Article: Conjugated copolymers containing low bandgap rhenium(I) complexes
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- Publisher Website: 10.1002/marc.200900890
- Scopus: eid_2-s2.0-77952643584
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| Title | Conjugated copolymers containing low bandgap rhenium(I) complexes | ||||||
|---|---|---|---|---|---|---|---|
| Authors | Mak, CSK1 Cheung, WK1 Leung, QY1 Chan, WK1 | ||||||
| Keywords | Conjugated polymer Low bandgap Metal-containing polymer Morphology Photovoltaic Rhenium(I) | ||||||
| Issue Date | 2010 | ||||||
| Publisher | Wiley - V C H Verlag GmbH & Co KGaA. | ||||||
| Citation | Macromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882 [How to Cite?] DOI: http://dx.doi.org/10.1002/marc.200900890 | ||||||
| Abstract | Conjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA. | ||||||
| ISSN | 1022-1336 2011 Impact Factor: 4.596 2011 SCImago Journal Rankings: 0.424 | ||||||
| DOI | http://dx.doi.org/10.1002/marc.200900890 | ||||||
| ISI Accession Number ID | WOS:000278436300014
Funding Information: The project was supported by the Research Grants Council of the Hong Kong Special Administrative Region, China (project Nos. HKU 7008/07P and 7005/08P). Financial support from the University Development Fund, Strategic Research Theme and Small Project Fund (administrated by The University of Hong Kong) are also acknowledged. | ||||||
| References | References in Scopus |
| dc.contributor.author | Mak, CSK | ||||||
|---|---|---|---|---|---|---|---|
| dc.contributor.author | Cheung, WK | ||||||
| dc.contributor.author | Leung, QY | ||||||
| dc.contributor.author | Chan, WK | ||||||
| dc.date.accessioned | 2010-09-06T06:16:57Z | ||||||
| dc.date.available | 2010-09-06T06:16:57Z | ||||||
| dc.date.issued | 2010 | ||||||
| dc.description.abstract | Conjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer mainchain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-lmked with tunctionalized intramolecular charge transfer units, which exhibited prominent absorption band in the UV-vis region. These functionalized charge transfer units not only broadened the absorption spectrum, but also functioned as a bidentate ligand. Upon the complexation of rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting polymers was further boardened, and the bandgap was reduced. The material design of this work has opened up a new approach in developing low bandgap metal-containing polymers as light harvesting materials. (Reprented Fig.) © 2010 WILEY-VCH Verlag GmbH & Co. KGaA. | ||||||
| dc.description.nature | Link_to_subscribed_fulltext | ||||||
| dc.identifier.citation | Macromolecular Rapid Communications, 2010, v. 31 n. 9-10, p. 875-882 [How to Cite?] DOI: http://dx.doi.org/10.1002/marc.200900890 | ||||||
| dc.identifier.doi | http://dx.doi.org/10.1002/marc.200900890 | ||||||
| dc.identifier.epage | 882 | ||||||
| dc.identifier.hkuros | 170070 | ||||||
| dc.identifier.isi | WOS:000278436300014
Funding Information: The project was supported by the Research Grants Council of the Hong Kong Special Administrative Region, China (project Nos. HKU 7008/07P and 7005/08P). Financial support from the University Development Fund, Strategic Research Theme and Small Project Fund (administrated by The University of Hong Kong) are also acknowledged. | ||||||
| dc.identifier.issn | 1022-1336 2011 Impact Factor: 4.596 2011 SCImago Journal Rankings: 0.424 | ||||||
| dc.identifier.issue | 9-10 | ||||||
| dc.identifier.openurl | | ||||||
| dc.identifier.scopus | eid_2-s2.0-77952643584 | ||||||
| dc.identifier.spage | 875 | ||||||
| dc.identifier.uri | http://hdl.handle.net/10722/69800 | ||||||
| dc.identifier.volume | 31 | ||||||
| dc.language | eng | ||||||
| dc.publisher | Wiley - V C H Verlag GmbH & Co KGaA. | ||||||
| dc.publisher.place | Germany | ||||||
| dc.relation.ispartof | Macromolecular Rapid Communications | ||||||
| dc.relation.references | References in Scopus | ||||||
| dc.subject | Conjugated polymer | ||||||
| dc.subject | Low bandgap | ||||||
| dc.subject | Metal-containing polymer | ||||||
| dc.subject | Morphology | ||||||
| dc.subject | Photovoltaic | ||||||
| dc.subject | Rhenium(I) | ||||||
| dc.title | Conjugated copolymers containing low bandgap rhenium(I) complexes | ||||||
| dc.type | Article |
Author Affiliations
- The University of Hong Kong