-
dc.date.available2010-09-06T06:16:57Z-
dc.date.issued2010en_HK
dc.identifier.citationMacromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882en_HK
dc.identifier.issn1022-1336en_HK
dc.identifier.urihttp://hdl.handle.net/10722/69800-
dc.description.abstractConjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co KGaA.en_HK
dc.relation.ispartofMacromolecular Rapid Communicationsen_HK
dc.subjectConjugated polymeren_HK
dc.subjectLow bandgapen_HK
dc.subjectMetal-containing polymeren_HK
dc.subjectMorphologyen_HK
dc.subjectPhotovoltaicen_HK
dc.subjectRhenium(I)en_HK
dc.titleConjugated copolymers containing low bandgap rhenium(I) complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1022-1336&volume=31&spage=&epage=&date=2010&atitle=Conjugated+Copolymers+Containing+Low+Bandgap+Rhenium(I)+Complexesen_HK
dc.identifier.emailMak, CSK: cskm@hkucc.hku.hken_HK
dc.identifier.emailChan, WK: waichan@hku.hken_HK
dc.identifier.authorityMak, CSK=rp00761en_HK
dc.identifier.authorityChan, WK=rp00667en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/marc.200900890en_HK
dc.identifier.scopuseid_2-s2.0-77952643584en_HK
dc.identifier.hkuros170070en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-77952643584&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume31en_HK
dc.identifier.issue9-10en_HK
dc.identifier.spage875en_HK
dc.identifier.epage882en_HK
dc.identifier.eissn1521-3927-
dc.identifier.isiWOS:000278436300014-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridMak, CSK=8899597100en_HK
dc.identifier.scopusauthoridCheung, WK=36104019200en_HK
dc.identifier.scopusauthoridLeung, QY=25650267500en_HK
dc.identifier.scopusauthoridChan, WK=13310083000en_HK

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats