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Article: Synthesis, photophysics, photochemistry, electrochemistry and structural studies of luminescent rhenium (I) surfactant complexes; non-linear optical properties in Langmuir-Blodgett films

TitleSynthesis, photophysics, photochemistry, electrochemistry and structural studies of luminescent rhenium (I) surfactant complexes; non-linear optical properties in Langmuir-Blodgett films
Authors
Issue Date1998
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/jm/index.asp
Citation
Journal Of Materials Chemistry, 1998, v. 8 n. 1, p. 89-97 How to Cite?
AbstractA series of structurally related rhenium(i) tricarbonyl diimine surfactant-active complexes, [Re(CO)3(diimine){py(CH2)nCH3}] + and [Re(CO)3(diimine){pyCO(Chol)}]+ have been synthesized (n = 0, 1, 4, 12, 14, 16, 18; py = pyridyl, Chol = cholesteryl), and their photophysical, photochemical and electrochemical properties studied. A systematic study on the dependence of their photophysical properties in different environments has also been presented. In general, there is no apparent change in the photophysical behavior of these complexes as a function of the chain length of the surfactant type pyridyl ligands, the mechanism of which has been discussed. Langmuir-Blodgett films of the complexes have been prepared, and their π-A isotherms, together with their electronic absorption and emission properties studied. The second harmonic generation (SHG) properties of the LB films have also been investigated. The X-ray crystal structure of a surfactant rhenium(I) complex, [Re(bpy)(CO)3(pyC17H35)]ClO4 has been determined.
Persistent Identifierhttp://hdl.handle.net/10722/68993
ISSN
2013 Impact Factor: 6.626
2015 SCImago Journal Rankings: 2.540
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorLau, VCYen_HK
dc.contributor.authorWang, KZen_HK
dc.contributor.authorCheung, KKen_HK
dc.contributor.authorHuang, CHen_HK
dc.date.accessioned2010-09-06T06:09:34Z-
dc.date.available2010-09-06T06:09:34Z-
dc.date.issued1998en_HK
dc.identifier.citationJournal Of Materials Chemistry, 1998, v. 8 n. 1, p. 89-97en_HK
dc.identifier.issn0959-9428en_HK
dc.identifier.urihttp://hdl.handle.net/10722/68993-
dc.description.abstractA series of structurally related rhenium(i) tricarbonyl diimine surfactant-active complexes, [Re(CO)3(diimine){py(CH2)nCH3}] + and [Re(CO)3(diimine){pyCO(Chol)}]+ have been synthesized (n = 0, 1, 4, 12, 14, 16, 18; py = pyridyl, Chol = cholesteryl), and their photophysical, photochemical and electrochemical properties studied. A systematic study on the dependence of their photophysical properties in different environments has also been presented. In general, there is no apparent change in the photophysical behavior of these complexes as a function of the chain length of the surfactant type pyridyl ligands, the mechanism of which has been discussed. Langmuir-Blodgett films of the complexes have been prepared, and their π-A isotherms, together with their electronic absorption and emission properties studied. The second harmonic generation (SHG) properties of the LB films have also been investigated. The X-ray crystal structure of a surfactant rhenium(I) complex, [Re(bpy)(CO)3(pyC17H35)]ClO4 has been determined.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/jm/index.aspen_HK
dc.relation.ispartofJournal of Materials Chemistryen_HK
dc.titleSynthesis, photophysics, photochemistry, electrochemistry and structural studies of luminescent rhenium (I) surfactant complexes; non-linear optical properties in Langmuir-Blodgett filmsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0959-9428&volume=8&issue=1&spage=89&epage=97&date=1998&atitle=Synthesis,+photophysics,+photochemistry,+electrochemistry+and+structural+studies+of+luminescent+rhenium(I)+surfactant+complexes;+non-linear+optical+properties+in+Langmuir-Blodgett+filmsen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/A705015A-
dc.identifier.scopuseid_2-s2.0-0003108581en_HK
dc.identifier.hkuros31393en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0003108581&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume8en_HK
dc.identifier.issue1en_HK
dc.identifier.spage89en_HK
dc.identifier.epage97en_HK
dc.identifier.isiWOS:000071595100019-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridLau, VCY=7005811453en_HK
dc.identifier.scopusauthoridWang, KZ=7501396674en_HK
dc.identifier.scopusauthoridCheung, KK=7402406613en_HK
dc.identifier.scopusauthoridHuang, CH=36065677300en_HK

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